Patent classifications
C10G2300/4006
Circular economy for plastic waste to polyethylene and chemicals via refinery crude unit
Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization or for normal alpha olefins. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit in a refinery from which is recovered a straight run naphtha fraction (C.sub.5-C.sub.8) or a propane/butane (C.sub.3-C.sub.4) fraction. The straight run naphtha fraction, or propane and butane (C.sub.3-C.sub.4) fraction, is passed to a steam cracker for ethylene production. The ethylene is converted to normal alpha olefin and/or polyethylene. Also, a heavy fraction from the pyrolysis reactor can be combined with a heavy fraction of normal alpha olefin stream recovered from the steam cracker. The combined heavy fraction and heavy fraction of normal alpha olefin stream can be passed to a wax hydrogenation zone to produce wax.
Circular economy for plastic waste to polypropylene and lubricating oil via refinery FCC and isomerization dewaxing units
A continuous process for converting waste plastic into recycle for polypropylene polymerization is provided. The process integrates refinery operations to provide an effective and efficient recycle process. The process comprises selecting waste plastics containing polyethylene and polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a refinery FCC unit, from which is recovered a liquid petroleum gas C.sub.3 olefin/paraffin mixture. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with a propane/propylene splitter. The C.sub.3 olefin fraction is passed to a propylene polymerization reactor. The C.sub.3 paraffin fraction is optionally passed to a dehydrogenation unit to produce additional propylene and then the resulting C.sub.3 olefin is passed to a propylene polymerization reactor. The heavy fraction of pyrolyzed oil is passed to an isomerization dewaxing unit to produce a lubricating base oil.
Processes for producing alcohols from biomass and further products derived therefrom
Processes for producing alcohols from biomass are provided. The processes utilize supercritical methanol to depolymerize biomass with subsequent conversion to a mixture of alcohols. In particular the disclosure relates to continuous processes which produce high yields of alcohols through recycling gases and further employ dual reactor configurations which improve overall alcohol yields. Processes for producing higher ethers and olefins from the so-formed alcohols, through alcohol coupling and subsequent dehydration are also provided. The resulting distillate range ethers and olefins are useful as components in liquid fuels, such as diesel and jet fuel.
PROCESS FOR THE PREPARATION OF OLEFINS, COMPRISING HYDROTREATMENT, DE-ASPHALTING, HYDROCRACKING AND STEAM CRACKING
The present invention relates to a process for producing olefins from a hydrocarbon feedstock 11 with a sulfur content of at least 0.1 weight %, an initial boiling point of at least 180° C. and a final boiling point of at least 600° C.
PROCESS CONTROL SYSTEMS AND METHODS FOR SIMULTANEOUS CRUDE OIL DEHYDRATION, DESALTING, SWEETENING, AND STABILIZATION WITH INDIRECT RECYCLE HEATING
Systems and methods for crude oil separations including degassing, dewatering, desalting, and stabilization, one method including separating crude oil into a crude oil off-gas and a partially degassed crude oil output; compressing the crude oil off-gas; applying the compressed crude oil off-gas for indirect heating of the partially degassed crude oil output; further heating the partially degassed crude oil output indirectly with compressed low pressure gas; directly mixing with the partially degassed crude oil output a compressed atmospheric pressure gas; separating from the partially degassed crude oil output a low pressure gas for use in the step of further heating; and separating from the partially degassed crude oil output an atmospheric pressure gas for use in the step of directly mixing.
Methods for producing long-chain hydrocarbon molecules using heat source
Provided is a method for producing organic molecules having at least two carbon atoms chained together by the reaction of a hydrogen-containing source, a carbon-containing source and an optional nitrogen-containing source in the presence of a nanostructure or nanostructures, wherein the reaction is initiated by heat.
Process for producing light olefins and low-sulfur fuel oil components
A process for producing propylene and a low-sulfur fuel oil component, comprising the steps of: i) contacting a hydrocarbon-containing feedstock oil with a catalytic conversion catalyst for reaction under effective conditions in a catalytic conversion reactor in the absence of hydrogen to obtain a reaction product comprising propylene; ii) separating the reaction product from step i) to obtain a catalytic cracking distillate oil, and iii) subjecting the catalytic cracking distillate oil to hydrodesulfurization to obtain a low-sulfur hydrogenated distillate oil suitable for use as a fuel oil component. The process can greatly improve the propylene selectivity and propylene yield while producing more fuel oil components, significantly reduce the yield of dry gas and coke, and thus has better economic and social benefits.
PROCESS FOR THE PREPARATION OF OLEFINS, COMPRISING DE-ASPHALTING, HYDROCRACKING AND STEAM CRACKING
The present invention relates to a process for producing olefins from a hydrocarbon feedstock 11 having a sulfur content of at least 0.1 weight %, an initial boiling point of at least 180° C. and a final boiling point of at least 600° C.
PROCESS AND SYSTEM FOR HYDROTREATING DEOILED ASPHALT
Described are a process and a system for hydrotreating a deoiled asphalt. The process includes: (2) introducing a deoiled asphalt and an aromatics-containing stream into a first reaction unit for hydrogenation reaction, wherein the first reaction unit comprises a mineral-rich precursor material and/or a hydrogenation catalyst, and the first reaction unit is a fixed bed hydrogenation unit; (21) fractionating the liquid-phase product from the first reaction unit to provide a first light component and a first heavy component; (31) introducing the first light component into a second reaction unit for reaction, to provide a gasoline component, a diesel component and/or a BTX feedstock component; and (32) introducing the first heavy component to a delayed coking unit for reaction; or using the first heavy component as a low sulfur ship fuel oil component.
INTEGRATED SLURRY HYDROPROCESSING CATALYST AND PROCESS
An integrated catalytic process for upgrading a feed oil comprises the steps of introducing a catalyst precursor solution to a supercritical water (SCW) process unit, where the catalyst precursor solution comprises a catalyst precursor dissolved in liquid water; introducing a feed water to the SCW process unit; introducing the feed oil to the SCW process unit; treating the catalyst precursor solution, the feed water, and the feed oil in the SCW process unit to produce a SCW effluent, where the catalyst precursor is converted to catalyst particles; separating the SCW effluent in a separator unit to produce a SCW distillate product, a SCW residue product; introducing the SCW residue product to a slurry hydroprocessing unit, where the SCW residue product comprises the catalyst particles; treating the SCW residue product and the hydrogen gas in the slurry hydroprocessing unit to produce a product gas stream and an upgraded oil product.