Patent classifications
C10G2300/4025
METHOD FOR PRODUCING LIQUID HYDROCARBON FUEL
The present invention relates to a method for producing a liquid hydrocarbon fuel comprising a first reaction step and a second reaction step given below: (1) a first reaction step: hydrocracking a raw material oil in the presence of a hydrocracking reaction catalyst at a feeding pressure of hydrogen of from 0.2 to 0.95 MPa, a liquid hourly space velocity of a liquid volume of the raw material oil of from 0.05 to 0.5 hr.sup.−1, and a ratio of a flow rate of the hydrogen to a flow rate of the raw material oil of from 100 to 1,000 NL of the hydrogen per 1 L of the raw material oil; and (2) a second reaction step: hydrogenating the cracked solution in the presence of a hydrogenation reaction catalyst at a feeding pressure of hydrogen of from 0.2 to 0.95 MPa, a liquid hourly space velocity of a liquid volume of the raw material oil of from 0.2 to 5 hr.sup.−1, and a ratio of a flow rate of the hydrogen to a flow rate of the raw material oil of from 100 to 1,000 NL of the hydrogen per 1 L of the raw material oil. According to the present invention, a desired liquid hydrocarbon fuel can be produced by carrying out a combination of the hydrocracking reaction and the hydrogenation reaction of a raw material oil such as fats and oils in a given composition by feeding a low-pressure hydrogen of nearly a normal pressure.
CATALYTIC CRACKING GASOLINE PREHYDROGENATION METHOD
The invention relates to a catalytic cracking gasoline prehydrogenation method. Thiol etherification and double bond isomerization reactions are carried out on catalytic cracking gasoline through a prehydrogenation reactor. The reaction conditions are as follows: the reaction temperature is between 80° C. and 160° C., the reaction pressure is between 1 MPa and 5 MPa, the liquid-volume hourly space velocity is from 1 to 10 h.sup.−1, and the hydrogen-oil volume ratio is (3-8):1; a prehydrogenation catalyst comprises a carrier and active ingredients, the carrier contains an aluminium oxide composite carrier with a macroporous structure and one or more of ZSM-5, ZSM-11, ZSM-12, ZSM-35, mordenite, amorphous form aluminum silicon, SAPO-11, MCM-22, a Y molecular sieve and a beta molecular sieve, the surface of the carrier is loaded with one or more of the active ingredients cobalt, molybdenum, nickel and tungsten; based on oxides, the content of the active ingredients is between 0.1% and 15.5%.
Two-step hydrocracking process for the production of naphtha comprising a hydrogenation step carried out upstream of the second hydrocracking step
The present invention is based on the use of a two-step hydrocracking process for the production of naphtha, comprising a step of hydrogenation placed upstream of the second hydrocracking step, the hydrogenation step treating the unconverted liquid fraction separated in the distillation step in the presence of a specific hydrogenation catalyst. Furthermore, the hydrogenation step and a second hydrocracking step are carried out under specific operating conditions and in particular under temperature conditions that are very specific with respect to one another.
Process for the production of petrochemical feedstock and high octane gasoline from middle distillates
A process for upgrading light cycle oil (LCO) to a high octane gasoline and a high aromatic feedstock for aromatic complex, by utilizing fluid catalytic cracking (FCC) is disclosed. FCC cracks unconverted diesel range stream from a hydrocracker to a high octane gasoline. This process further improves the quality (e.g., research octane number (RON), and Sulfur) of gasoline by utilizing FCC and hydrocracking process.
SYSTEM AND PROCESS FOR STEAM CRACKING AND PFO TREATMENT INTEGRATING SELECTIVE HYDROGENATION AND SELECTIVE HYDROCRACKING
A process for treatment of PFO from a steam cracking zone includes selectively hydrogenating PFO or a portion thereof for conversion of polyaromatics compounds contained in the PFO into aromatic compounds with one benzene ring to produce a selectively hydrogenated stream. The selectively hydrogenated stream is selectively hydrocracked for selective ring opening and dealkylation to produce a selectively hydrocracked BTX+ stream. The selectively hydrocracked BTX+ stream is separated into BTX compounds. Optionally the PFO is separated into a first stream containing C9+ aromatics compounds with one benzene ring, and a second stream containing C10+ aromatic compounds, whereby the first stream containing C9+ aromatics compounds with one benzene ring is passed to the selective hydrocracking step, and the feed to the selective hydrogenation step comprises all or a portion of the second stream containing C10+ aromatic compounds.
