C10G2300/1022

GASIFICATION PROCESS
20230135142 · 2023-05-04 ·

An integrated process for the production of a useful liquid hydrocarbon product comprises: feeding a gasification zone with an oxygen-containing feed and a first carbonaceous feedstock comprising waste materials and/or biomass, gasifying the first carbonaceous feedstock in the gasification zone to produce first synthesis gas, partially oxidising the first synthesis gas in a partial oxidation zone to generate partially oxidised synthesis gas, combining at least a portion of the first synthesis gas and/or the partially oxidised synthesis gas and at least a portion of electrolysis hydrogen obtained from an electrolyser in an amount to achieve the desired hydrogen to carbon monoxide molar ratio of from about 1.5:1 to about 2.5:1, and to generate a blended synthesis gas, wherein the electrolyser operates using green electricity; and subjecting at least a portion of the blended synthesis gas to a conversion process effective to produce the liquid hydrocarbon product.

PROCESS TO PREPARE PARAFFIN WAX

A process to prepare paraffins and waxes is provided, the process comprising:

subjecting a Fischer-Tropsch product stream comprising paraffins having from 10 to 300 carbon atoms to a hydrogenation step, thereby obtaining a hydrogenated Fischer-Tropsch product stream comprising 10 to 300 carbon atoms;
separating the hydrogenated Fischer-Tropsch product stream, thereby obtaining at least a fraction comprising 10 to 17 carbon atoms and a fraction comprising 18 to 300 carbon atoms;
separating the fraction comprising 18 to 300 carbon atoms, thereby obtaining one or more first light waxes having a congealing point in the range of 30 to 75° C. and a second heavy wax having a congealing point in the range of 75 to 120° C.; and
hydrofinishing one or more wax fractions having a congealing point in the range of 30 to 75° C. thereby obtaining one or more hydrofinished wax fractions having a congealing point in the range of 30 to 75° C.

SYSTEMS AND METHODS RELATED TO THE SEPARATION WAX PRODUCTS FROM PRODUCTS

Disclosed herein is a system comprising: a) a separator tank comprising a first inlet, a second inlet, a first outlet, and a second outlet, b) a heat exchanger, and c) a holding tank comprising a third inlet and a third outlet, wherein the separator tank is in fluid communication with the holding tank via a first connector and via a second connector, wherein the first connector is connected to the first outlet of the separator tank and to the third inlet of the holding tank, wherein the second connector is connected to the first inlet of the separator tank and to the third outlet of the holding tank, and wherein the first connector and the second connector are in communication with the heat exchanger.

PROCESS FOR PREPARING A BASE OIL HAVING A REDUCED CLOUD POINT

A process for preparing a base oil fraction having a reduced cloud point from a hydrocarbon feed which is derived from a Fischer-Tropsch process is provided. The process comprises: subjecting a hydrocarbon feed which is derived from a Fischer-Tropsch process to a catalytic dewaxing treatment to obtain an at least partially isomerised product; separating at least part of the at least partially isomerised product into one or more light hydrocarbon fractions and one or more heavy base oil fractions; separating at least one of the heavy base oil fractions by means of a first membrane into a first permeate and a first retentate; separating at least part of the first permeate by means of a second membrane into a second permeate and a second retentate; and recovering the second permeate.

METHOD FOR HYDROFINING OF MIDDLE DISTILLATES OF FISCHER-TROPSCH SYNTHETIC FULL-RANGE DISTILLATES
20170362517 · 2017-12-21 ·

A method for hydrofining of middle distillates of Fischer-Tropsch synthetic full-range distillates, the method including: 1) separating middle distillates of Fischer-Tropsch synthetic full-range distillates to yield light distillates, heavy distillates and intermediate distillates; 2) metering the light distillates, the heavy distillates and the intermediate distillates; providing a hydrogenation reactor filled with a hydrofining catalyst and including a first feed inlet, a second feed inlet and a third feed inlet from the top down; mixing hydrogen and the light distillates, the heavy distillates and the intermediate distillates, respectively, and introducing resulting mixtures to the hydrogenation reactor via the first feed inlet, the second feed inlet and the third feed inlet, respectively; and 3) introducing products from 2) to a gas-liquid separator to yield hydrogen and liquid products, returning the hydrogen to the hydrogenation reactor, and introducing the liquid products to a fractionating column for further separation.

