Patent classifications
C10J3/78
COMBINATION OF ANAEROBIC TREATMENT OF CARBONACEOUS MATERIAL WITH HYDROTHERMAL GASIFICATION TO MAXIMIZE VALUE ADDED PRODUCT RECOVERY
A method for treating carbonaceous material, the method includes a) providing a carbonaceous material CM, b) subjecting the carbonaceous material CM to hydrothermal gasification in a HTG reactor, thereby producing: an inorganic solid residue, a first gaseous fraction G1 comprising CH.sub.4, CO, CO.sub.2 and H.sub.2, and a filtrate F1 containing readily biodegradable carbons such as VFAs, c) subjecting at least part of the filtrate F1 to an anaerobic treatment step in an anaerobic tank, leading to a digestate. An installation for treating carbonaceous material is also provided.
COMBINATION OF ANAEROBIC TREATMENT OF CARBONACEOUS MATERIAL WITH HYDROTHERMAL GASIFICATION TO MAXIMIZE VALUE ADDED PRODUCT RECOVERY
A method for treating carbonaceous material, the method includes a) providing a carbonaceous material CM, b) subjecting the carbonaceous material CM to hydrothermal gasification in a HTG reactor, thereby producing: an inorganic solid residue, a first gaseous fraction G1 comprising CH.sub.4, CO, CO.sub.2 and H.sub.2, and a filtrate F1 containing readily biodegradable carbons such as VFAs, c) subjecting at least part of the filtrate F1 to an anaerobic treatment step in an anaerobic tank, leading to a digestate. An installation for treating carbonaceous material is also provided.
Supercritical Water Gasification Process
The process described herein converts biomass directly into a combination of hydrogen, methane and carbon dioxide. A portion of the gases are collected at pressures above the thermodynamic critical pressure for water, which is 3200 psi (pounds per square inch). Typical operating pressure at the point where the first portion of gas collected can range from 3200 psi to 6000 psi. Upon cooling, most of the CO.sub.2 condenses to a liquid. At this density and pressure, the CO.sub.2 can be injected into a deep well aquifer to sequester the carbon dioxide. The overall process is superior to carbon neutral processes, can be carbon negative, and possesses the potential to reverse atmospheric CO.sub.2 trends if implemented on a global scale.
Supercritical Water Gasification Process
The process described herein converts biomass directly into a combination of hydrogen, methane and carbon dioxide. A portion of the gases are collected at pressures above the thermodynamic critical pressure for water, which is 3200 psi (pounds per square inch). Typical operating pressure at the point where the first portion of gas collected can range from 3200 psi to 6000 psi. Upon cooling, most of the CO.sub.2 condenses to a liquid. At this density and pressure, the CO.sub.2 can be injected into a deep well aquifer to sequester the carbon dioxide. The overall process is superior to carbon neutral processes, can be carbon negative, and possesses the potential to reverse atmospheric CO.sub.2 trends if implemented on a global scale.
Apparatus for Supercritical Water Gasification
The present disclosure provides a supercritical fluid gasification system. In some embodiments, the system includes a reactor having a reactor shell including sidewalls that extend between a top reactor cover and a bottom reactor cover, where the sidewalls, the top cover, and the bottom cover enclosing a reactor shell channel. In some embodiments, the reactor includes a thermal shield positioned within the reactor shell channel, the thermal shield having sidewalls that extend between a top thermal shield cover and a bottom thermal shield cover, where the sidewalls, the top thermal shield cover, and the bottom thermal shield cover enclosing a thermal shield channel. In some embodiments, the reactor includes a fluid feed supply conduit in fluid communication with the thermal shield channel, a supercritical fluid conduit in fluid communication with the thermal shield channel, and a product conduit in fluid communication with the thermal shield channel.
Apparatus for Supercritical Water Gasification
The present disclosure provides a supercritical fluid gasification system. In some embodiments, the system includes a reactor having a reactor shell including sidewalls that extend between a top reactor cover and a bottom reactor cover, where the sidewalls, the top cover, and the bottom cover enclosing a reactor shell channel. In some embodiments, the reactor includes a thermal shield positioned within the reactor shell channel, the thermal shield having sidewalls that extend between a top thermal shield cover and a bottom thermal shield cover, where the sidewalls, the top thermal shield cover, and the bottom thermal shield cover enclosing a thermal shield channel. In some embodiments, the reactor includes a fluid feed supply conduit in fluid communication with the thermal shield channel, a supercritical fluid conduit in fluid communication with the thermal shield channel, and a product conduit in fluid communication with the thermal shield channel.
