A method for processing feedstock is described, characterized in that incoming feedstock is processed to selectively recover biogenic carbon material from the incoming feedstock. In some embodiments the incoming feedstock is comprised of mixed solid waste, such as municipal solid waste (MSW). In other embodiments the incoming feedstock is comprised of woody biomass. In some instances, the incoming feedstock is processed to selectively recover biogenic carbon material from the incoming feedstock to produce a processed feedstock having biogenic carbon content of 50% and greater suitable for conversion into biogenic carbon Fischer Tropsch liquids. The high biogenic carbon Fischer Tropsch liquids may be upgraded to biogenic carbon liquid fuels. Alternatively, the incoming feedstock is processed to selectively recover plastic material from the incoming feedstock to produce a processed feedstock having biogenic carbon content of 50% or less.

A grid-energy firming process and a grid energy firming system. The process comprises alternating between a process for generating electrical energy, and a process for generating gaseous fuels in response to the energy demands of a grid energy system. The system comprises a reactor containing a carbonaceous fuel, and a heat exchanger to extract heat from the flue gas and/or gaseous fuel.

An ASG system for polygeneration with CC includes a devolatilizer that pyrolyzes solid fuel to produce char and gases. A burner adds exothermic heat by high-pressure sub-stoichiometric combustion, a mixing pot causes turbulent flow of the gases to heat received solid fuel, and a riser micronizes resulting friable char. A devolatilizer cyclone separates the micronized char by weight providing micronized char, steam and gases to a gasifier feed and oversized char to the mixing pot. An indirect fluid bed gasifier combustion loop includes a gasifier coupled to the gasifier feed, a steam input to provide oxygen for gasification and to facilitate sand-char separation, and an output for providing syngas. A burner provides POC to a mixing pot which provides hot sand with POC to a POC cyclone via a riser, where the POC cyclone separates sand and POC by weight and provides POC and sand for steam-carbon reaction.

A gasification process may include (a) introducing a liquid hydrocarbon feedstock and at least one of a dry feedstock or a first slurried feedstock into a reactor lower section, wherein the at least one dry feedstock or first slurried feedstock is introduced through two primary feed nozzles while the liquid hydrocarbon feedstock is introduced through at least two secondary feed nozzles; (b) partially combusting the feedstocks in the reactor lower section with a gas stream comprising an oxygen-containing gas or steam to evolve heat and form products comprising hot synthesis gas; (c) passing said hot synthesis gas from step (b) upward into a reactor upper section; (d) and introducing a second slurried feedstock into said reactor upper section, whereby heat from said hot synthesis gas supports reaction of the second slurried feedstock by pyrolysis and gasification reactions.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

An apparatus is provided that receives waste and generates electrical power or thermal energy with minimal NOx emissions. A gasifier is provided that receives the waste and air to produce fuel gas for delivery to a fluidly coupled reformer. The reformer receives the fuel gas, recycled flue gas, and air to auto-thermally produce a reformed fuel gas and destroy fuel gas pollutants at a first temperature without a catalyst. A burner is fluidly coupled to the reformer and receives recycled flue gas and air to oxidize the reformed fuel gas at a second temperature that prevents nitrogen oxide formation, the second temperature being lower than the first temperature. A quench chamber is fluidly coupled to the burner and receives flue gas from the burner for quenching with recycled flue gas. A heat recovery system is fluidly coupled to the reformer, burner, and quench chamber to extract usable energy.

Methods of making fuel are described herein. A method may include providing a first working fluid, a second working fluid, and a third working fluid. The method may also include exposing the first working fluid to a first high voltage electric field to produce a first plasma, exposing the second working fluid to a second high voltage electric field to produce a second plasma, and exposing the third working fluid to a third high voltage electric field to produce a third plasma. The method may also include providing and contacting a carbon-based feedstock with the third plasma, the second plasma, and the first plasma within a processing chamber to form a mixture, cooling the mixture using a heat exchange device to form a cooled mixture, and contacting the cooled mixture with a catalyst to form a fuel.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

An integrated chemical looping combustion (CLC) electrical power generation system and method for diesel fuel combining four primary units including: gasification of diesel to ensure complete conversion of fuel, chemical looping combustion with supported nickel-based oxygen carrier on alumina, gas turbine-based power generation and steam turbine-based power generation is described. An external combustion and a heat recovery steam generator (HRSG) are employed to maximize the efficiency of a gas turbine generator and steam turbine generator. The integrated CLC system provides a clean and efficient diesel fueled power generation plant with high CO.sub.2 recovery.