Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

A waste management system, primarily intended to be for waste floating in water, though it can also be used on land. A shredding device will reduce the size of the particles of waste. Ocean water is removed by a drying device. The dried waste material is cryogenically frozen using liquid nitrogen or other suitable means. The frozen waste material is then pulverized and ground into a powder. The powder may then be sprayed into a gas-filled chamber and heated. Temperature, pressure and humidity are maintained within the chamber for more than one minute. Microwave or other radiation and catalysts may be used to enhance the process of extraction. The processed material is then removed from the chamber. Carbon and water may be recycled. The carbon may be used as fuel by the ship. Water may also be used by the ship or returned to the ocean in a non-toxic condition.

Systems and methods of producing a solid fuel composition are disclosed. In particular, systems and methods for producing a solid fuel composition by heating and mixing a solid waste mixture to a maximum temperature sufficient to melt the mixed plastics within the solid waste mixture is disclosed.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

Methods and apparatus may permit the generation of consistent output synthesis gas from highly variable input feedstock solids carbonaceous materials. A stoichiometric objectivistic chemic environment may be established to stoichiometrically control carbon content in a solid carbonaceous materials gasifier system. Processing of carbonaceous materials may include dominative pyrolytic decomposition and multiple coil carbonaceous reformation. Dynamically adjustable process determinative parameters may be utilized to refine processing, including process utilization of negatively electrostatically enhanced water species, process utilization of flue gas, and adjustment of process flow rate characteristics. Recycling may be employed for internal reuse of process materials, including recycled negatively electrostatically enhanced water species, recycled flue gas, and recycled contaminants. Synthesis gas generation may involve predetermining a desired synthesis gas for output and creating high yields of such a predetermined desired synthesis gas.

Disclosed are novel engineered fuel feed stocks, feed stocks produced by the described processes, and methods of making the fuel feed stocks. Components derived from processed. MSW waste streams can be used to make such feed stocks which are substantially free of glass, metals, grit and noncombustibles. These feed stocks are useful for a variety of purposes including co-firing with coal and as substitutes for coal.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

A process for the gasification of a solid carbonaceous feed, the process comprising the steps of: introducing a batch of the solid carbonaceous feed into a sluice vessel, while an internal pressure in the sluice vessel is at a first pressure; introducing at least recycled CO2 into the sluice vessel via one or more gas inlets covered by the solid carbonaceous feed, to pressurize the sluice vessel from the first pressure to a second pressure exceeding the first pressure, during a predetermined time period; closing the one or more gas inlets; opening a feed outlet of the sluice vessel to supply the batch of the solid carbonaceous feed to a feed vessel for feeding the solid carbonaceous feed to a gasification reactor; closing the feed outlet; venting the sluice vessel to reduce the internal pressure to the first pressure; and repeating the process.

Methods and apparatus may permit the generation of consistent output synthesis gas from highly variable input feedstock solids carbonaceous materials. A stoichiometric objectivistic chemic environment may be established to stoichiometrically control carbon content in a solid carbonaceous materials gasifier system. Processing of carbonaceous materials may include dominative pyrolytic decomposition and multiple coil carbonaceous reformation. Dynamically adjustable process determinative parameters may be utilized to refine processing, including process utilization of negatively electrostatically enhanced water species, process utilization of flue gas, and adjustment of process flow rate characteristics. Recycling may be employed for internal reuse of process materials, including recycled negatively electrostatically enhanced water species, recycled flue gas, and recycled contaminants. Synthesis gas generation may involve predetermining a desired synthesis gas for output and creating high yields of such a predetermined desired synthesis gas.

The invention is directed to a process for a combined biomass and plastic product conversion by subjecting a moulded product comprising of between 1 and 20 wt % of a plastic product and between 99 and 80 wt % of a torrefied biomass to a pyrolysis or mild gasification thereby obtaining a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds and a char product.