Patent classifications
C10G2300/4081
PROCESS FOR HYDROTREATING A FEED STREAM COMPRISING A BIORENEWABLE FEEDSTOCK WITH TREATMENT OF AN OFF-GAS STREAM
A process for hydrotreating a feed stream comprising a biorenewable feedstock is disclosed. The process comprises hydrotreating the feed stream in the presence of a hydrotreating hydrogen stream and a hydrotreating catalyst to provide a hydrotreated stream. The hydrotreated stream is separated into a hydrotreated liquid stream and a hydrotreated gas stream. The hydrotreated liquid stream is subjected to stripping to provide a stripper off-gas stream. At least a portion of the stripper off-gas stream is contacted with a caustic stream to provide a sulfur-lean gas stream and a sulfur-rich caustic stream. The sulfur-rich caustic stream is further treated to provide a treated gas stream.
PROCESS FOR RECYCLING SUPPLEMENTAL FUEL FOR REGENERATING CATALYST
A composition of fuel gas that when mixed with spent catalyst and oxygen has an induction time that allows bubbles to break up while combusting in the regenerator. Bubble breakage in a dense bed avoids generation of a flame that can generate hot spots in the regenerator which can damage equipment and catalyst. The fuel gas can be obtained from paraffin dehydrogenation products, so it can sustain operation of the unit even in remote locations. Heavier streams can be mixed with lighter streams to obtain a fuel gas composition with a desirable induction time to avoid such hot spots. Mixing of a depropanizer bottom stream and/or deethanizer overhead stream with lighter gas streams such as cold box light gas or PSA tail gas can provide the desired fuel gas composition.
Process for extracting gasoline from a gas containing condensable hydrocarbons
The present invention relates to the extraction of gasoline from a gas G, with (a) a step of extracting gasoline from the gas to be treated comprising methanol GM obtained from step (d), (b) a step of separating said fluid GL1 partially condensed in step (a), producing a first aqueous liquid phase A1, a first liquid phase H1 of hydrocarbon(s) a gaseous phase G1 obtained from the gas G; (c) a step of contacting a portion of the gas G to be treated with said first aqueous liquid phase A1, producing a second aqueous liquid phase A2, a gaseous phase of gas to be treated comprising methanol GM′; (d) a step of mixing said gaseous phase of gas to be treated comprising methanol GM′ with the remainder of the gas G to be treated, producing a gas to be treated comprising methanol GM, (e) a step of stabilizing said first liquid phase H1 of hydrocarbon(s).
Atmospheric-vacuum Heat Exchange System Having Coil-Wound Heat Exchangers, and Heat Exchange Process
An atmospheric-vacuum heat exchange system with a winding-tube heat exchanger, has a first and second heat exchanging group; a primary distillation tower (4) or flash tower; an atmospheric furnace (5); an atmospheric tower (6); a vacuum furnace (7) and a vacuum tower (8); each winding-tube heat exchanger has a shell-pass cylinder (370), a first and second shell-pass connecting tube (371,372), a first and second tube plate (330,340), a plurality of first and second tube box (310,320), a plurality of heat exchange tubes (360) spirally wounded with multiple spiral tube layers; the number of the first and second tube box (310, 320) are respectively N, and each spiral tube layer has N group(s) of the wounded heat exchange tubes (360), N is a natural number greater than or equal to 1. The loss of heat exchanger is reduced.
METHOD AND APPARATUS FOR PRODUCING GREEN OLEFINS AND GREEN GASOLINE FROM RENEWABLE SOURCES
A method for producing green olefins and green gasoline from renewable sources, the method including: providing CO.sub.2 and hydrogen as feed to produce methanol in a methanol reactor, to produce an MTO reaction effluent, reacting the MTO reaction effluent in a plurality of separation columns to separate hydrocarbons, wherein the plurality of separation columns includes a Deethanizer column, a Depropanizer column, and a Debutanizer column, hydrogenating a fraction of separated hydrocarbons in the Debutanizer column with the hydrogen in a hydrogenation reactor, wherein the fraction of separated hydrocarbons from the Debutanizer column includes C.sub.5+ hydrocarbons; producing the green gasoline and Liquefied Petroleum Gas (LPG) by stabilizing the hydrogenated hydrocarbons in a gasoline stabilizer column; and producing the olefins by separating ethylene from C.sub.2 hydrocarbons using a C.sub.2 splitter column and by separating propylene from C.sub.3 hydrocarbons using a C.sub.3 splitter column.
