Patent classifications
C10G2300/1088
Systems and processes to deolefinate aromatic-rich hydrocarbon streams
Systems and methods for reducing olefin concentration in a hydrocarbon stream comprising aromatic compounds and olefins, the method including supplying an aromatic-rich olefinic hydrocarbon stream; combining the aromatic-rich olefinic hydrocarbon stream with a catalyst; heating the aromatic-rich olefinic hydrocarbon stream and the catalyst to effect a reaction selected from the group consisting of: oxidation of olefins; hydration of olefins; and combinations of the same; separating an aqueous phase from a produced hydrocarbon phase; and separating C.sub.7 compounds from C.sub.8+ compounds in the produced hydrocarbon phase.
PROCESS FOR CRACKING AN OLEFINIC FEED COMPRISING DIOLEFINS AND MONOOLEFINS
A process for cracking an olefinic feed comprising diolefins and monoolefins is provided. The process comprises selectively hydrogenating the olefinic feed in a hydrogenation reactor to convert the diolefins to monoolefins to provide a hydrogenated effluent stream. The hydrogenated effluent stream is vaporized to provide a vaporized hydrogenated effluent stream. The vaporized hydrogenated effluent stream is passed to an olefin cracking reactor to provide a cracked olefin stream comprising C.sub.2 and C.sub.3 olefins. The cracked olefin stream is passed to a recycle column to provide one of an overhead vapor stream comprising C.sub.5 hydrocarbons or a side draw vapor stream comprising C.sub.6+. At least a portion of the overhead vapor stream or the side draw vapor stream is recycled to the olefin cracking reactor.
Method for sweetening an olefinic petrol of sulphide-type compounds
A process reducing sulfides R1-S-R2, with R1 and R2 methyl or ethyl, in a gasoline containing diolefins, mono-olefins and sulphur: A) contacting gasoline in mixture with a light gasoline cut recycled from C) and hydrogen in a reactor with catalyst A at least one VIb metal and at least one non noble group VIII metal on a support, producing effluent having diolefins and sulfides R1-S-R2, with R1 and R2 methyl or ethyl radicals lower than that that of the starting gasoline; B) the effluent from A) is sent into a fractionating column separating at the top a light gasoline cut containing hydrocarbons having less than 6 carbon atoms per molecule and at the bottom a heavy gasoline cut containing hydrocarbons having 6 and more than 6 carbon atoms per molecule; C) recycling a part of the light gasoline from B) to the reactor of A) with a recycle ratio 0.1 to 0.7.
Catalytic cracking process with increased production of a gasoline having a low olefin content and a high octane number
A catalytic cracking process includes the following steps: i) subjecting a heavy feedstock oil to flail catalytic cracking; ii) separating the catalytic cracking reaction product obtained from step i) to obtain a catalytic cracking gasoline and a catalytic cracking light cycle oil; iii) splitting the catalytic cracking gasoline to obtain a light gasoline fraction, a medium gasoline fraction and a heavy gasoline fraction; iv) subjecting the catalytic cracking light cycle oil to hydrogenation to obtain a hydrogenated light cycle oil); v) mixing a portion of the light gasoline fraction with at least a portion of the hydrogenated light cycle oil to obtain a mixed fraction; vi) subjecting the mixed fraction to catalytic cracking; and vii) subjecting a portion of the medium gasoline fraction to flail catalytic cracking. The process is capable of producing more catalytic cracking gasoline, reducing the olefin content of the catalytic cracking gasoline, and increasing its octane number.
Process and apparatus for hydrogenation
The present disclosure relates to hydrogenation reactions of different fractions in oil refining. It also relates to a process device applicable thereto for hydrogenation of various feedstocks, such as arrangements during campaign changes.
A METHOD FOR PRODUCING HIGH-OCTANE MOTOR GASOLINES OF LOW-OCTANE HYDROCARBON FRACTIONS, FRACTIONS OF GASEOUS OLEFINS AND OXYGENATES AND A PLANT FOR THE METHOD EMBODIMENT
The invention relates to method and plant for the production of high-octane gasolines from raw hydrocarbon fractions, fractions of gaseous olefins and oxygenates. A method has been proposed, wherein the feedstock component flow is supplied to a unit for supplying flows to be treated, into the reactor, wherein the reaction is carried out in the presence of a zeolite-containing catalyst, high-octane gasoline is isolated by separation of the conversion product, while diverting simultaneously the reaction water and the exhaust gases. A reactor contains at least two reaction zones, between which there are further arranged means for mixing the reaction product from the previous reaction zone and the supplied oxygenates and olefin-containing feedstock, whereas using the unit for supplying flows there is supplied a flow oxygenates and olefin-containing feedstock and the flow of raw hydrocarbon fractions into the first reaction zone of the reactor, and the flow oxygenates and olefin-containing feedstock into the second reaction zone of the reactor.
Methods and systems for separating olefins
Systems and methods for separating one or more olefins are provided. In one or more embodiments, the method for separating one or more olefins can include separating at least a portion of one or more C.sub.3 and heavier hydrocarbons from a hydrocarbon containing C.sub.1 to C.sub.20 hydrocarbons to provide a first mixture that can include methane, ethane, ethylene, and/or acetylene. At least a portion of the first mixture can be hydrogenated to convert at least a portion of the acetylene to ethane and ethylene. At least a portion of the methane can be separated from the hydrogenated mixture to provide a second mixture that can include ethane and ethylene. At least a portion of the ethylene can be separated from the second mixture to provide a first product that can include at least 95 mol % ethylene and a second product that can include at least 95 mol % ethane.
CONVERSION OF METHANOL TO GASOLINE WITH INTEGRATED PARAFFIN CONVERSION
Systems and methods are provided for conversion of methanol to gasoline in an integrated system that can also upgrade light paraffins generated by the methanol conversion process to aromatics. In some aspects, the integrated configuration can include integration of the stage for upgrading of light paraffins to aromatics into the product separation sequence for processing of the methanol conversion effluent. In other aspects, the integrated configuration can further include sharing a common catalyst between the methanol conversion stage and the stage for upgrading light paraffins to aromatics.
Process For The Removal Of Nitrogen-Containing Compounds From A Hydrocarbon Feed
Process for the removal of nitrogen-containing compounds from a hydrocarbon feed comprising at least one olefin selected from the C3, C4, C5 and optionally C6 olefins and mixtures thereof comprising solvent extraction comprising monitoring the degradation of the solvent.
METHOD OF INCREASING ALPHA-OLEFIN CONTENT
Implementations described herein generally relate to methods for purifying alpha-olefins. The alpha-olefins may be used to form drag reducing agents for improving flow of hydrocarbons through conduits, particularly pipelines. In one implementation, a method of increasing alpha-olefin content is provided. The method includes providing an olefin feedstock composition having an alpha-mono-olefin and at least one of a diolefin having an equal number of carbon atoms to the alpha-mono-olefin and/or a triolefin having an equal number of carbon atoms to the alpha-mono-olefin. The method further includes contacting the olefin feedstock composition with ethylene in the presence of a catalyst composition including an olefin metathesis catalyst. The method further includes reacting the olefin feedstock composition and ethylene at metathesis reaction conditions to produce an alpha-olefin product comprising the alpha-mono-olefin and alpha-olefins having fewer carbon atoms than the alpha-mono-olefin.