The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of the gas processing system.

A method for removing contaminants from a waste plastics pyrolysis stream containing the contaminants by introducing an effective amount of an additive thereto and separating the contaminants from the stream by a physical process, where suitable additives include, but are not necessarily limited to, crude oil demulsifiers, crude oil wax control additives, crude oil pour point reducers, dispersants/antifoulants, nanoscale metallic oxides, overbased metal oxide carbonates, and combinations thereof.

An ebullated bed hydroprocessing system is upgraded using a dual catalyst system that includes a heterogeneous catalyst and dispersed metal sulfide particles to improve the quality of vacuum residue. The improved quality of vacuum residue can be provided by one or more of reduced viscosity, reduced density (increased API gravity), reduced asphaltene content, reduced carbon residue content, reduced sulfur content, and reduced sediment. Vacuum residue of improved quality can be produced while operating the upgraded ebullated bed reactor at the same or higher severity, temperature, throughput and/or conversion. Similarly, vacuum residue of same or higher quality can be produced while operating the upgraded ebullated bed reactor at higher severity, temperature, throughput and/or conversion.

A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.

A method of separating hydrocarbons from an oil field production stream may include providing a production stream having a gas phase and a liquid phase, the production stream including oil, hydrocarbon gas, carbon dioxide, and water; substantially separating the gas phase from the liquid phase; separating the liquid phase into a stream composed substantially of oil and a stream substantially composed of water, the stream substantially composed of water containing carbon dioxide absorbed therein; pressurizing the water stream containing carbon dioxide absorbed therein; and injecting the pressurized water stream containing carbon dioxide absorbed therein to a downhole injection location; the method may include operating each step at a pressure above 150 psig.

A process for reducing the environmental contaminants in a ISO8217 compliant Feedstock Heavy Marine Fuel Oil, the process involving: mixing a quantity of the Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil is compliant with ISO 8217 for residual marine fuel oils and the Environmental Contaminants, which are selected from the group consisting of: a sulfur; vanadium, nickel, iron, aluminum and silicon and combinations thereof, have concentration less than 0.5 wt %. The Product Heavy Marine Fuel Oil can be used as or as a blending stock for an ISO 8217 compliant, IMO MARPOL Annex VI (revised) compliant low sulfur or ultralow sulfur heavy marine fuel oil.

A computer-implemented method includes controlling water separation in a hydrocarbon stream flowing through a separator train including one or more separator vessels located upstream of a dehydrator by manipulating a demulsifier flowrate added to the separator train by: receiving data from a real-time process test of the separation train, estimating model fit parameters to the data to generate a water separation profile (WSP) correlating water draw-off and demulsifier flowrate for the separation train, determining a maximum and a minimum demulsifier flowrate from the WSP, receiving, from an operator, a separation performance for a target water separation value entering the dehydrator downstream from the separator train, and adjusting the demulsifier flowrate according to the WSP to achieve the target water separation entering the dehydrator.

An adsorbent composition for removing chlorides from hydrocarbon includes an adsorbent matrix and a metallic component. The metallic component forms an intimate complex with the adsorbent matrix. The adsorbent composition is characterized by pore size in the range of 20 Å to 120 Å. It is found that the amount of chlorides removed by the adsorbent composition from the hydrocarbon is in the range of 0.020 wt. % to 0.047 wt. %.

Marine diesel fuel/fuel blending component compositions and fuel oil/fuel blending component compositions are provided that are derived from crude oils having high naphthenes to aromatics volume and/or weight ratios and a low sulfur content. In addition to having a high naphthenes to aromatics ratio, a low sulfur content, and a low but substantial content of aromatics, such fuels and/or fuel blending components can have a reduced or minimized carbon intensity relative to fuels derived from conventional sources. The unexpected ratio of naphthenes to aromatics contributes to the fuels and/or fuel blending components further having additional unexpected properties, including low density, low kinematic viscosity, and/or high energy density.

A process for upgrading a heavy oil includes passing heavy oil and disulfide oil to a thermal cracking system that includes a thermal cracking unit and a cracker effluent separation system downstream of the thermal cracking unit and thermally cracking at least a portion of the heavy oil in the presence of the disulfide oil in the thermal cracking unit to produce solid coke and a cracking effluent comprising reaction products. The reaction products include one or more liquid reaction products, one or more gaseous reaction products, or both. The presence of the disulfide oil in the thermal cracking unit promotes conversion of hydrocarbons from the heavy oil to the liquid reaction products, the gaseous reaction products, or both relative to the production of the solid coke.