Patent classifications
C10G69/12
NEW POLYOLEFIN CATALYST AND USE THEREOF
Disclosed is a new polyolefin catalyst and preparation therefor. Specifically, disclosed is a catalytic system comprising a new complex of iron, cobalt, nickel, palladium, and platinum. In the presence of the catalytic system, oily polyethylene can be efficiently obtained from simple olefins such as ethylene under mild conditions, highly branched oily alkane mixture is then obtained after hydrogenation. The alkane mixture can be used as a processing aid and a high-performance lubricant base oil. The present invention also provides a method for preparing the catalyst, a method for preparing the highly branched oily alkane mixture and a method for preparing functional polyolefin oil.
Exotherm, conversion and selectivity management for oligomerization process
A process is presented for the control of the exotherm from an oligomerization process. The oligomerization process is for the conversion of C3 and C4 olefins to distillate. The process includes controlling the extent of the reaction to limit temperature rise, and recycle of a portion of the reactor effluent stream for dilution of the C3 and C4 olefins passed to the oligomerization reactors, and for separating out the product distillate.
METHOD TO PRODUCE HIGH QUALITY COMPONENTS FROM RENEWABLE RAW MATERIAL
The present disclosure relates to a method of producing high quality components from renewable raw material. Specifically, the disclosure relates to production of renewable materials which can be employed as high-quality chemicals and/or as high quality drop-in gasoline components. Further, the disclosure relates to drop-in gasoline components and to polymers obtainable by the method.
METHOD TO PRODUCE HIGH QUALITY COMPONENTS FROM RENEWABLE RAW MATERIAL
The present disclosure relates to a method of producing high quality components from renewable raw material. Specifically, the disclosure relates to production of renewable materials which can be employed as high-quality chemicals and/or as high quality drop-in gasoline components. Further, the disclosure relates to drop-in gasoline components and to polymers obtainable by the method.
Process for the preparation of polypropylenes from waste plastic feedstocks
The present invention relates to a process for the production of propylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising propylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an propylene-based polymer; wherein in step (d): •⋅ the coil outlet temperature is 2:: 800 and:::; 850° C., preferably 2:: 805 and:::; 835° C.; and •⋅ the weight ratio of steam to feed C is >0.3 and <0.8.
Process for the preparation of polypropylenes from waste plastic feedstocks
The present invention relates to a process for the production of propylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising propylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an propylene-based polymer; wherein in step (d): •⋅ the coil outlet temperature is 2:: 800 and:::; 850° C., preferably 2:: 805 and:::; 835° C.; and •⋅ the weight ratio of steam to feed C is >0.3 and <0.8.
Integrated process for conversion of vacuum gas oil and heavy oil
An integrated process and apparatus for conversion of gas oil and heavy oil is described. The process includes passing a gas oil feed to a fluid catalytic cracking (FCC) zone to obtain a FCC effluent; separating the FCC effluent in a separation zone into at least two fractions comprising a clarified slurry oil fraction and an overhead fraction; passing the clarified slurry oil fraction to a slurry hydrocracking zone forming at least a naphtha stream; and recycling at least a portion of the slurry hydrocracking naphtha stream to the FCC zone.
Systems and processes for conversion of ethylene feedstocks to hydrocarbon fuels
Systems, processes, and catalysts are disclosed for obtaining fuels and fuel blends containing selected ratios of open-chain and closed-chain fuel-range hydrocarbons suitable for production of alternate fuels including gasolines, jet fuels, and diesel fuels. Fuel-range hydrocarbons may be derived from ethylene-containing feedstocks and ethanol-containing feedstocks.
PROCESS FOR PRODUCING BENZENE AND LPG2
The invention is directed to a process for producing benzene and LPG comprising the steps of: (a) reacting a source feed stream comprising monoaromatic compounds of formula (I), wherein R1-R5 are the same or different and are chosen from hydrogen or a linear alkyl group of 1-10 carbon atoms, and methanol in an alkylation reactor comprising a basic catalyst to obtain an alkylation product stream and subsequently (b) contacting the alkylation product stream in the presence of hydrogen in a hydrocracking reactor with a hydrocracking catalyst comprising 0.01-1 wt-% hydrogenation metal in relation to the total catalyst weight and a zeolite having a pore size of 5-8 Å and a silica (SiO2) to alumina (Al2O3) molar ratio of 5-200 to produce a hydrocracking product stream comprising benzene and LPG under process conditions including a temperature of 425-580° C., a pressure of 300-5000 kPa gauge and a Weight Hourly Space Velocity of 0.1-15 h.sup.−1.
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Process for preparing hydrocarbon mixture exhibiting unique branching structure
Provided herein is a unique process that prepares a saturated hydrocarbon mixture with well-controlled structural characteristics that address the performance requirements driven by the stricter environmental and fuel economy regulations for automotive engine oils. The process allows for the branching characteristics of the hydrocarbon molecules to be controlled so as to consistently provide a composition that has a surprising CCS viscosity at −35° C. (ASTM D5329) and Noack volatility (ASTM D5800) relationship. The process comprises providing a specific olefinic feedstock, oligomerizing in the presence of a BF.sub.3 catalyst, and hydroisomerizing in the presence of a noble-metal impregnated, 10-member ring zeolite catalyst.