Patent classifications
C10G2300/1037
Method for producing high-octane motor gasolines of low-octane hydrocarbon fractions, fractions of gaseous olefins and oxygenates and a plant for the method embodiment
The invention relates to method and plant for the production of high-octane gasolines from raw hydrocarbon fractions, fractions of gaseous olefins and oxygenates. A method has been proposed, wherein the feedstock component flow is supplied to a unit for supplying flows to be treated, into the reactor, wherein the reaction is carried out in the presence of a zeolite-containing catalyst, high-octane gasoline is isolated by separation of the conversion product, while diverting simultaneously the reaction water and the exhaust gases. A reactor contains at least two reaction zones, between which there are further arranged means for mixing the reaction product from the previous reaction zone and the supplied oxygenates and olefin-containing feedstock, whereas using the unit for supplying flows there is supplied a flow oxygenates and olefin-containing feedstock and the flow of raw hydrocarbon fractions into the first reaction zone of the reactor, and the flow oxygenates and olefin-containing feedstock into the second reaction zone of the reactor.
CATALYST COMPRISING AN ACTIVE NICKEL PHASE IN THE FORM OF SMALL PARTICLES DISTRIBUTED IN A SHELL AND A NICKEL-COPPER ALLOY
Nickel and copper catalyst, and an alumina support: nickel distributed both in the core of and on a crust at the periphery of the support, crust thickness being 2% to 15% of catalyst diameter; nickel density ratio between the crust and the core greater than 3; crust contains more than 25% by weight of nickel element relative to total weight of nickel in the catalyst; mole ratio between nickel and copper is 0.5 to 5, at least one portion of nickel and copper is a nickel-copper alloy; nickel content in the nickel-copper alloy is 0.5% to 15% by weight of nickel element relative to total weight of the catalyst; size of the nickel particles in the catalyst is less than 7 nm.
Hydroisomerization catalysts based on Fe containing molecular sieves
The hydroisomerization of a paraffinic hydrocarbon feedstock obtained from renewable sources is effectively achieved by passing the feedstock in the presence of hydrogen over a hydroisomerization catalyst comprising a crystalline metal silicate molecular sieve, in which a portion of the crystalline framework contains iron.
Method of Hydrocarbon Pyrolysis and Device for Implementing Same
A method of oxidative pyrolysis involves heating hydrocarbon feedstock, heating a steam-oxygen mixture, combusting hydrocarbon feedstock in vapors of a steam-oxygen mixture in a special reactor, rapidly cooling the obtained products of incomplete combustion of chemical reactions in two steps, after which the cooled steam-gas mixture is directed to the fractionation unit. A hydrocarbons pyrolysis device has a steam-oxygen mixture and feedstock mixing chamber, a pyrolysis chamber and a coking reactor, a device for heating hydrocarbon feedstock, a device for heating steam-oxygen mixture coupled to a mixing chamber, a coking reactor having a device for supplying coolant to the pyrogas flow, a separation unit coupled to the coking reactor, a fractionation unit with an additional coolant supply device. Disposal of heavy oil residues by rapid coking with high economic efficiency and environmental safely while obtaining high-quality coke and producing aromatic compounds occurs without construction or additional installations.
INTEGRATED PROCESS FOR HYDROTREATING A RENEWABLE FEEDSTOCK WITH IMPROVED CARBON MONOXIDE MANAGEMENT
A process for hydrotreating a renewable feedstock with improved carbon monoxide management is disclosed. A mixture of renewable feedstock and hydrocarbon feedstock is treated in a hydrotreating reactor to produce a hydrotreated effluent stream and contacting the hydrotreated effluent stream with a water gas shift catalyst bed to produce a shift reactor effluent stream. The shift reactor effluent stream is passed to a cold separator to recover a cold vapor stream and recycling the cold vapor stream having reduced concentration of carbon monoxide to the hydrotreating zone. The subject matter disclosed provides an improved process and apparatus to reduce the accumulation of CO by converting CO present in the hydrotreated effluent stream to CO.sub.2 using the water shift gas reaction.
Method and system for obtaining polymerizable aromatic compounds
The invention relates to a process (100) for deriving polymerizable aromatic compounds having nine carbon atoms (S) in which a component mixture (B) is formed at least partially by steam cracking, in which the component mixture (B) is subjected to a workup (2, 3, 4, 5) comprising a gasoline removal (5) and thereafter is a compression (8) and a fractionation (10), and wherein one or more pyrolysis gasoline fractions (H, L) is or are formed in the gasoline removal (5) and/or the compression (8). The invention provides that a separation feed is formed which comprises predominantly exclusively pyrolysis gasoline from the or at least one of the pyrolysis gasoline fractions (H, L) and that the separation feed is subjected to a separation (7), wherein in the separation (7) at least one fraction (P) enriched in aromatic compounds having nine carbon atoms compared to the separation feed is formed. A corresponding plant likewise forms part of the subject matter of the invention.
Multi-stage process and device for treatment heavy marine fuel oil and resultant composition including ultrasound promoted desulfurization
A multi-stage process for reducing the environmental contaminants in an ISO8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process and a ultrasound treatment process as either a pre-treating step or post-treating step to the core process. The Product Heavy Marine Fuel Oil complies with ISO 8217 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.
METHOD AND DEVICE FOR TREATING OIL GAS
Provided is a method for treating an oil gas, which can realize high-efficiency separation for and recovery of gasoline components, C.sub.2, C.sub.3, and C.sub.4 components. The method first conducts separation of light hydrocarbon components from gasoline components, and then performs subsequent treatment on a stream rich in the light hydrocarbon components, during which it is no longer necessary to use gasoline to circularly absorb liquefied gas components, which significantly reduces the amount of gasoline to be circulated and reduces energy consumption throughout the separation process. Besides, in this method, impurities, such as H.sub.2S and mercaptans, in the stream rich in the light hydrocarbon components are removed first before the separation for the components. This ensures that impurities will not be carried to a downstream light hydrocarbon recovery section, thus avoiding corrosion issues caused by hydrogen sulfide in the light hydrocarbon recovery section.
PARAFFIN DEHYDROGENATION PROCESS AND APPARATUS
A process for recovering hydrogen from dehydrogenation reactor effluent is disclosed. A feed stream comprising hydrocarbons and hydrogen to a dehydrogenation reactor maintained at dehydrogenation conditions to provide a dehydrogenation reactor effluent. The dehydrogenation reactor effluent is passed to a cold box separation unit to provide a liquid hydrocarbon product stream and a recycle hydrogen stream. A return portion of the recycle hydrogen stream is passed to the reactor effluent compressor. The subject matter disclosed improved process and apparatus which enables the paraffin dehydrogenation reactor to run at reduced H.sub.2/HC ratio without requiring an investment in a resized compressor or resized turboexpanders or separators in the cold box.
Cracking C.SUB.8.+ fraction of pyoil
A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.