Patent classifications
C10G69/12
Base oil synthesis via ionic catalyst oligomerization and waterless separation of the oligomerization catalyst
Described herein is a base oil synthesis via ionic catalyst oligomerization further utilizing a hydrophobic process for removing an ionic catalyst from a reaction mixture with a silica gel composition, specifically a reaction mixture comprising an oligomerization reaction to produce PAO utilizing an ionic catalyst wherein the ionic catalyst is removed post reaction.
Process for the preparation of polymers from waste plastic feedstocks
The present invention relates to a process for the production of polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an polymer. The process of the present invention allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.
Process for the preparation of polymers from waste plastic feedstocks
The present invention relates to a process for the production of polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an polymer. The process of the present invention allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.
Process for upgrading pygas feed by aromatizing non-aromatics to BTX
In accordance with one or more embodiments of the present disclosure, a method for producing aromatic compounds from pyrolysis gasoline includes hydrotreating a stream comprising the pyrolysis gasoline, thereby producing a hydrotreated pyrolysis gasoline stream comprising paraffins; aromatizing the hydrotreated pyrolysis gasoline stream comprising paraffins, thereby producing a stream comprising benzene-toluene-xylenes (BTX); and processing the stream comprising BTX in an aromatics recovery complex, thereby producing the aromatic compounds from the pyrolysis gasoline.
Process for upgrading pygas feed by aromatizing non-aromatics to BTX
In accordance with one or more embodiments of the present disclosure, a method for producing aromatic compounds from pyrolysis gasoline includes hydrotreating a stream comprising the pyrolysis gasoline, thereby producing a hydrotreated pyrolysis gasoline stream comprising paraffins; aromatizing the hydrotreated pyrolysis gasoline stream comprising paraffins, thereby producing a stream comprising benzene-toluene-xylenes (BTX); and processing the stream comprising BTX in an aromatics recovery complex, thereby producing the aromatic compounds from the pyrolysis gasoline.
PROCESS FOR CONVERTING C2-C5 HYDROCARBONS TO GASOLINE AND DIESEL FUEL BLENDSTOCKS
A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.
Methanol to olefin (MTO) process
A process for producing an olefin stream, said process comprising passing a feedstock stream comprising oxygenates over catalyst comprises a zeolite with a framework having a 10-ring pore structure, in which said 10-ring pore structure comprises a unidimensional (1-D) pore structure, such as *MRE, at a pressure of 1-25 bar and a temperature of 240-360° C. The olefin stream may be converted to jet fuel, particularly sustainable aviation fuel (SAF) by further oligomerization and hydrogenation.
Methanol to olefin (MTO) process
A process for producing an olefin stream, said process comprising passing a feedstock stream comprising oxygenates over catalyst comprises a zeolite with a framework having a 10-ring pore structure, in which said 10-ring pore structure comprises a unidimensional (1-D) pore structure, such as *MRE, at a pressure of 1-25 bar and a temperature of 240-360° C. The olefin stream may be converted to jet fuel, particularly sustainable aviation fuel (SAF) by further oligomerization and hydrogenation.
METHODS FOR INTEGRATED SEPARATION OF DIENES
Systems and methods for processing a C.sub.4 and C.sub.5 stream are disclosed. A pygas stream can be separated in a depentanizer to produce a C.sub.4 and C.sub.5 stream and a C.sub.6 to C.sub.9+ stream. The C.sub.4 and C.sub.5 stream is further processed to recover C.sub.5 dienes including isoprene, pentadiene, cyclopentadiene, or combinations thereof. The C.sub.6 to C.sub.9+ stream is further processed to recover aromatics including benzene, toluene, xylene, ethylbenzene, or combinations thereof.
Systems and processes for processing pyrolysis oil
A system for processing plastic waste may include a feed line, a feed fractionator, a hydrotreater, a catalytic reforming unit, a heavy oil cracker, and a steam cracker. A pyrolyzed plastics feed is separated into light, medium, and heavy hydrocarbon streams. The hydrotreater removes sulfur, and the catalytic reforming unit produces a circular aromatic-rich stream. The heavy oil cracker generates cracked streams. The steam cracker produces a circular olefin stream from a cracked stream. A system for processing plastic waste may include the feed line, the feed fractionator, the hydrotreater, a medium hydrocarbon fractionator, the catalytic reforming unit, a full-range reforming unit, the heavy oil cracker, and the steam cracker. The medium hydrocarbon fractionator produces two hydrocarbon streams. The full-range naphtha reforming unit produces a second circular aromatic-rich stream.