Patent classifications
C10G70/06
RAW-MATERIAL SUPPLY SYSTEM AND RAW-MATERIAL SUPPLY METHOD
The present invention relates to a raw-material supply system and a raw-material supply method for pyrolyzing waste plastic including PVC and PET. The raw-material supply system includes: a slaked-lime supply device (12) configured to feed slaked lime to the waste plastic; an operation controller (15) configured to instruct the slaked-lime supply device (12) to feed the slaked lime to the waste plastic, the slaked lime to be fed having the number of moles that is 1 to 4 times a total number of moles of the polyvinyl chloride and the polyethylene terephthalate in the waste plastic; a melting dechlorination device (18) configured to dechlorinate the polyvinyl chloride and hydrolyze the polyethylene terephthalate by mixing the waste plastic and the slaked lime while heating the waste plastic and the slaked lime; a degassing hopper (20) coupled to the melting dechlorination device (18); and a raw-material supply device (22) configured to deliver the molten waste plastic from the degassing hopper (20) to a pyrolysis furnace (6).
Recovery of Hydrogen and Ethylene from Fluid Catalytic Cracking Refinery Off Gas
A method comprising: introducing a refinery off gas stream into an oil absorber wherein the refinery off gas stream comprises H.sub.2, N.sub.2, O.sub.2, methane, ethane, ethylene, propane, propylene, and C.sub.4+; introducing a solvent into the oil absorber; counter-currently contacting the refinery off gas stream and the solvent in the oil absorber; generating an absorber overhead stream comprising H.sub.2, N.sub.2, O.sub.2, and methane; generating an absorber bottoms stream comprising the solvent wherein ethane, ethylene, propane, propylene, and C.sub.4+ are dissolved in the solvent; introducing the absorber bottoms stream into a solvent regenerator and generating an overhead stream comprising ethane, ethylene, propane, propylene, and C.sub.4+; and introducing the overhead stream into a C.sub.2-C.sub.3 splitter that generates a dilute ethylene product stream and a bottoms product stream, wherein the dilute ethylene product stream comprises ethylene and ethane, and wherein the bottoms product stream comprises propane, propylene, and C.sub.4+.
Aqueous absorbent composition for enhanced removal of hydrogen sulfide from gaseous mixtures and method for using the same
The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures containing hydrogen sulfide. The aqueous alkanolamine solution comprises (i) an amino compound with the formula:
R.sup.1R.sup.2NCH.sub.2CH(OH)CH.sub.2OH
wherein R.sup.1 and R.sup.2 independently represent lower alkyl groups of 1 to 3 carbon atoms, (ii) piperazine, and (iii) optionally a physical solvent, wherein said solution does not contain a strong acid. Further, the present invention relates to a process for removing hydrogen sulfide from a gaseous mixture containing hydrogen sulfide, and additionally other acid gases, if present, for example carbon dioxide, comprising the step of contacting the gaseous mixture contain hydrogen sulfide with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140 F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.
QUENCH WATER HYDROCYCLONE
An apparatus for processing liquid from a quench water tower includes a first pipe for removing the liquid from the quench water tower; a hydrocyclone in fluid communication with the first pipe and in which the liquid is separated into particulate and liquid constituents by centrifugal force; and an oil-water separator downstream of and in fluid communication with a first outlet of the hydrocyclone. A related system and method are also provided.
METHOD AND APPARATUS FOR RECOVERING ABSORBING AGENTS IN ACID GAS TREATMENT
A method and apparatus for continuously treating acid gases including recovering absorbent chemicals by introducing streams leaving a regenerator and/or leaving an absorber into a static mixing zone wherein supplemental washing water is added to recover absorbent chemicals. Improvements to the prior art methods are provided where one or more absorbent chemical recovery units are included to increase the amount of recovered absorbent chemicals exiting the regenerator and/or exiting the absorber are increased and/or maximized. Absorbent chemical recovery units can include mixing units where liquid is added to the stream of sour gas and absorbent chemical to mix with and absorb the absorbent chemical from the stream.
