A plasma or ionic reactor or gasifier implements an ultra-high temperature ionic gasification process that can be used in an environmentally friendly manner to dispose of dried biosolids from, for example, wastewater treatment plants as well other waste feed stocks such as municipal solid waste (MSW) to produce, for example, renewable syngas that can be used to provide heat, power, renewable fuels, renewable hydrogen, and/or renewable chemical production. The systems described herein do so by generating electrical arcs across the interior of the gasifier reaction chamber creating a localized, controlled temperature in excess of 3000 C along with ionic gas or particles (plasma). This ultra-high temperature gasification zone and active ionic environment combine to very effectively and efficiently break down molecules into their constituent atoms, in a process called complete molecular dissociation. This ultra-high temperature ionic zone will also rapidly decompose impurities in the feed stock such as microplastics, PFAS (Per- and Polyfluorinated Substances), and other fluorocarbon materials.

The present invention relates to reaction equipment for the treatment of organic and/or inorganic waste of refineries or petrochemical plants comprising: a drying and pyrolysis device (4) which rotates around its longitudinal, tilted rotation axis (A), a gasification device (6) which rotates around its longitudinal, horizontal rotation axis (B), a combustion device (14) comprising a burner (13) having a longitudinal horizontal axis (C), at least one settling chamber (15) for the collection of intermediate solid residues and the accumulation of intermediate gaseous reaction products, at least one outlet duct of the gaseous end-products (16), at least one outlet duct of the solid end-products (7), and at least one inlet duct of the feedstock (2) said combustion device (14), drying and pyrolysis device (4), gasification device (6) are physically separated and positioned on three different levels, the longitudinal rotation axis (A) of the drying and pyrolysis device (4) is tilted with respect to both the longitudinal rotation axis (B) of the gasification device (6) and also with respect to the longitudinal axis (C) of the combustion device (14), the longitudinal rotation axis (B) of the gasification device (6) is parallel to the longitudinal axis (C) of the combustion device (14), the combustion device (14) is in fluid communication with the drying and pyrolysis device (4), the drying and pyrolysis device (4) comprises, in its interior, a first indirect heat exchange device (3) in which the combustion fumes coming from the combustion device (14) flow, at least one settling chamber (15) in fluid communication with said drying and pyrolysis device (4) and with said gasification device (6) and with said combustion device (14), conveying means (5) are positioned in the settling chamber (15) and put the drying and pyrolysis device (4) in fluid communication with the gasification device, it comprises a second heat exchange device (12) in fluid communication with the first indirect heat exchange device (3) and the combustion device (14), it comprises means for the suction of the intermediate gaseous reaction products, said means being positioned in the settling chamber (15).

The present invention relates to reaction equipment for the treatment of organic and/or inorganic waste of refineries or petrochemical plants comprising: a drying and pyrolysis device (4) which rotates around its longitudinal, tilted rotation axis (A), a gasification device (6) which rotates around its longitudinal, horizontal rotation axis (B), a combustion device (14) comprising a burner (13) having a longitudinal horizontal axis (C), at least one settling chamber (15) for the collection of intermediate solid residues and the accumulation of intermediate gaseous reaction products, at least one outlet duct of the gaseous end-products (16), at least one outlet duct of the solid end-products (7), and at least one inlet duct of the feedstock (2) said combustion device (14), drying and pyrolysis device (4), gasification device (6) are physically separated and positioned on three different levels, the longitudinal rotation axis (A) of the drying and pyrolysis device (4) is tilted with respect to both the longitudinal rotation axis (B) of the gasification device (6) and also with respect to the longitudinal axis (C) of the combustion device (14), the longitudinal rotation axis (B) of the gasification device (6) is parallel to the longitudinal axis (C) of the combustion device (14), the combustion device (14) is in fluid communication with the drying and pyrolysis device (4), the drying and pyrolysis device (4) comprises, in its interior, a first indirect heat exchange device (3) in which the combustion fumes coming from the combustion device (14) flow, at least one settling chamber (15) in fluid communication with said drying and pyrolysis device (4) and with said gasification device (6) and with said combustion device (14), conveying means (5) are positioned in the settling chamber (15) and put the drying and pyrolysis device (4) in fluid communication with the gasification device, it comprises a second heat exchange device (12) in fluid communication with the first indirect heat exchange device (3) and the combustion device (14), it comprises means for the suction of the intermediate gaseous reaction products, said means being positioned in the settling chamber (15).

A process for the manufacture of one or more useful products comprises: gasifying a carbonaceous feedstock comprising waste materials and/or biomass in a gasification zone to generate a raw synthesis gas; supplying at least a portion of the raw synthesis gas to a clean-up zone to remove contaminants and provide a clean synthesis gas; supplying the clean synthesis gas to a first further reaction train to generate at least one first useful product and a tailgas; and diverting selectively on demand a portion of at least one of the carbonaceous feedstock, the clean synthesis gas, the tailgas and the light gas fraction to heat or power generation within the process, in response to external factors to control the carbon intensity of the overall process and enable GHG emission savings.

A process for the manufacture of one or more useful products comprises: gasifying a carbonaceous feedstock comprising waste materials and/or biomass in a gasification zone to generate a raw synthesis gas; supplying at least a portion of the raw synthesis gas to a clean-up zone to remove contaminants and provide a clean synthesis gas; supplying the clean synthesis gas to a first further reaction train to generate at least one first useful product and a tailgas; and diverting selectively on demand a portion of at least one of the carbonaceous feedstock, the clean synthesis gas, the tailgas and the light gas fraction to heat or power generation within the process, in response to external factors to control the carbon intensity of the overall process and enable GHG emission savings.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

The present invention relates to a method and system for recovering and processing a hydrocarbon mixture from a subterranean formation. The method comprises: (i) mobilizing said hydrocarbon mixture; (ii) recovering said mobilized hydrocarbon mixture; (iii) deasphalting said recovered hydrocarbon mixture to produce deasphalted hydrocarbon and asphaltenes; (iv) gasifying said asphaltenes in a gasifier to generate hydrogen, steam and/or energy and CO.sub.2; (v) upgrading said deasphalted hydrocarbon by hydrogen addition to produce upgraded hydrocarbon; and (vi) adding a diluent to said upgraded hydrocarbon, wherein said method is at least partially self-sufficient in terms of hydrogen and diluent.

The present invention relates to a method and system for recovering and processing a hydrocarbon mixture from a subterranean formation. The method comprises: (i) mobilizing said hydrocarbon mixture; (ii) recovering said mobilized hydrocarbon mixture; (iii) deasphalting said recovered hydrocarbon mixture to produce deasphalted hydrocarbon and asphaltenes; (iv) gasifying said asphaltenes in a gasifier to generate hydrogen, steam and/or energy and CO.sub.2; (v) upgrading said deasphalted hydrocarbon by hydrogen addition to produce upgraded hydrocarbon; and (vi) adding a diluent to said upgraded hydrocarbon, wherein said method is at least partially self-sufficient in terms of hydrogen and diluent.

Processes and systems are provided for converting a carbonaceous feedstock into a reaction gas and a syngas, involving a step of pyrolysing and methanating the feedstock in a pyrolysis chamber to produce the reaction gas and a step of gasifying unconverted feedstock in the presence of a reactant to produce a syngas.

In accordance with one embodiment, a process is described for a water treatment process in which process water is treated with recycled biochar. In accordance with one aspect, process water is passed through activated carbon generated by the biomass pyrolysis and gasification. In accordance with another aspect, the process water is treated to expel gaseous compounds within the process water. In this manner both inorganics, light organics and heavy organics can be removed from the process water. No fermentation is involved.