This application relates to methods and systems that utilize catalytic methods to produce jet fuel such as hydrocarbons with carbons numbers from C9 to C16. Disclosed herein is an example method of producing renewable jet fuel. Examples embodiments of the method include hydrocracking a biofeedstock by reaction with hydrogen in the presence of a hydrocracking catalyst to form a hydrocracked biofeedstock. Examples embodiments of the method further include isomerizing at least a portion of the hydrocracked biofeedstock in the presence of a dewaxing catalyst to form a dewaxed effluent. Examples embodiments of the method further include separating the dewaxed effluent to form a renewable jet fuel product.

Systems and methods are provided for integrated pyrolysis and gasification of a biomass feed, either as a separate feed or under co-processing conditions. The integrated pyrolysis and gasification can be performed using any convenient reactor configuration, such as fluidized coking reactor configuration or a fluid catalytic cracking reactor configuration. The biomass feed can initially by pyrolyzed to form liquid products, gas phase products, and char. The char can then be used as the input feed to gasification. In aspects where the biomass feed is co-processed, the biomass can be co-processed with a co-feed that is suitable for processing under fluidized coking conditions or other pyrolysis conditions, such as a conventional fluidized coking feedstock.

A non-petroleum or renewable feedstock containing oxygen and contaminants of metals, gums, and resins is treated by introducing the feedstock into a reactor at a flow velocity of at least 20 ft/sec. The feedstock is heated within the reactor and cooled to form a reduced-temperature reactor product. At least a portion of the reduced-temperature reactor product is feed into a hydroprocessing reactor containing a hydroprocessing catalyst to form a hydroprocessed product. The hydroprocessed product is cooled and non-condensable gases, metals and water are separated and removed to form a final product. The final product has an oxygen content that is 60% or less of that of the feedstock, and wherein the final product comprises 25 wt % or less any triglycerides, monoglycerides, diglycerides, free fatty acids, phosphatides, sterols, tocopherols, tocotrienols, or fatty alcohols, from 5 wt % to 30 wt % naphtha, and 50 wt % or more diesel.

In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt % to 99 wt % total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt %, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H.sub.2, H.sub.2O, CO, CO.sub.2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt % to 99 wt % total carbon and optimized for a compositional parameter.

A process for producing high octane bio-based alkylate is provided. The process involves reacting isobutane and bio-ethylene using an ionic liquid catalyst. Reaction conditions can be chosen to assist in attaining, or to optimize, desirable alkylate yields and/or properties.

Electric-powered, closed-loop, continuous-feed, endothermic energy-conversion systems and methods are disclosed. In one embodiment, the presently disclosed energy-conversion system includes a shaftless auger. In another embodiment, the presently disclosed energy-conversion system includes a drag conveyor. In yet another embodiment, the presently disclosed energy-conversion system includes a distillation and/or fractionating stage. The endothermic energy-conversion systems and methods feature mechanisms for natural resource recovery, refining, and recycling, such as secondary recovery of metals, minerals, nutrients, and/or carbon char.

The present disclosure relates to methods for producing renewable base oil and other valuable renewable fuel components from a feedstock of biological origin comprising free fatty acids and glycerides. The feedstock is first separated to two or more effluent streams containing a fatty acid fraction and glyceride fraction. The glycerides are hydrolyzed to free fatty acids and glycerol, and the fatty acids thus obtained are recycled to the separating. The fatty acids are then converted to the base oil by ketonisation, hydrodeoxygenation and hydroisomerisation. The glycerol is converted to propanols by selective hydrogenolysis.

A biomass pyrolysis device and a biomass pyrolysis method is for optimal matching of thermal energy and microwave energy, wherein the device comprises a power generation system, a drying device and a microwave pyrolysis device; wherein the drying device is a cylinder nested with a flue gas layer and a material layer, a material inlet of the drying device is connected with a feeding device, and a volatile outlet is connected with a condensing unit; the microwave pyrolysis device is connected with a material outlet of the drying device, and a pyrolysis gas outlet of the microwave pyrolysis device is connected with the condensing unit; the condensing unit is connected with the power generation system, and waste gas generated by the power generation system is introduced into the flue gas layer of the drying device.

An integrated process for the production of a useful liquid hydrocarbon product comprises: feeding a gasification zone with an oxygen-containing feed and a first carbonaceous feedstock comprising waste materials and/or biomass, gasifying the first carbonaceous feedstock in the gasification zone to produce first synthesis gas, partially oxidising the first synthesis gas in a partial oxidation zone to generate partially oxidised synthesis gas, combining at least a portion of the first synthesis gas and/or the partially oxidised synthesis gas and at least a portion of electrolysis hydrogen obtained from an electrolyser in an amount to achieve the desired hydrogen to carbon monoxide molar ratio of from about 1.5:1 to about 2.5:1, and to generate a blended synthesis gas, wherein the electrolyser operates using green electricity; and subjecting at least a portion of the blended synthesis gas to a conversion process effective to produce the liquid hydrocarbon product.

The present disclosure relates to methods for preparing aviation fuel component from a feedstock containing fossil hydrotreating feed and a second feed containing esters of fatty acids and rosins, free fatty acids and resin acids. The method includes subjecting the feedstock to hydrotreatment reaction conditions to produce a hydrotreated stream, separating the hydrotreated stream to three fractions from which at least part the highest boiling fraction is subjected to hydrocracking reaction to produce a hydrocracked stream. At least part of the hydrocracked stream is admixed with at least part of the hydrotreated stream, and their admixture is processed further until desired conversion of the feedstock to the aviation fuel component is obtained.