In an FCC apparatus and process structured packing should be located at the very top of the stripping section in an upper region. The lower region below the structural packing may be equipped with fluidization equipment such as stripping media distributors and one or more gratings. This arrangement enables stripping of entrained hydrocarbons off the incoming catalyst immediately upon entry into the stripping section allowing the entrained hydrocarbon to exit the stripping section with minimized residence time to minimize post-riser cracking. Revamp of stripping sections with tall stripping sections should conducted in this way to improve performance and reduce down-time for equipment installation.

A method for producing a diesel having improved cold flow properties, the method comprising the steps of introducing a crude oil to a distillation column, separating the crude oil in the distillation unit to produce a light gas oil, and a light vacuum gas oil, where the light gas oil has a T95% cut point in the range between 300 deg C. and 340 deg C., where the light vacuum gas oil has a T95% cut point in the range between 400 deg C. and 430 deg C., processing the light vacuum gas oil in the supercritical water unit to produce an upgraded vacuum gas oil, separating the upgraded vacuum gas oil in the fractionator to produce an upgraded light fraction, an upgraded light gas oil, and upgraded heavy fraction, introducing the upgraded light gas oil into a diesel pool, and blending the light gas oil into the diesel pool.

A catalyst system has been designed that disrupts the sedimentation process. The catalyst system achieves this by saturating key feed components before the feed components are stripped into their incompatible aromatic cores. The efficacy of this disruptive catalyst system is particularly evident in a hydrocracker configuration that runs in two-stage-recycle operation. The catalyst is a self-supported multi-metallic catalyst prepared from a precursor in the hydroxide form, and the catalyst must be toward the top level of the second stage of the two-stage system.

An extraction solvent comprised of one or more ethyleneamines having structure (I), (II), or (III): ##STR00001##
where R.sub.1-R.sub.6 can independently be H, C.sub.1-C.sub.4 linear or branched alkyl, amido (RRNCO), or hydroxyalkyl, where each R in the amido group independently H or C.sub.1 alkyl, and where x ranges from 1 to 6, may be contacted with a hydrocarbon stream to remove or extract non-acidic contaminants, such as thiophenes, benzothiophenes, alkyl sulfides, alkyl disulfides, mercaptans, aromatics, oxygenates, metals, olefins, and combinations thereof, from the hydrocarbon stream. The extraction solvent may include co-solvents and the hydrocarbon stream may be in gas and/or liquid form.

Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include one or more naphtha fractions from hydroprocessing zones within the battery limits, including vacuum residue hydrocracking, within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feeds to the gas oil steam cracker include gas oil range intermediates from the vacuum gas oil hydroprocessing zone and the vacuum residue hydrocracking zone.

Base stocks having Group III/III+ characteristics are prepared from certain advantageous crude oils via simplified process configurations and/or under less severe process conditions. Crude oils comprising a vacuum gas oil (VGO) fraction having a ratio of a sum of paraffin content plus 1-Ring species content to multi-ring species content that is greater than or equal to about 1.5 are advantageous in this context. Other parameters such as API gravity and crude compositional ranges may also be considered for identifying advantageous crudes. In some instances, advantageous crudes are processed into Group III base stocks via a process configuration in which the crude oil is directly supplied to a hydroprocessing unit.

The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.

An integrated process for maximizing recovery of LPG is provided. The process comprises providing a hydrocarbonaceous feed comprising naphtha, and a hydrogen stream to a reforming zone. The hydrocarbonaceous feed is reformed in the reforming zone in the presence of the hydrogen stream and a reforming catalyst to provide a reformate effluent stream. At least a portion of the reformate effluent stream and at least one stream comprising C.sub.6 hydrocarbons from one or more of a hydrocracking zone, an isomerization zone, and a transalkylation zone is passed to a debutanizer column of the reforming zone to provide a fraction comprising liquid petroleum gas (LPG) and a debutanizer column bottoms stream.

A composition of matter is provided comprising hierarchically ordered crystalline microporous material having well-defined long-range mesoporous ordering of cubic symmetry. The composition possesses mesopores having walls of crystalline microporous material and a mass of mesostructure between mesopores of crystalline microporous material. Long-range ordering is defined by presence of secondary peaks in an X-ray diffraction (XRD) pattern and/or cubic symmetry observable by microscopy.

An integrated process catalytically cracks whole light crude oil into light olefins, especially propylene and ethylene. The process is integrated with an adjacent conventional fluid catalytic cracking unit whereby the heavy liquid product mixture (light and heavy cycle oils) from whole crude oil cracking is mixed with vacuum gas oil (VGO) for further processing. The process comprises recycling total product fraction of light cracked naphtha (LCN) and mixing with fresh crude oil feed. High propylene and ethylene yields are obtained by cracking; the whole light crude oil and LCN in an FCC configuration using a mixture of FCC catalyst and ZSM-5 additive at a temperature between, that of conventional FCC and steam cracking.