SLURRY HYDROCONVERSION WITH PITCH RECYCLE
Systems and methods are provided for performing slurry hydroconversion of feeds that include substantial amounts of 1050° F+ (566° C+) components. The productivity of the slurry hydroconversion reaction is improved by recycling slurry hydroconversion pitch or bottoms back to the slurry hydroprocessing reaction system. The mass flow rate of the recycle stream can correspond to 50% or more of the mass flow rate of the fresh feed to the reaction system, and the recycle stream can include more than 50 wt % of 566° C+ components. It has been discovered that using a substantial recycle stream composed of a majority of unconverted 566° C+ bottoms can increase the productivity of the slurry hydroprocessing reaction system when operating at a net conversion relative to 524° C (975° F) of less than 90 wt %. Additionally, by using a recycle stream composed of a majority of 566° C+ components, the amount of lower boiling components (in the heavy hydrocarbon feed and/or in the recycle stream) that are exposed multiple times to the slurry hydroprocessing environment is reduced or minimized This can allow for formation of slurry hydroconversion products with increased amounts of vacuum gas oil boiling range components.
CATALYST CONFIGURATION FOR RENEWABLE JET PRODUCTION
This application relates to methods and systems that utilize catalytic methods to produce jet fuel such as hydrocarbons with carbons numbers from C9 to C16. Disclosed herein is an example method of producing renewable jet fuel. Examples embodiments of the method include hydrocracking a biofeedstock by reaction with hydrogen in the presence of a hydrocracking catalyst to form a hydrocracked biofeedstock. Examples embodiments of the method further include isomerizing at least a portion of the hydrocracked biofeedstock in the presence of a dewaxing catalyst to form a dewaxed effluent. Examples embodiments of the method further include separating the dewaxed effluent to form a renewable jet fuel product.
INTEGRATED PYROLYSIS AND GASIFICATION OF BIOMASS
Systems and methods are provided for integrated pyrolysis and gasification of a biomass feed, either as a separate feed or under co-processing conditions. The integrated pyrolysis and gasification can be performed using any convenient reactor configuration, such as fluidized coking reactor configuration or a fluid catalytic cracking reactor configuration. The biomass feed can initially by pyrolyzed to form liquid products, gas phase products, and char. The char can then be used as the input feed to gasification. In aspects where the biomass feed is co-processed, the biomass can be co-processed with a co-feed that is suitable for processing under fluidized coking conditions or other pyrolysis conditions, such as a conventional fluidized coking feedstock.
PLASTIC BLENDING METHODS, SYSTEMS, AND APPPARATUS FOR EFFICIENTLY REDUCING CARBON FOOTPRINTS IN REFINING SYSTEMS AND PETROCHEMICAL PROCESSING SYSTEMS
Aspects of the present disclosure relate to methods, systems, and apparatus for efficiently reducing carbon footprints in refining systems and petrochemical processing systems. In one aspect, a plastic powder feedstock is blended into a feedstock of a processing system to re-use plastic and reduce carbon footprints. In one implementation, a method of blending plastics into a processing system includes pulverizing a plastic supply to a plastic stock having a granule size that is within a range of 7 nanometers to 10 nanometers. The method includes separating the plastic stock to remove a portion having a granule size that is outside of the range of 7 nanometers to 10 nanometers and generate a plastic feedstock. The method includes blending the plastic feedstock into a feedstock of the processing system to generate a blended feedstock, and processing the blended feedstock.
PROCESS TO PREPARE PROPYLENE
The invention is directed to a process to prepare propylene from a mixture of hydrocarbons having an olefin content of between 5 and 50 wt. % and boiling for more than 90 vol. % between 35 and 280 ?C or from a hydrocarbon feed comprising paraffins, naphthenics and/or aromatics and optionally up to 10 wt. % of olefins, by first contacting the feed with a low acidic density cracking catalyst in a reactor, separating propylene and subsequently contacting the residue with a high acidic density cracking catalyst in a reactor at a more elevated temperature, separating propylene and recycling the residue to first and second cracking reactors. Aromatics may be added to first and second cracking step to improve cycle length.