There is provided an absorbent for decreasing the leakage of halogen compound gases in subsequent processes, at high temperatures and in the presence of high concentrations of water vapor in the process of heating and gasifying a fuel, such as coal, to produce a synthesis gas.

The adsorbent includes a halogen compound absorbent containing 30 to 90% by mass of a basic calcium compound and 10 to 70% by mass of a metal compound other than basic calcium compounds and/or of a clay mineral. A method for producing synthesis gas using the absorbent is also disclosed.

There is provided an absorbent for decreasing the leakage of halogen compound gases in subsequent processes, at high temperatures and in the presence of high concentrations of water vapor in the process of heating and gasifying a fuel, such as coal, to produce a synthesis gas.

The adsorbent includes a halogen compound absorbent containing 30 to 90% by mass of a basic calcium compound and 10 to 70% by mass of a metal compound other than basic calcium compounds and/or of a clay mineral. A method for producing synthesis gas using the absorbent is also disclosed.

The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor that is configured to provide an output stream that is enriched in methane content. The resulting partially oxidized stream can be cooled, filtered, additionally cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO.sub.2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The recycle CO.sub.2 stream is compressed and passed through the recuperator heat exchanger and optionally the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.

The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor that is configured to provide an output stream that is enriched in methane content. The resulting partially oxidized stream can be cooled, filtered, additionally cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO.sub.2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The recycle CO.sub.2 stream is compressed and passed through the recuperator heat exchanger and optionally the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.

A system for preheating a pressure vessel includes a throat including an area of excess heat and a dome having an area of deficient heat. The throat includes a conduit extending from a pressure vessel opening to the pressure vessel interior. A plenum is defined between the throat and a seal within the dome. The throat extends from the dome toward a dome floor. The floor is substantially perpendicular to the throat. A conduit is coupled to the plenum and channels a flow of purge fluid into the plenum wherein heat from the throat is transferred to the flow of purge fluid and carried by the flow of purge fluid into the area of deficient heat via a gap defined between the seal and the floor such that the flow of purge fluid reduces temperature differential stresses within the pressure vessel and purges the area of deficient heat.

A system for preheating a pressure vessel includes a throat including an area of excess heat and a dome having an area of deficient heat. The throat includes a conduit extending from a pressure vessel opening to the pressure vessel interior. A plenum is defined between the throat and a seal within the dome. The throat extends from the dome toward a dome floor. The floor is substantially perpendicular to the throat. A conduit is coupled to the plenum and channels a flow of purge fluid into the plenum wherein heat from the throat is transferred to the flow of purge fluid and carried by the flow of purge fluid into the area of deficient heat via a gap defined between the seal and the floor such that the flow of purge fluid reduces temperature differential stresses within the pressure vessel and purges the area of deficient heat.

A modular system and method for producing urea from bio-mass includes means and steps for “homogenizing” a biomass feedstock stream having components with different bulk density BTU content into a stream having a consistent bulk density BTU content. The steps include cleaning the incoming bio-mass feedstock stream to remove non-organic matter, blending the cleaned bio-mass feedstock stream to obtain a homogeneous blend having a consistent bulk density BTU content, and milling the homogeneous blend bio-mass feedstock stream to a predetermined size no greater than 12 mm.

A modular system and method for producing urea from bio-mass includes means and steps for “homogenizing” a biomass feedstock stream having components with different bulk density BTU content into a stream having a consistent bulk density BTU content. The steps include cleaning the incoming bio-mass feedstock stream to remove non-organic matter, blending the cleaned bio-mass feedstock stream to obtain a homogeneous blend having a consistent bulk density BTU content, and milling the homogeneous blend bio-mass feedstock stream to a predetermined size no greater than 12 mm.

The present invention concerns a reactor and a process for the hydrothermal treatment of an aqueous mixture, such as watery biomass. The reactor according to the invention comprises (31) an inlet for receiving the aqueous mixture, (32) a tube-shaped reactor interior, which is inclined at an angle in the range of 1-45°; (33) a first zone in the reactor interior (32) comprising means (5) for heating the aqueous mixture; (34) a second zone in the reactor interior (32) for keeping the aqueous mixture at the predetermined temperature; (35) a third zone in the reactor interior (32) for cooling the aqueous mixture; (38) an outlet for discharging a hydrothermally treated aqueous mixture, and (43) an outlet for discharging gas, wherein inlet (31) and outlet (43) are positioned at the top part of the reactor and outlet (38) at the bottom part of the reactor. The inclined nature of the reactor ensures that all gases are efficiently removed from the liquid effluent, and the CO.sub.2 formed during the process is used to improved efficacy of the hydrothermal treatment.

The present invention concerns a reactor and a process for the hydrothermal treatment of an aqueous mixture, such as watery biomass. The reactor according to the invention comprises (31) an inlet for receiving the aqueous mixture, (32) a tube-shaped reactor interior, which is inclined at an angle in the range of 1-45°; (33) a first zone in the reactor interior (32) comprising means (5) for heating the aqueous mixture; (34) a second zone in the reactor interior (32) for keeping the aqueous mixture at the predetermined temperature; (35) a third zone in the reactor interior (32) for cooling the aqueous mixture; (38) an outlet for discharging a hydrothermally treated aqueous mixture, and (43) an outlet for discharging gas, wherein inlet (31) and outlet (43) are positioned at the top part of the reactor and outlet (38) at the bottom part of the reactor. The inclined nature of the reactor ensures that all gases are efficiently removed from the liquid effluent, and the CO.sub.2 formed during the process is used to improved efficacy of the hydrothermal treatment.