NOVEL PROCESS OF ABSORPTION AND STABILIZATION UNIT AND COMPREHENSIVE UTILIZATION METHOD OF PRODUCTS THEREFROM
The present invention relates to a novel process of an absorption and stabilization unit, comprising operation steps of: sS1, primary compression of rich gas, S2, secondary compression of rich gas, S3, dry gas absorption, S4, gasoline stabilization, and so on. After rich gas from a catalytic fractionation unit undergoes operations such as primary compression, rectification using a de-heavy fractionator, and secondary compression, the gas phase mainly composed of C3 from the top of the de-heavy fractionator and naphtha from the catalytic fractionation unit are absorbed in an absorption tower, and dry gas of unabsorbed components is discharged from the top of the absorption tower; rich-absorption oil from the bottom of the absorption tower and the liquid phase mainly composed of C4 from the bottom of the de-heavy fractionator enter an stabilization tower to perform stable operation. The novel process of the absorption and stabilization unit of the present invention can obviously reduce the energy consumed by the absorption and stabilization unit by means of step-by-step compression, and facilitates further utilization of products from the absorption and stabilization unit. The present invention also relates to a method for comprehensive utilization of products from the absorption and stabilization unit, for maximizing the conversion of effective components in stabilized gasoline, liquefied gas, and dry gas after the novel absorption and stabilization process into high value-added chemical products such as propylene.
PROCESS FOR PRODUCING BTX AND LPG
The invention is directed to a process for producing BTX and LPG, comprising: a) contacting a feed stream comprising C5-C12 hydrocarbons in the presence of hydrogen with a hydrocracking catalyst in a hydrocracking reactor to produce a hydrocracking product stream comprising hydrogen, methane, LPG and BTX, b) separating the hydrocracking product stream into a first gas stream and a first liquid stream, c) separating the first gas stream to obtain a second gas stream comprising hydrogen and methane and a second liquid stream comprising LPG and BTX, wherein the separation is performed such that the second liquid stream is substantially free of hydrogen and methane, d) separating the second liquid stream into a third gas stream comprising LPG and a third liquid stream comprising BTX, wherein step (c) involves adding a part of the third liquid stream to the first gas stream to absorb the LPG in the first gas stream to obtain the second liquid stream or adding a part of the third liquid stream to a gas stream sep crated from the first gas stream to absorb the LPG in said gas stream separated from the first gas stream to obtain the second liquid stream.
PROCESS FOR PRODUCING BTX AND LPG
The invention is directed to a process for producing BTX and LPG, comprising: a) contacting a feed stream comprising C5-C12 hydrocarbons in the presence of hydrogen with a hydrocracking catalyst in a hydrocracking reactor to produce a hydrocracking product stream comprising hydrogen, methane, LPG and BTX, b) separating the hydrocracking product stream into a first gas stream and a first liquid stream, c) separating the first gas stream to obtain a second gas stream comprising hydrogen and methane and a second liquid stream comprising LPG and BTX, wherein the separation is performed such that the second liquid stream is substantially free of hydrogen and methane, d) separating the second liquid stream into a third gas stream comprising LPG and a third liquid stream comprising BTX, wherein step (c) involves adding a part of the third liquid stream to the first gas stream to absorb the LPG in the first gas stream to obtain the second liquid stream or adding a part of the third liquid stream to a gas stream sep crated from the first gas stream to absorb the LPG in said gas stream separated from the first gas stream to obtain the second liquid stream.
Method and apparatus for reducing condensation in vapor-liquid acid gas scrubbers
The invention generally relates to a hydrocarbon process for reducing condensation in a vapor-liquid amine or caustic acid gas scrubber. A first mixture is provided, the first mixture being superheated and comprising C.sub.2+ mono-olefin, acid gases, and diolefin molecules. The first mixture is divided into a first stream and a second stream, the first and second streams having substantially the same composition. The first stream is cooled to produce a gas phase and a liquid phase, the gas phase comprising less C.sub.6+, the liquid phase containing more C.sub.6+. The gas phase is separated to create a third stream. The third stream and the second stream are combined to form a second substantially superheated mixture. The second mixture is conducted to an acid gas scrubbing tower. The invention also relates to an apparatus for carrying out this process.
Method and apparatus for reducing condensation in vapor-liquid acid gas scrubbers
The invention generally relates to a hydrocarbon process for reducing condensation in a vapor-liquid amine or caustic acid gas scrubber. A first mixture is provided, the first mixture being superheated and comprising C.sub.2+ mono-olefin, acid gases, and diolefin molecules. The first mixture is divided into a first stream and a second stream, the first and second streams having substantially the same composition. The first stream is cooled to produce a gas phase and a liquid phase, the gas phase comprising less C.sub.6+, the liquid phase containing more C.sub.6+. The gas phase is separated to create a third stream. The third stream and the second stream are combined to form a second substantially superheated mixture. The second mixture is conducted to an acid gas scrubbing tower. The invention also relates to an apparatus for carrying out this process.