C10J3/721

TWO-STAGE SYNGAS PRODUCTION WITH SEPARATE CHAR AND PRODUCT GAS INPUTS INTO THE SECOND STAGE

A two-stage syngas production method to produce a final product gas from a carbonaceous material includes producing a first product gas in a first reactor, separating char from the first product gas to produce separated char and char-depleted product gas, and separately reacting the separated char and the char-depleted product gas with an oxygen-containing gas in a second reactor to produce a final product gas. The separated char is introduced into the second reactor above the char-depleted product gas. The solids separation device may include serially connected cyclones, and the separated char may be entrained in a motive fluid in an eductor to produce a char and motive fluid mixture prior to being transferred to the second reactor. A biorefinery method produces a purified product from the final product gas.

Thermochemical conversion of biomass

The present invention is directed to a process for the production of a syngas suited for further conversion to fine chemicals and/or automotive fuels from biomass by a thermochemical process conducted in a several steps procedure, said process comprising; a) Providing a stream of biomass material; b) Providing an aqueous alkaline catalyst stream comprising sodium and/or potassium compounds; c) Mixing comminuted biomass and alkaline catalyst and optional additives to form an alkaline biomass slurry or suspension; d) Treating alkaline biomass slurry or suspension in a hydrothermal treatment reactor at a temperature in the range of 200-400° C. and a pressure from 10-500 bar, forming a bio-oil suspension comprising liquefied biomass and spent alkali catalyst; e) Directly or indirectly charging the bio-oil suspension from step d), after optional depressurization to a pressure in the range 10-100 bar, heat exchange and separation of gases, such as CO2, steam and aqueous spent catalyst into a gasification reactor operating in the temperature range of 600-1250° C. thereby forming a syngas and alkali compounds; and f) Separating alkali compounds from a gasification reactor or from syngas and recycling alkali compounds directly or indirectly to be present to treat new biomass in the hydrothermal biomass treatment reactor of step d) and/or recycling aqueous alkali salts to a pulp mill chemicals recovery cycle.

Highly efficient and compact syngas generation system
11142714 · 2021-10-12 ·

A syngas generator has at least pyrolysis unit and a cracking unit which recycles treated input therein. The pyrolysis unit may recycle treated char to provide input heat for feedstock. The cracking unit may recycle syngas to assist in treating input gas/vapor mixture.

Temperature profile in an advanced thermal treatment apparatus and method
11136515 · 2021-10-05 ·

Applying heat from a heat source to a first region to cause a first pyrolysis process, the first pyrolysis process resulting in a gaseous mixture, and applying heat from the heat source to a second region to cause a second pyrolysis process, the second pyrolysis process being applied to the gaseous mixture, wherein the second region is located closer to the heat source than the first region. Pyrolysis is used to destroy oils, tars and/or PAHs in carbonaceous material.

Chemical looping syngas production from carbonaceous fuels

A reactor configuration is proposed for selectively converting gaseous, liquid or solid fuels to a syngas specification which is flexible in terms of H.sub.2/CO ratio. This reactor and system configuration can be used with a specific oxygen carrier to hydro-carbon fuel molar ratio, a specific range of operating temperatures and pressures, and a co-current downward moving bed system. The concept of a CO.sub.2 stream injected in-conjunction with the specified operating parameters for a moving bed reducer is claimed, wherein the injection location in the reactor system is flexible for both steam and CO.sub.2 such that, carbon efficiency of the system is maximized.

Processes For Producing High Biogenic Concentration Fischer-Tropsch Liquids Derived From Municipal Solid Wastes (MSW) Feedstocks
20210230491 · 2021-07-29 ·

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from municipal solid wastes (MSW) feedstocks

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

Two-stage gasifier and gasification process with feedstock flexibility

A two-stage gasification reactor may include a reactor lower section and a reactor upper section. The reactor lower section may include (a) a lower reactor body, (b) two primary feed nozzles, configured to introduce at least one of a dry feedstock or a first slurried feedstock and located on opposing terminal ends of the lower reactor body, and (c) at least two secondary feed nozzles, configured to introduce a liquid hydrocarbon feedstock, located on the lower reactor body. The reactor upper section may include (a) an upper reactor body, (b) at least one upper feed nozzle, configured to introduce at least one of a dry feedstock or a first slurried feedstock, located on the upper reactor body, and (c) an outlet.

Method and apparatus for gasifying carbon-containing material
11066613 · 2021-07-20 · ·

An apparatus and a method for gasifying carbon-containing materials in which the material for gasification and oxygen, usually in the form of air, are supplied to a gas generator where the gasification takes place in a fixed bed reactor. The product gas is drawn off via a product gas line and introduced into a hot gas filter. A filter, preferably provided with filter candles, removes solids such as particles not yet gasified, ash and foreign bodies, while clean gas passes through and is taken off via a clean gas line. An outlet is provided in the bottom region of the hot gas filter to remove residual solids. The hot gas filter is supplied through a line with oxygen, preferably in the form of air, in its middle height region, between the filter bottom and the outlet.

PROCESS

A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; recovering at least part of the raw synthesis gas from the gasification zone and supplying at least part of the recovered raw synthesis gas to a partial oxidation zone; equilibrating the H.sub.2:CO ratio of the raw synthesis gas in the partial oxidation zone to obtain equilibrated synthesis gas; recovering at least part of the equilibrated synthesis gas from the partial oxidation zone and treating the gas to remove impurities and generate a fine synthesis gas; and converting the optionally adjusted fine synthesis gas into the useful product in a further chemical reaction requiring a usage ratio.