An apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Synthesis gas (syngas) exits the gasifier which is coupled to a thermal oxidizer and is combusted at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat can be recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger that is coupled with the thermal oxidizer. Cooled flue gas is mixed with hydrated lime, enhancing PFAS decomposition, with the spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements. The apparatus and methods thereby eliminate PFAS from wastewater biosolids and control emissions in the resulting flue gas.

Apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Syngas exits the gasifier which is coupled to a thermal oxidizer and combusts at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat is recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger coupled with the thermal oxidizer. Various methods inject moisture into the gas stream, controlling temperature through evaporative cooling and/or injecting chemicals that react with gas stream components. Cooled flue gas mixes with hydrated lime capturing decomposed PFAS molecules with spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements, eliminating PFAS from wastewater biosolids and controlling emissions in the resulting flue gas.

An integrated biomass conversion system and a method of starting and shutting down the system are disclosed. The integrated biomass conversion system comprises a syngas generator, such as a gasifier, a cleanup engine and a syngas utilization system, which could be a power producing engine or a chemical reactor for chemical or fuel synthesis. The cleanup engine operates rich and at high temperatures so that the tars exhausted by the syngas generators are destroyed and not allowed to foul other components. An orderly sequence to start and shut down the integrated biomass conversion system is disclosed.

A method and system for continuous production of contaminant free and size specific biochar using downdraft gasification of variable quality feedstock. The system and process of the present invention includes the transfer of biochar from a gasifier after gasification to a temperature-controlled cooling screw conveyor, into a drum magnet for ferrous metal removal into multiple diverters to separate and remove ungasified materials and non-ferrous metal contaminants, then transferred into a granulator for grinding and screening the biochar to a pre-selected size. By directly attaching a novel and continuous product treatment process to the biochar stream as it exits the gasifier, the particle size, moisture content, carbon content and yield of a contaminant free biochar product can be narrowly controlled and improved to meet strict product quality specifications required by specialty applications.

A method and system for continuous production of contaminant free and size specific biochar using downdraft gasification of variable quality feedstock. The system and process of the present invention includes the transfer of biochar from a gasifier after gasification to a temperature-controlled cooling screw conveyor, into a drum magnet for ferrous metal removal into multiple diverters to separate and remove ungasified materials and non-ferrous metal contaminants, then transferred into a granulator for grinding and screening the biochar to a pre-selected size. By directly attaching a novel and continuous product treatment process to the biochar stream as it exits the gasifier, the particle size, moisture content, carbon content and yield of a contaminant free biochar product can be narrowly controlled and improved to meet strict product quality specifications required by specialty applications.

A gasification gas treatment facility for treating a gasification gas obtained by gasification of a fuel includes: a first heat exchanger for performing heat exchange between a purified gas obtained by removing at least ammonia and hydrogen chloride from the gasification gas and steam at a saturation temperature; a second heat exchanger for performing heat exchange between the gasification gas and at least condensed water produced by the heat exchange in the first heat exchanger to produce the steam at the saturation temperature; and a circulation system for circulating a circulating fluid including at least one of the steam or the condensed water between the first heat exchanger and the second heat exchanger. The circulation system is configured to supply the circulating fluid including at least the condensed water at the saturation temperature produced in the first heat exchanger to the second heat exchanger.

A reactor system made up of a single canister or a plurality of separate canister sections for the advanced thermal chemical conversion processing of municipal solid waste (“MSW”), either sorted or unsorted, and autoclaves specially designed to process the waste at suitable temperature and pressure combinations is disclosed. The canister sections can be individually and separately filled with compressed bales of MSW or with selected loose MSW. The reactor system can produce syngas that has an enhanced BTU value, typically between about 300 to 700 BTU/ft.sup.3. The remainder solid waste material generally amounts to approximately 5% of the original MSW volume. This material can then be sorted for metals with the balance being sent to a landfill or other recycling processes depending on its composition.

A direct carbonaceous material to power generation system integrates one or more solid oxide fuel cells (SOFC) into a fluidized bed gasifier. The fuel cell anode is in direct contact with bed material so that the H.sub.2 and CO generated in the bed are oxidized to H.sub.2O and CO.sub.2 to create a push-pull or source-sink reaction environment. The SOFC is exothermic and supplies heat within a reaction chamber of the gasifier where the fluidized bed conducts an endothermic reaction. The products from the anode are the reactants for the reformer and vice versa. A lower bed in the reaction chamber may comprise engineered multi-function material which may incorporate one or more catalysts and reactant adsorbent sites to facilitate excellent heat and mass transfer and fluidization dynamics in fluidized beds. The catalyst is capable of cracking tars and reforming hydrocarbons.

An operating guide system of a plant utilizing coal gasification includes a performance analyzer for analyzing performance of the plant by analyzing gasifier performance and synthesis gas cooler performance during an operation of the plant; an operation guide generator for generating an operation guide indicating control values for the operation of the plant based on the performance analysis of the plant; an action guide generator for generating an action guide indicating control values for controlling the plant to prevent an abnormal situation predicted in the plant based on the performance analysis of the plant; and a fuel determiner for determining gasification suitability of an analysis target fuel selected by a user before the plant is started, the gasification suitability including basic suitability and suitability of slag behavior.

A gasification unit includes a gasifier configured to gasify a carbon-containing solid fuel; a pressure vessel housing the gasification furnace; a pressure holding section that is to be filled with a pressurizing gas and is provided between the gasifier and the pressure vessel; a pressurizing gas supply device configured to supply a pressurizing gas to the pressure holding section; pressure equalizing pipes by which the inside of the gasifier is communicated with the pressure holding section; a pressure difference detection and estimation device configured to detect or estimate a pressure difference between a first pressure on the gasifier side and a second pressure on the pressure holding section side; and a control device configured to control the pressurizing gas supply device such that the second pressure is higher than the first pressure based on a detection or estimation result of the pressure difference detection and estimation device.