Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

A two-stage gasification reactor may include a reactor lower section and a reactor upper section. The reactor lower section may include (a) a lower reactor body, (b) two primary feed nozzles, configured to introduce at least one of a dry feedstock or a first slurried feedstock and located on opposing terminal ends of the lower reactor body, and (c) at least two secondary feed nozzles, configured to introduce a liquid hydrocarbon feedstock, located on the lower reactor body. The reactor upper section may include (a) an upper reactor body, (b) at least one upper feed nozzle, configured to introduce at least one of a dry feedstock or a first slurried feedstock, located on the upper reactor body, and (c) an outlet.

A reactor system made up of a single canister or a plurality of separate canister sections for the advanced thermal chemical conversion processing of municipal solid waste (“MSW”), either sorted or unsorted, and autoclaves specially designed to process the waste at suitable temperature and pressure combinations is disclosed. The canister sections can be individually and separately filled with compressed bales of MSW or with selected loose MSW. The reactor system can produce syngas that has an enhanced BTU value, typically between about 300 to 700 BTU/ft.sup.3. The remainder solid waste material generally amounts to approximately 5% of the original MSW volume. This material can then be sorted for metals with the balance being sent to a landfill or other recycling processes depending on its composition.

A method of producing liquid fuel and/or chemicals from a carbonaceous material entails combusting a conditioned syngas in pulse combustion heat exchangers of a steam reformer to help convert carbonaceous material into first reactor product gas which includes carbon monoxide, hydrogen, carbon dioxide and other gases. A portion of the first reactor product gas is transferred to a hydrogen reformer into which additional conditioned syngas is added and a reaction carried out to produce an improved syngas. The improved syngas is then subject to one or more gas clean-up steps to form a new conditioned syngas. A portion of the new conditioned syngas is recycled to be used as the conditioned syngas in the pulse combustion heat exchangers and in the hydrocarbon reformer. A system for carrying out the method include, a steam reformer, a hydrocarbon reformer, first and second gas-cleanup systems, a synthesis system and an upgrading system.

A thermochemical system & method may be configured to convert an organic feedstock to various products. A thermochemical system may include a solid material feed module, a reactor module, an afterburner module, and a solid product finishing module. The various operational parameters (temperature, pressure, etc.) of the various modules may vary depending on the desired products. The product streams may be gaseous, vaporous, liquid, and/or solid.

An ASG system for polygeneration with CC includes a devolatilizer that pyrolyzes solid fuel to produce char and gases. A burner adds exothermic heat by high-pressure sub-stoichiometric combustion, a mixing pot causes turbulent flow of the gases to heat received solid fuel, and a riser micronizes resulting friable char. A devolatilizer cyclone separates the micronized char by weight providing micronized char, steam and gases to a gasifier feed and oversized char to the mixing pot. An indirect fluid bed gasifier combustion loop includes a gasifier coupled to the gasifier feed, a steam input to provide oxygen for gasification and to facilitate sand-char separation, and an output for providing syngas. A burner provides POC to a mixing pot which provides hot sand with POC to a POC cyclone via a riser, where the POC cyclone separates sand and POC by weight and provides POC and sand for steam-carbon reaction.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

A land based or marine vessel based system for generating power from syngas utilizes a feedstock of waste material acquired from waste dumps, municipalities, and/or ports of call of the marine vessel. The marine vessel or land based system can be retrofitted to be fueled by the waste material. The syngas is used to provide propulsive and/or electrical power for the marine vessel or the land based system. The waste material is not just a feedstock for the syngas but is provided with payment from the ports of call to take the waste material away. The marine vessel also collects garbage floating on the waterway along the voyage between the various ports of call for use as feedstock in the production of syngas. The modular syngas generation system further generates H.sub.2 from the syngas. The H.sub.2 generated thereby is used to fuel an H.sub.2 fuel cell for the generation of electrical power.

A method is provided for thermally processing waste to produce steam and generate energy while minimizing air pollutants in a staged thermal reactor. The method includes gasifying the waste to convert the waste to a fuel gas and a substantially carbon free, inert, granulated, sintered mineral ash and reforming the fuel gas auto-thermally to minimize creation of nitrogen oxide when the fuel gas is combusted. The method further includes burning the reformed fuel gas to minimize creation of nitrogen oxide in a flame region of a fuel gas burner and recirculating cooled flue gas to control oxygen content and temperature during the reforming operation and the burning operation. In one example, reforming the fuel gas converts non-molecular nitrogen species into molecular nitrogen in an auto-thermal non-catalytic reformer unit by decomposition reactions promoted by a prevailing reducing gas atmosphere.