A system for upgrading heavy hydrocarbon feeds, such as crude oil, include a hydrotreating unit, a hydrotreated effluent separation system, a solvent-assisted adsorption system, and a hydrocracking unit. Processes for upgrading heavy hydrocarbon feeds include hydrotreating the hydrocarbon feed to produce a hydrotreated effluent that includes asphaltenes, separating the hydrotreated effluent into a lesser boiling hydrotreated effluent and a greater boiling hydrotreated effluent comprising the asphaltenes, combining the greater boiling hydrotreated effluent with a light paraffin solvent to produce a combined stream, adsorbing the asphaltenes from the combined stream to produce an adsorption effluent, and hydrocracking the lesser boiling hydrotreated effluent and at least a portion of the adsorption effluent to produce a hydrocracked effluent with hydrocarbons boiling less than 180° C. The systems and processes increase the hydrocarbon conversion and yield of hydrocarbons boiling less than 180° C.

Provided is a system for continuous processing of heavy fuel oil from recycling waste oil and the processing residues of crude oil into useful products including means for feeding waste oil; at least one hot-gas filter, at least one condenser, at least one rotating kiln including an outer stationary jacket which forms a heating channel, and an inner rotating reactor, and means for removing solid coke from the rotating reactor. The at least one hot gas filter is configured to separate a naphtha/gasoil fraction after the processing of the heavy fuel oil from a soft coke fraction. The rotating reactor is configured to recover a solid coke fraction comprising high contaminant content. The invention further relates to a process for continuous processing of heavy fuel oil from recycling waste oil and the processing residues of crude oil into useful products, preferably with the system of the invention. Moreover, the invention relates to use of the products and waste products produced with the process and system of the invention.

An ebullated bed hydroprocessing system is upgraded and operated at modified conditions using a dual catalyst system to produce less fouling sediment. The less fouling sediment produced by the upgraded ebullated bed reactor reduces the rate of equipment fouling at any given sediment production rate and/or concentration compared to the sediment produced by the ebullated bed reactor prior to upgrading. In some cases, sediment production rate and/or concentration are maintained or increased, after upgrading the ebullated bed reactor, while equipment fouling is reduced. In other cases, sediment production rate and/or concentration are increased, after upgrading the ebullated bed reactor, without increasing equipment fouling. In some cases, sediment production rate and/or concentration are decreased by a given percentage, after upgrading the ebullated bed reactor, and the rate of equipment fouling is decreased by a substantially greater percentage.

Systems and methods for enhancing the processing of hydrocarbons in a FCC unit by introduction of the coked FCC catalyst from the FCC reactor and a renewable feedstock to the FCC regenerator to facilitate regeneration of the coked FCC catalyst. The renewable feedstock can contain biomass-derived pyrolysis oil. The biomass-derived pyrolysis oil and coke from the coked FCC catalyst are oxidized by oxygen to provide a regenerated catalyst that is recycled to the FCC reactor.

Systems and methods for steam and catalytic cracking of a hydrocarbon inlet stream comprising hydrocarbons. Systems and methods can include a catalyst feed stream, where the catalyst feed stream comprises a fluid and a heterogeneous catalyst, the heterogeneous catalyst operable to catalyze cracking of the hydrocarbons on surfaces of the heterogeneous catalyst a steam feed stream, where the steam feed stream is operable to effect steam cracking of the hydrocarbons, and where the steam feed stream decreases coking of the heterogeneous catalyst; and a downflow reactor, where the downflow reactor is operable to accept and mix the hydrocarbon inlet stream, the catalyst feed stream, and the steam feed stream, where the downflow reactor is operable to produce light olefins by steam cracking and catalytic cracking, and where the downflow reactor is operable to allow the heterogeneous catalyst to flow downwardly by gravity.

An organometallic chemistry-based compound for preventing coke formation in a hydrocarbon fluid system. The organometallic chemistry-based compound includes a coordination complex that interrupts an autoxidative pathway of coke formation. A component and a system for mitigating coke formation during delivery or circulation of a hydrocarbon fluid. The component includes a contact surface configured to be in contact with the hydrocarbon fluid. The contact surface is functionalized with an inhibitor ligand to form an inhibitor ligand-functionalized surface. The inhibitor ligand-functionalized surface interrupts an autoxidative pathway of coke formation.

Provided is a system for continuous processing of heavy fuel oil from recycling waste oil and the processing residues of crude oil into useful products including means for feeding waste oil; at least one hot-gas filter, at least one condenser, at least one rotating kiln including an outer stationary jacket which forms a heating channel, and an inner rotating reactor, and means for removing solid coke from the rotating reactor. The at least one hot gas filter is configured to separate a naphtha/gasoil fraction after the processing of the heavy fuel oil from a soft coke fraction. The rotating reactor is configured to recover a solid coke fraction comprising high contaminant content. The invention further relates to a process for continuous processing of heavy fuel oil from recycling waste oil and the processing residues of crude oil into useful products, preferably with the system of the invention. Moreover, the invention relates to use of the products and waste products produced with the process and system of the invention.

This disclosure relates to a procedure, which through the application of a catalyst in homogeneous phase, allows the transformation of heavy hydrocarbons (vacuum residue, atmospheric residue, heavy and extra-heavy crudes) into hydrocarbons of lower molecular weight, characterized because after its application, the hydrocarbons obtain greater API gravity, lower kinematic viscosity and different composition by hydrocarbon families (SARA) that increases the proportion of saturated and aromatic resins and asphalts. The sulphur and nitrogen content is also reduced, resulting in higher yields to high commercial value distillates and a lighter product as compared to the original crude.

The present invention provides a process for producing liquid hydrocarbon products from a biomass, biomass containing and/or biomass-derived feedstock, said process comprising the steps of: a) contacting the feedstock with a first hydropyrolysis catalyst composition and molecular hydrogen in a first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600° C. and a pressure in the range of from 0.50 to 7.50 MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H.sub.2O, H.sub.2, CO.sub.2, CO, C.sub.1-C.sub.3 gases, char and catalyst fines; b) removing said char and catalyst fines from said product stream; c) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst compositions and of the H.sub.2O, CO.sub.2, CO, H.sub.2, and C.sub.1-C.sub.3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H.sub.2O, CO, CO.sub.2, and C.sub.1-C.sub.3 gases, wherein one or more of the first hydropyrolysis catalyst composition and the hydroconversion catalyst composition is prepared by a process comprising combining a porous support with one or more catalytically active metals selected from Group VI and Group VIII of the Periodic Table, thereby forming a catalyst precursor having a volatile content, and reducing the volatile content of the catalyst precursor in one or more steps, wherein at least one volatile content reduction step is performed in the presence of one or more sulfur containing compounds; and wherein the catalyst precursor does not reach calcining temperatures prior to said at least one combined volatile content reduction-sulfurizing step.

The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to delayed coking and then oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated in to the integrated process.