The present invention concerns a process for the manufacture of one or more useful products comprising: gasifying a carbonaceous feedstock comprising waste materials and/or biomass in a gasification zone to generate a raw synthesis gas; optionally partially oxidising the raw synthesis gas in a partial oxidation zone to generate partially oxidised raw synthesis gas; supplying at least a portion of the, optionally partially oxidised, raw synthesis gas to a clean-up zone to remove contaminants and provide a clean synthesis gas; optionally shifting the hydrogen to carbon monoxide ratio of the clean synthesis gas in a hydrogen to carbon monoxide ratio shifting zone to generate shifted clean synthesis gas; supplying the, optionally shifted, clean synthesis gas to a first further reaction train to generate at least one first useful product and a tailgas; optionally upgrading the first useful product in a second further reaction train to generate a second useful product and a light gas fraction; and diverting selectively on demand a portion of at least one of the carbonaceous feedstock, the clean synthesis gas, the tailgas and the light gas fraction to heat or power generation within the process, in response to external factors to control the carbon intensity of the overall process and enable GHG emission savings.

The present invention concerns a process for the manufacture of one or more useful products comprising: gasifying a carbonaceous feedstock comprising waste materials and/or biomass in a gasification zone to generate a raw synthesis gas; optionally partially oxidising the raw synthesis gas in a partial oxidation zone to generate partially oxidised raw synthesis gas; supplying at least a portion of the, optionally partially oxidised, raw synthesis gas to a clean-up zone to remove contaminants and provide a clean synthesis gas; optionally shifting the hydrogen to carbon monoxide ratio of the clean synthesis gas in a hydrogen to carbon monoxide ratio shifting zone to generate shifted clean synthesis gas; supplying the, optionally shifted, clean synthesis gas to a first further reaction train to generate at least one first useful product and a tailgas; optionally upgrading the first useful product in a second further reaction train to generate a second useful product and a light gas fraction; and diverting selectively on demand a portion of at least one of the carbonaceous feedstock, the clean synthesis gas, the tailgas and the light gas fraction to heat or power generation within the process, in response to external factors to control the carbon intensity of the overall process and enable GHG emission savings.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

Provided is a carbonizing furnace capable of improving combustion efficiency of combustible gas generated by combustion of organic waste and of improving carbonization efficiency of organic waste by appropriately controlling the temperature of carbide. Provided is a pyrolytic furnace in which heating gas can be suppressed from outflowing to the outside from a gap between the upper surface of the body part of the pyrolytic furnace and the outer circumferential surface of a reaction tube where a pyrolysis reaction between carbide and a gasification agent is caused, and in which the temperature of a region where the pyrolysis reaction is caused can be suppressed from being reduced. Provided is a water gas generation system which improves thermal efficiency without using a dedicated heat source for generating water steam to be used as a gasification agent for carbide, promotes a pyrolysis reaction, and thereby, achieves the excellent heat efficiency. Provided are a hydrogen gas generation system and a power generation system which use water gas generated by a water gas generation system including a carbonizing furnace and a pyrolytic furnace and which have excellent productivity. Provided is a carbonizing furnace which improves combustion efficiency by controlling the supply amount of air being supplied to the carbonizing furnace according to the temperature of combustion gas in the carbonizing furnace, and which improves carbonization efficiency by controlling the discharge amount of carbide to be discharged to the outside according to the temperature of carbide or the deposit amount of organic waste in the carbonizing furnace, to make the temperature of carbide appropriate, and by controlling the temperature of air being supplied to the carbonizing furnace. In addition, provided is a pyrolytic furnace which blocks outflow of heating gas or water gas by providing seal portions at the attachment positions of a body part, a reaction tube, and a water gas outlet part, etc. of the pyrolytic furnace, and which maintains a pyrolysis reaction temperature by providing a pyrolysis promoting mechanism to the reaction tube. Provided is a water gas generation system which has excellent thermal efficiency and in which a combustion gas flow path is formed so as to allow combustion gas generated by a carbonizing furnace to flow through a carbonizing furnace, a pyrolytic furnace, a steam superheater, a steam generator, a dryer, and the like. Provided is a hydrogen gas generation system or a power generation system formed by combining the water gas generation system with a hydrogen purifying apparatus or a power generation equipment.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

The present invention is directed to an apparatus for domestic hot water and electricity production by the use of a natural organic fuel, the apparatus comprising a separated chambers pyrolysis furnace comprising: a) a pyrolysis chamber wherein the fuel is heated, substantially in the absence of oxygen at a temperature capable of causing pyrolysis of fuel; b) a combustion chamber of the pyrolyzed fuel, wherein the pyrolyzed fuel is burned in the presence of an air flux. The invention is also directed to an apparatus for the production of domestic hot water and electricity, which apparatus comprises: the above defined furnace; b) a heat exchanger connected to the exit of the exhausted gas, wherein domestic water is heated; c) a power generator connected with the exit of syngas, wherein syngas produced in the pyrolysis chamber is used as a fuel.

The present invention is directed to an apparatus for domestic hot water and electricity production by the use of a natural organic fuel, the apparatus comprising a separated chambers pyrolysis furnace comprising: a) a pyrolysis chamber wherein the fuel is heated, substantially in the absence of oxygen at a temperature capable of causing pyrolysis of fuel; b) a combustion chamber of the pyrolyzed fuel, wherein the pyrolyzed fuel is burned in the presence of an air flux. The invention is also directed to an apparatus for the production of domestic hot water and electricity, which apparatus comprises: the above defined furnace; b) a heat exchanger connected to the exit of the exhausted gas, wherein domestic water is heated; c) a power generator connected with the exit of syngas, wherein syngas produced in the pyrolysis chamber is used as a fuel.

An improved process is provided for catalytic pyrolysis of biomass, comprising pneumatically injecting a biomass feed via a pneumatic injection line into a fluidized heat medium, for example, hot catalyst, with a carrier gas at a velocity of from 5 to 40 m/s in at least one mixing zone in communication with a pyrolysis reactor in which catalytic pyrolysis occurs, and maintaining a catalyst/biomass mixture flowrate ratio (C/B) of from 4 to 40 downstream from the point of catalyst injection via a catalyst injection line in the at least one mixing zone.