The apparatus produces a diesel stream from a biorenewable feedstock by hydrotreating to remove heteroatoms and hydroisomerization to improve cold flow properties. Heavy diesel can be hydrocracked to jet fuel range material or further hydroisomerized to increase its value lower its freeze point while light diesel may be taken as a motor fuel.

A jet boiling range composition is provided with an unexpected distribution of carbon chain lengths for the hydrocarbons and paraffins in the composition. The hydrocarbon composition corresponds to a jet boiling range composition that includes 40 wt % or more of hydrocarbons and/or paraffins that have carbon chain lengths of 17 carbons or 18 carbons. Additionally or alternately, the hydrocarbon composition can contain 45 wt % or less of C.sub.14-C.sub.17 hydrocarbons and/or paraffins. This unexpected distribution of carbon chain lengths in a jet boiling range composition can be achieved for a composition that has a freeze point of −40° C. or lower and a flash point of 38° C. or higher. Optionally, the jet boiling range composition can also have a T10 distillation point of 205° C. or less (such as down to 150° C.) and a final boiling point of 300° C. or less

A reaction device is provided with a first wall that defines an interior in which a stirring mechanism is located. A heat exchanger is at least partly provided on the first outer wall surface facing away from the interior and/or on the stirring mechanism, wherein the heat exchanger has a grate structure, and at least two layers are provided which have a grate structure. Thus, it is possible to transfer heat in a precise and efficient manner primarily by means of thermal radiation in endothermic processes at different temperature levels, in particular pyrolysis, gassing, and reforming processes, and thereby use the exhaust heat for other processes.

A system that includes a feedstock of a non-petroleum or renewable feedstock containing oxygen and contaminants of one or more of metals, gums, and resins that is introduced into the reactor at a flow velocity of from 20 ft/sec to 100 ft/sec. The feedstock is heated within the reactor to a temperature of from 700° F. to 1100° F. to remove and/or reduce the content of one or more of gums and resins in the fats and/or oils of the feedstock. The system further includes a reactor product that is formed in the reactor from the feedstock that has the one or more of gums and resins in the fats and/or oils of the feedstock removed and/or reduced and a heat exchanger to cool the reactor product. A separator unit separates and removes non-condensable gases, metals and water from the cooled reactor product. A final product of the system is separated from the non-condensable gases, metals and water from the cooled reactor product. The final product has an oxygen content that is 60% or less of that of the feedstock, and wherein the final product comprises 25 wt % or less of any triglycerides, monoglycerides, diglycerides, free fatty acids, phosphatides, sterols, tocopherols, tocotrienols, and fatty alcohols, from 5 wt % to 30 wt % naphtha, and 50 wt % or more diesel.

The process produces a diesel stream from a biorenewable feedstock by hydrotreating to remove heteroatoms and hydroisomerization to improve cold flow properties. Heavy diesel can be hydrocracked to jet fuel range material or further hydroisomerized to increase its value lower its freeze point while light diesel may be taken as a motor fuel.

The invention relates to a catalytic process for upgrading a renewable crude oil produced from biomass and/or waste comprising providing a renewable crude oil and pressurizing it to a pressure in the range in the range 60 to 150 bar, contacting the pressurized renewable crude oil with hydrogen and at least one heterogeneous catalyst contained in a first reaction zone at a weight based hourly space velocity (WHSV) in the range 0.1 to 2.0 h.sub.−1 and at a temperature in the range of 150° C. to 360° C., hereby providing a partially upgraded renewable crude oil, separating the partially upgraded renewable crude oil from the first reaction zone to a partially upgraded heavy renewable oil fraction, a partially upgraded light renewable oil fraction, a water stream and a process gas stream, introducing the separated and partially upgraded heavy renewable oil fraction and separated process gas to a second reaction zone comprising at least two reactors arranged in parallel and being adapted to operate in a first and a second mode of operation, the reactors comprising dual functioning heterogeneous catalyst(-s) capable of performing a catalytic steam cracking reaction in a first mode of operation or a steam reforming reaction in a second mode of operation, where the partially upgraded heavy renewable oil fraction from the first reaction zone is contacted with the dual functioning heterogeneous catalyst and steam at a pressure of 10 to 150 bar and a temperature of 350° C. to 430° C. whereby a catalytic steam cracking of the partially upgraded heavy renewable oil is performed in the reactors in the first mode of operation, hereby providing a further upgraded heavy renewable oil fraction, while separated process gas from the first and/or second reaction zone is contacted with the dual functioning catalyst and steam at a pressure of 0.1 to 10 bar and a temperature of 350 to 600° C. in the reactors in the second mode of operation and contacted with the dual functioning catalyst, thereby producing a hydrogen enriched gas, separating the further upgraded heavy renewable oil fraction from the catalytically steam cracking reactor to at least one light renewable oil fraction, a heavy renewable oil fraction, a hydrogen rich process gas and a water phase, separating hydrogen from the hydrogen enriched gas from the catalytic steam cracking zone and/or from the catalytic steam reforming and recycling it to the first reaction zone, alternating the reactors between the first mode of operation and the second mode of operation at predetermined time intervals thereby allowing for regeneration of the heterogeneous catalyst for the catalytic steam cracking in the first mode of op

The present disclosure relates to methods for preparing aviation fuel component from a feedstock containing fossil hydrotreating feed and a second feed containing esters of fatty acids and rosins, free fatty acids and resin acids. The method includes subjecting the feedstock to hydrotreatment reaction conditions to produce a hydrotreated stream, separating the hydrotreated stream to three fractions from which at least part the highest boiling fraction is subjected to hydrocracking reaction to produce a hydrocracked stream. At least part of the hydrocracked stream is admixed with at least part of the hydrotreated stream, and their admixture is processed further until desired conversion of the feedstock to the aviation fuel component is obtained.

Processes for treating highly viscous hydrocarbons, such as bitumen from oil sands or petroleum residues, with hydrogen-donor solvents are described. The hydrogen-donor solvent is prepared. A mixture of the hydrocarbon and the hydrogen-donor solvent is heated, and the product is cooled to produce a low viscosity and mildly upgraded hydrocarbon. The hydrogen-donor solvent can be modified to improve its solvent usefulness.

The present technology provides a method that includes contacting a composition with a caustic solution to produce a caustic-treated composition; combining the caustic-treated composition with silica particles to produce a slurry; and removing the silica particles from the slurry to produce a treated composition; wherein the composition includes one or more of animal fats, animal oils, plant fats, plant oils, vegetable fats, vegetable oils, greases, and used cooking oil and the composition includes: at least about 10 wppm of total metals, at least about 8 wppm of phosphorus, at least about 10 wppm of chlorine, at least about 10 wppm of sulfur, at least about 20 wppm of nitrogen, at least about 5 wt.% of free fatty acids; and has an acid number from about 10 mg KOH/g to about 150 mg KOH/g, and the silica particles has a particle size from about 10 microns to about 50 microns, a BET surface area from about 200 m.sup.2/g to about 1000 .sub.m.sup.2.sub./g.

The present invention relates to novel lignin-derived compounds and compositions comprising the same and their use as redox flow battery electrolytes. The invention further provides a method for preparing said compounds and compositions as well as a redox flow battery comprising said compounds and compositions. Additionally, an assembly for carrying out the inventive method is provided.