An integrated refinery process for the disposal of metal-containing spent coked catalyst from hydrotreating and/or hydrocracking unit operations includes introducing the spent coked catalyst into a membrane wall gasification reactor in the form of flowable particles along with predetermined amounts of oxygen and steam based upon an analysis of the hydrocarbon content of the coke, and optionally, a liquid hydrocarbon; gasifying the feed to produce synthesis gas and a slag material; recovering and subjecting the slag material to further processes in preparation for a leaching step to solubilize and form one or more active phase metal compounds that are recovered from the leaching solution, either separately by sequential processing, or together. The recovered active metal compounds can be used, e.g., in preparing fresh catalyst for use in the refinery's hydroprocessing units.

The invention is directed to a process to prepare an activated carbon product and a syngas mixture comprising hydrogen and carbon monoxide from a solid torrefied biomass feed comprising the following steps, (i) subjecting the solid biomass feed to a pyrolysis reaction thereby obtaining a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds and a solid fraction comprising of char particles, (ii) separating the solids fraction from the gaseous fraction, (iii) subjecting the gaseous fraction obtained in step (ii) to a continuously operated partial oxidation to obtain a syngas mixture further comprising water and having an elevated temperature and (iv) activating the char particles as obtained in step (ii) to obtain the activated carbon product.

In order to allow for thermal elongation of a liner, a pipe member, in the interior of which flows a fluid containing solids, is provided with: a tubular outer pipe; a single tubular liner provided inside the outer pipe with a gap therebetween in the radial direction, or a plurality thereof arranged serially in the direction of the pipe axis C; a refractory material filled in between the outer pipe and the liner; a first liner holding member that is provided on an end portion side of the outer pipe, and that holds the liner arranged on the end portion side in a restrained state in the pipe axis C direction and the circumferential direction around the pipe axis C; and a second liner holding member that is provided on an end portion side of the outer pipe, and that holds the liner arranged on the end portion side.

Aspects of the invention relate to improvements in the flexibility with which oxygen and hydrogen, for example from electrolysis, may be supplied to processes having both gasification and methanation steps, as well as improvements in how such processes may be operated in response to variations in carbonaceous feeds. Offsets, between the ideal quantity of hydrogen and the quantity available from a given source may be compensated for by adjusting one or more operations of the process, and in particular such operation(s) that ultimately impact the quantity of CO and/or CO.sub.2 available downstream of the gasifier for conversion to methane in an RNG product stream.

A gasification system and a method for gasifying a particulate carbonaceous fuel are disclosed. The gasification system has a gasification chamber with an upper section and a lower section with a fuel inlet for injecting a particulate carbonaceous fuel and oxidant into the upper section whereby, in a thermo-chemical reaction, synthesis gas and residual char is generated. The gasification system further includes a separator configured to receive the synthesis gas and to separate residual tar form the synthesis gas. Further, there is a char bed disposed in the lower section formed by residual char generated in the thermo-chemical reaction and a gas-inlet at a bottom portion of the lower section for injecting gas into the char bed. The residual tar is injected into the char bed whereby, in a thermal cracking process, the residual tar is converted into synthesis gas. Hereby, it is possible to utilize the otherwise lost energy contained in the residual tar, and thereby achieve better efficiency in a gasification system, in a cost-effective and simple manner.

A solids circulation system receives a gas stream containing char or other reacting solids from a first reactor. The solids circulation system includes a cyclone configured to receive the gas stream from the first reactor, a dipleg from the cyclone to a second reactor, and a riser from the second reactor which merges with the gas stream received by the cyclone. The second reactor has a dense fluid bed and converts the received materials to gaseous products. A conveying fluid transports a portion of the bed media from the second reactor through the riser to mix with the gas stream prior to cyclone entry. The bed media helps manipulate the solids that is received by the cyclone to facilitate flow of solids down the dipleg into the second reactor. The second reactor provides additional residence time, mixing and gas-solid contact for efficient conversion of char or reacting solids.

A process and apparatus for producing syngas from low grade coal and from a biomass wherein the process includes (i) gasification of a mixture of low grade coal and biomass, (ii) reforming the gasified mixture, and (iii) removing CO.sub.2 from the gasified and reformed syngas mixture.

A coal pyrolysis process device, including a primary coal pyrolysis device and a secondary coal pyrolysis device, wherein a discharge port of the primary coal pyrolysis device communicates with a feed port of the secondary coal pyrolysis device. When coal is in the primary coal pyrolysis device, coal tar is extracted to the maximum extent, and then enters the secondary coal pyrolysis device. The coal continues to be heated and undergo pyrolysis at an upper portion of the secondary coal pyrolysis device, so that volatile matter of upgraded coal having undergone primary pyrolysis and upgrading are further reduced in the secondary coal pyrolysis device, and more gas is produced.

A gasification system and a method for gasifying a particulate carbonaceous fuel are disclosed. The gasification system has a gasification chamber with an upper section and a lower section with a fuel inlet for injecting a particulate carbonaceous fuel and oxidant into the upper section whereby, in a thermo-chemical reaction, synthesis gas and residual char is generated. The gasification system further includes a separator configured to receive the synthesis gas and to separate residual tar form the synthesis gas. Further, there is a char bed disposed in the lower section formed by residual char generated in the thermo-chemical reaction and a gas-inlet at a bottom portion of the lower section for injecting gas into the char bed. The residual tar is injected into the char bed whereby, in a thermal cracking process, the residual tar is converted into synthesis gas. Hereby, it is possible to utilize the otherwise lost energy contained in the residual tar, and thereby achieve better efficiency in a gasification system, in a cost-effective and simple manner.

Aspects of the invention relate to improvements in the flexibility with which oxygen and hydrogen, for example from electrolysis, may be supplied to processes having both gasification and methanation steps, as well as improvements in how such processes may be operated in response to variations in carbonaceous feeds. Offsets, between the ideal quantity of hydrogen and the quantity available from a given source may be compensated for by adjusting one or more operations of the process, and in particular such operation(s) that ultimately impact the quantity of CO and/or CO.sub.2 available downstream of the gasifier for conversion to methane in an RNG product stream.