APPARATUS AND METHOD FOR PRODUCING DIESEL FUEL AND JET FUEL USING FISCHER-TROPSCH SYNTHETIC OIL
20170362518 · 2017-12-21 ·

An apparatus for producing diesel fuel and jet fuel using Fischer-Tropsch synthetic oil, the apparatus including a hydrofining reactor, a hot separator, a first rectifying column, a hydrocracking reactor, a hydroisomerization reactor, a second rectifying column, a first mixing chamber and a second mixing chamber. The hydrofining reactor includes a raw material inlet and a hydrofining product outlet. The hot separator includes a separated oil outlet and a hydrofining product inlet which is connected to the hydrofining product outlet. The first rectifying column includes a tail oil fraction outlet, a diesel fraction outlet and a separated oil inlet which is connected to the separated oil outlet. The first mixing chamber includes a circulating hydrogen inlet, a first mixture outlet and a tail oil fraction inlet which is connected to the tail oil fraction outlet.

Method for the production of synthetic jet fuel

A method to produce a fuel product such as jet fuel, diesel or single battlefield fuel from a Fischer Tropsch syncrude comprising the steps of: 1) Separating the HFTL product from the reactor effluent gasses at reactor temperature and partially cooling the reactor effluent gas before transferring it to the enhanced hot separator; 2) enhancing the hot separator downstream of the Fischer Tropsch reactor with trays or packing and also adding reflux of the LFTL product, to improve separation efficiency and substantially reduce the C16+ portion of the hydrocarbons in the LFTL product; 3) combining the HFTL and MFTL product to from a combined HFTL product and further processing the combined HFTL in a hydroprocessing reactor that has a stacked bed with a layer of hydrocracking catalyst to crack the waxy C20+ hydrocarbons and a layer of hydroisomerization catalyst to isomerize the light fraction to increase the iso to n-paraffin ratio of the hydroprocessed product; 4) the LFTL product that is not recycled to the hot separator as reflux, bypasses the hydroprocessing reactor and is blended with the hydroprocessed product before distillation; and 5) the combined raw LFTL product and the hydroprocessed product is distilled to make naphtha, a fuel product, and a baseoil product. The method may be modified to make a single fuel product, preferably a jet fuel product.

Diesel fuel or diesel fuel base stock and production method thereof

Provided is a hydrotreating step (A) containing a hydroisomerization step (A1) that obtains a hydroisomerized oil (a1) by bringing a FT synthesis oil into contact with a hydroisomerization catalyst and/or a hydrocracking step (A2) that obtains a hydrocracked oil (a2) by bringing it into contact with a hydrocracking catalyst, and a fractionation step (B) that transfers at least a portion of the hydrotreated oil (a) composed of the hydroisomerized oil (a1) and/or the hydrocracked oil (a2) to a fractionator and, at the very least, obtains a middle distillate (b1) with a 5% distillation point of 130 to 170° C. and a 95% distillation point of 240 to 300° C., and a heavy oil (b2) that is heavier than the middle distillate (b1).

PROCESS TO PREPARE A HEAVY PARAFFIN WAX

The present invention provides a paraffin wax having a congealing point according to ASTM D938 of at least 100° C. and a Saybolt colour according to ASTM D156 of at least 25 cm.

METHOD FOR PREPARING MONOCYCLIC AROMATIC COMPOUNDS AND LONG-CHAIN OLEFIN COMPOUNDS FROM CARBON DIOXIDE-RICH SYNTHESIS GAS

Disclosed is a method for directly synthesizing monocyclic aromatic compounds and long-chain olefin compounds from a carbon dioxide-rich synthetic gas and, specifically, a method for directly synthesizing monocyclic aromatic compounds and long-chain olefin compounds from a carbon dioxide-rich synthetic gas, the method comprising a step of preparing a C.sub.1-C.sub.15 short-chain hydrocarbon by Fischer-Tropsch (FT) synthesis and a step of preparing monocyclic aromatic compounds and long-chain olefin compounds by dehydrogenating the short-chain hydrocarbon products, and maximizing the yield of the short-chain hydrocarbon by using, as a synthetic gas to be used in FT synthesis, a carbon dioxide-rich synthetic gas in which the molar ratio of hydrogen, carbon monoxide and carbon dioxide is delimited to a specific range, and maximizing the yield of the monocyclic aromatic compounds or the long-chain olefin compounds by specifying the composition of a catalyst to be used in the dehydrogenation and the temperature and pressure condition.