System and process for steam cracking and PFO treatment integrating selective hydrogenation and selective hydrocracking
A process for treatment of PFO from a steam cracking zone includes selectively hydrogenating PFO or a portion thereof for conversion of polyaromatics compounds contained in the PFO into aromatic compounds with one benzene ring to produce a selectively hydrogenated stream. The selectively hydrogenated stream is selectively hydrocracked for selective ring opening and dealkylation to produce a selectively hydrocracked BTX+ stream. The selectively hydrocracked BTX+ stream is separated into BTX compounds. Optionally the PFO is separated into a first stream containing C9+ aromatics compounds with one benzene ring, and a second stream containing C10+ aromatic compounds, whereby the first stream containing C9+ aromatics compounds with one benzene ring is passed to the selective hydrocracking step, and the feed to the selective hydrogenation step comprises all or a portion of the second stream containing C10+ aromatic compounds.
PROCESS FOR PRODUCING OLEFINS AND AROMATICS THROUGH HYDRO PYROLYSIS AND COKE MANAGEMENT
Systems and processes for producing olefins and aromatics. A process can include contacting a first hydrocarbon feed with a catalyst and a hydrogen source under conditions sufficient to produce a used catalyst and an intermediate stream containing olefins and aromatics, and contacting the used catalyst with the intermediate stream and a coke precursor feed to produce a spent coked catalyst and a products stream comprising additional olefins and aromatics.
INTEGRATED METHOD AND APPARATUS FOR CATALYTIC CRACKING OF HEAVY OIL AND PRODUCTION OF SYNGAS
The present disclosure provides an integrated method and apparatus for catalytic cracking of heavy oil and production of syngas. A cracking-gasification coupled reactor having a cracking section and a gasification section is used as a reactor in the method. A heavy oil feedstock is fed into a cracking section to contact with a bed material in a fluidized state that contains a cracking catalyst, a catalytic cracking reaction is conducted under atmospheric pressure to obtain light oil-gas and coke. The coke is carried downward by the bed material into a gasification section to conduct a gasification reaction to generate syngas; the syngas goes upward into the cracking section to merge with the light oil-gas, and is guided out from the coupled reactor and enter a gas-solid separation system. Oil-gas fractionation is performed to a purified oil-gas product output from the gas-solid separation system to collect light oil and syngas products.
Renewable Jet Production
Systems and methods are provided for production of renewable jet fuel and/or jet fuel blending component fractions. The systems and methods provide for formation of jet boiling range fractions via hydrodeoxygenation and catalytic dewaxing of bio-derived feeds. The systems and methods for reducing or minimizing recycle and/or forming only a jet boiling range product and a lower boiling range product can be facilitated based on selection of a suitable feedstock and/or based on selection of suitable reaction conditions and catalyst for the catalytic dewaxing.
Process for extracting gasoline from a gas containing condensable hydrocarbons
The present invention relates to the extraction of gasoline from a gas G, with (a) a step of extracting gasoline from the gas to be treated comprising methanol GM obtained from step (d), (b) a step of separating said fluid GL1 partially condensed in step (a), producing a first aqueous liquid phase Al , a first liquid phase H1 of hydrocarbon(s) a gaseous phase G1 obtained from the gas G; (c) a step of contacting a portion of the gas G to be treated with said first aqueous liquid phase A1, producing a second aqueous liquid phase A2, a gaseous phase of gas to be treated comprising methanol GM; (d) a step of mixing said gaseous phase of gas to be treated comprising methanol GM with the remainder of the gas G to be treated, producing a gas to be treated comprising methanol GM, (e) a step of stabilizing said first liquid phase H1 of hydrocarbon(s).