A system for processing solid waste including a segmented gasifier having a first segment detachably connected to a second segment, and a burner positioned downstream of the segmented gasifier and coupled to the segmented gasifier. A process for treating solid waste including introducing the solid waste into a first end of a segmented gasifier having a first segment detachably connected to a second segment. Gasifying the solid waste as it traverses from the first end of the gasifier to a second end of the segmented gasifier, and producing a gaseous output and a solid output at the second end of the segmented gasifier. Separating the gaseous output and the solid output, and introducing a portion of the gaseous output to a burner and recycling a portion of the gaseous output to the segmented gasifier as an energy source.

A system and process for the resultant gas constituent-controlled gasification of a carbonaceous feedstock uses feedback loop-controlled pyrolysis to produce a stable and predictable gas product from a variable or unknown feedstock, such as MSW, that may include methane, ethane, and other desirable hydrocarbon gases, and a solid product, that includes activated Carbon or Carbon.

Provided herein are novel devices, systems, and methods of using the same, that enable plasma-enhanced gasification of biogenic hydrocarbon waste material comprising: a geometrically designed reactor having a biochar carbon catalyst bed, together with a gas inlet system disposed around a lower section of the apparatus to supply oxidant gas generated by an integrated oxygen absorber system; to enhance the partial oxidation of biogenic hydrocarbon waste materials using exothermic heat generated by an oxidation reaction created in part by the integrated oxygen absorber system into the apparatus, in order to optimize the quantity and quality of hydrogen production in the synthetic gas produced therein.

Disclosed herein are integrated preparation and detection devices for studying biomass-burning aerosols, where the devices include a micro-fluidized bed reactor (MFBR), a transmission line, and an on-line detection unit that are connected in sequence. The MFBR may include a pyrolysis reactor and a pyrolysis furnace; the pyrolysis reactor may include a thermocouple, an introduction tube, and quartz sands; the on-line detection unit may be an on-line photoionization mass spectrometer; and the photoionization mass spectrometer may include a laser desorption system, a laser ionizer and a light energy ionizer. Devices of the present disclosure are beneficial to retain the original state of aerosol particles, and the fixed MFBR can realize rapid pyrolysis of a biomass due to its high and stable heat conduction efficiency, which is beneficial to studying the formation mechanism of aerosol particles.

A solids circulation system receives a gas stream containing char or other reacting solids from a first reactor. The solids circulation system includes a cyclone configured to receive the gas stream from the first reactor, a dipleg from the cyclone to a second reactor, and a riser from the second reactor which merges with the gas stream received by the cyclone. The second reactor has a dense fluid bed and converts the received materials to gaseous products. A conveying fluid transports a portion of the bed media from the second reactor through the riser to mix with the gas stream prior to cyclone entry. The bed media helps manipulate the solids that is received by the cyclone to facilitate flow of solids down the dipleg into the second reactor. The second reactor provides additional residence time, mixing and gas-solid contact for efficient conversion of char or reacting solids.

A method for thermal volume reduction of waste material contaminated with radionuclides includes feeding the waste material into a fluidized bed reactor, injecting fluidizing gas into the fluidized bed reactor to fluidize bed media in the fluidized bed reactor, and decomposing the waste material in the fluidized bed reactor. A system for thermal volume reduction of the waste material includes one or more of a feedstock preparation and handling system, a fluidized bed reactor system, a solids separation system, and an off-gas treatment system. The method and system may be used to effectively reduce the volume or radioactive wastes generated from the operation of nuclear facilities such as nuclear power plants including wastes such as spent ion exchange resin, spent granular activated carbon, and dry active waste. The majority of the organic content in the waste material is converted into carbon dioxide and steam and the solids, including the radionuclides, are converted into a waterless stable final product that is suitable for disposal or long-term storage.

Disclosed are novel engineered fuel feed stocks, feed stocks produced by the described processes, methods of making the fuel feed stocks, methods of producing energy from the fuel feed stocks. Components derived from processed MSW waste streams can be used to make such feed stocks which are substantially free of glass, metals, grit and noncombustibles and contain a sorbent. These feed stocks are useful for a variety of purposes including as gasification and combustion fuels. In addition, one or more sorbents can be added to the feed stocks in order to reduce the amount of a variety of pollutants present in traditional fuel and feed stocks, including, but not limited, sulfur and chlorine. Further, these feed stocks with added sorbent can mitigate corrosion, improve fuel conversion, extend power generating plant lifetime, reduce ash slagging, and reduced operating temperature.

The disclosure relates generally to methods and systems for manufacturing ammonia, ammonium sulfate, nitric acid, ammonium nitrate, or combinations thereof, and particularly to clean and efficient methods and system configurations for manufacturing ammonia, ammonium sulfate, nitric acid, ammonium nitrate, or combinations thereof using coal, petcoke, asphaltenes and/or hydrocarbon waste products.

The present invention provides a process and apparatus for converting feedstock comprising biomass and/or carbon-containing solid waste material to synthesis gas. The process comprises supplying a densified and pressurized feedstock to a gasifier comprising a fluidized bed zone and a post-gasification zone and contacting the feedstock with a gasification agent. Recovery and purification of the synthesis gas is then carried out involving the recycling of CO.sub.2 back to various stages in the process. The apparatus is configured to carry out the process and comprises transport lines to recycle the CO.sub.2. The synthesis gas can be further processed to form renewable synthetic products and/or chemicals.

The present disclosure is directed to methods using durable functional materials for processes that include an oxidation step. The durable functional materials are redox active oxygen carrier materials that include a zirconia or yttria-stabilized-zirconia (YSZ) matrix containing a redox-active metal ion(s), such as, but not limited to Fe, Mn, Cu, Co and Cr. In an embodiment, these materials are used in chemical looping processes.