Heating and cooling system for high pressure processing system
The invention relates to a method of heating and cooling a feed mixture in a continuous high pressure process for transforming carbonaceous materials into liquid hydrocarbon products in a high pressure processing system adapted for processing a feed mixture at a temperature of at least 340° C. and a pressure of at least 150 bar, the high pressure processing system comprising a first and a second heat exchanger having a heat transfer fluid comprising at least 90% water, preferably at least 99% water circulating in the external part of the first and the second heat exchanger, the first heat exchanger comprising a cold internal input side and a hot internal output side, the second heat exchanger comprising a hot internal input side and a cold internal output side, the system further comprising a high pressure water heater and a high pressure water cooler between the first and the second heat exchanger, where the pressurized feed mixture is heated by feeding the feed mixture to the cold internal side of the first heat exchanger, heating and pressurizing the heat transfer fluid to a pressure of at least 240 bar and a temperature of at least 400° C. at the input to the hot external side of the first heat exchanger, where the cooled heat transfer fluid from the first heat exchanger having a temperature in the range 150 to 300° C. is further cooled to a temperature of 60 to 150° C. in the high pressure water cooler prior to entering the cold external side of the second heat exchanger, where the pressurized, heated and converted feed mixture is cooled to a temperature in the range 60 to 200° C. by feeding it to the internal side of the second heat exchanger, and where the partly heated heat transfer fluid is further heated in the high pressure water heater before entering the first heat exchanger.
GASIFIER FOR ORGANIC SOLID WASTE BY INJECTION INTO MOLTEN IRON AND SLAG BATH
A gasifier for organic solid waste by injection into molten iron and slag bath includes a gasification furnace, a liquid level adjusting furnace and a slag discharge and heat exchange shaft furnace. The liquid level adjusting furnace, in communication with the bottom of the gasification furnace, contains 1200-1700° C. molten iron-based alloy liquid, which is covered with molten liquid slag layer. When gas pressure above or liquid volume in the liquid level adjusting furnace increases, liquid level of the molten liquid in the gasification furnace rises simultaneously. A particle material injection lance is immersed, through which organic particles to be gasified are blown into molten bath, and oxygen gas or oxygen-enriched air as gasifying agent is blown into the melt at the same time. Organic substance is gasified into CO-rich and H.sub.2-rich syngas, and most of inorganic substance enters molten slag and is discharged termly.
GASIFIER FOR ORGANIC SOLID WASTE BY INJECTION INTO MOLTEN IRON AND SLAG BATH
A gasifier for organic solid waste by injection into molten iron and slag bath includes a gasification furnace, a liquid level adjusting furnace and a slag discharge and heat exchange shaft furnace. The liquid level adjusting furnace, in communication with the bottom of the gasification furnace, contains 1200-1700° C. molten iron-based alloy liquid, which is covered with molten liquid slag layer. When gas pressure above or liquid volume in the liquid level adjusting furnace increases, liquid level of the molten liquid in the gasification furnace rises simultaneously. A particle material injection lance is immersed, through which organic particles to be gasified are blown into molten bath, and oxygen gas or oxygen-enriched air as gasifying agent is blown into the melt at the same time. Organic substance is gasified into CO-rich and H.sub.2-rich syngas, and most of inorganic substance enters molten slag and is discharged termly.
HEATING AND COOLING SYSTEM FOR HIGH PRESSURE PROCESSING SYSTEM
The invention relates to a method of heating and cooling a feed mixture in a continuous high pressure process for transforming carbonaceous materials into liquid hydrocarbon products in a high pressure processing system adapted for processing a feed mixture at a temperature of at least 340° C. and a pressure of at least 150 bar, the high pressure processing system comprising a first and a second heat exchanger having a heat transfer fluid comprising at least 90% water, preferably at least 99% water circulating in the external part of the first and the second heat exchanger, the first heat exchanger comprising a cold internal input side and a hot internal output side, the second heat exchanger comprising a hot internal input side and a cold internal output side, the system further comprising a high pressure water heater and a high pressure water cooler between the first and the second heat exchanger, where the pressurized feed mixture is heated by feeding the feed mixture to the cold internal side of the first heat exchanger, heating and pressurizing the heat transfer fluid to a pressure of at least 240 bar and a temperature of at least 400° C. at the input to the hot external side of the first heat exchanger, where the cooled heat transfer fluid from the first heat exchanger having a temperature in the range 150 to 300° C. is further cooled to a temperature of 60 to 150° C. in the high pressure water cooler prior to entering the cold external side of the second heat exchanger, where the pressurized, heated and converted feed mixture is cooled to a temperature in the range 60 to 200° C. by feeding it to the internal side of the second heat exchanger, and where the partly heated heat transfer fluid is further heated in the high pressure water heater before entering the first heat exchanger.