Patent classifications
C10J2300/1861
Integrated coal gasification combined power generation process with zero carbon emission
The present disclosure relates to the technical field of coal chemical industry, and particularly discloses an integrated coal gasification combined power generation process with zero carbon emission, the process comprising: pressurizing air for performing air separation to obtain liquid oxygen and liquid nitrogen, wherein the liquid oxygen is used for gasification and power generation, the liquid nitrogen is applied as the coolant for the gasification and power generation, the liquid nitrogen and a part of liquid oxygen stored during the valley period with low electricity load are provided for use during the peak period with high electricity load; the pulverized coal delivered under pressure and high-pressure oxygen enter a coal gasification furnace for gasification, so as to generate high-temperature fuel gas, which subjects to heat exchange and purification, and then the high-pressure fuel gas enters into a combustion gas turbine along with oxygen and recyclable CO.sub.2 for burning and driving an air compressor and a generator to rotate at a high speed; the air compressor compresses the air to a pressure of 0.40.8 MPa, and the generator generates electricity; the high-temperature combustion flue gas performs the supercritical CO.sub.2 power generation, its coolant is liquid oxygen or liquid nitrogen; the heat exchanged combustion fuel gas subsequently perform heat exchange with liquid nitrogen, the liquid nitrogen vaporizes to drive a nitrogen turbine generator for generating electricity, the cooled flue gas is dehydrated and distilled to separate CO.sub.2, a part of CO.sub.2 is used for circulation and temperature control, and another portion of CO.sub.2 is sold outward as liquid CO.sub.2 product. The power generation process provided by the present disclosure not only solves the difficult problems of high water consumption, low power generation efficiency and small range of peak load adjustment capacity of the existing IGCC technology; but also can compress air with high unit volume for energy storage with a high conversion efficiency, and greatly reduce load of the air compressor, thereby perform CO.sub.2 capture and utilization with low-cost, zero NO.sub.x emission and discharging fuel gas at a normal temperature, and significantly improve the power generation efficiency.
PARTICULATE CLASSIFICATION VESSEL HAVING GAS DISTRIBUTOR VALVE FOR RECOVERING CONTAMINANTS FROM BED MATERIAL
A multi-stage product gas generation system converts a carbonaceous material, such as municipal solid waste, into a product gas which may subsequently be converted into a liquid fuel or other material. One or more reactors containing bed material may be used to conduct reactions to effect the conversions. Unreacted inert feedstock contaminants present in the carbonaceous material may be separated from bed material using a portion of the product gas. A heat transfer medium collecting heat from a reaction in one stage may be applied as a reactant input in another, earlier stage.
THERMOCHEMICAL CONVERSION OF BIOMASS
The present invention is directed to a process for the production of a syngas suited for further conversion to fine chemicals and/or automotive fuels from biomass by a thermochemical process conducted in a several steps procedure, said process comprising; a) Providing a stream of biomass material; b) Providing an aqueous alkaline catalyst stream comprising sodium and/or potassium compounds; c) Mixing comminuted biomass and alkaline catalyst and optional additives to form an alkaline biomass slurry or suspension; d) Treating alkaline biomass slurry or suspension in a hydrothermal treatment reactor at a temperature in the range of 200-400 C. and a pressure from 10-500 bar, forming a bio-oil suspension comprising liquefied biomass and spent alkali catalyst; e) Directly or indirectly charging the bio-oil suspension from step d), after optional depressurization to a pressure in the range 10-100 bar, heat exchange and separation of gases, such as CO2, steam and aqueous spent catalyst into a gasification reactor operating in the temperature range of 600-1250 C. thereby forming a syngas and alkali compounds; and f) Separating alkali compounds from a gasification reactor or from syngas and recycling alkali compounds directly or indirectly to be present to treat new biomass in the hydrothermal biomass treatment reactor of step d) and/or recycling aqueous alkali salts to a pulp mill chemicals recovery cycle.
System and method for recovering inert feedstock contaminants from municipal solid waste during gasification
A multi-stage product gas generation system converts a carbonaceous material, such as municipal solid waste, into a product gas which may subsequently be converted into a liquid fuel or other material. One or more reactors containing bed material may be used to conduct reactions to effect the conversions. Unreacted inert feedstock contaminants present in the carbonaceous material may be separated from bed material using a portion of the product gas. A heat transfer medium collecting heat from a reaction in one stage may be applied as a reactant input in another, earlier stage.
Pyrolysis Reactor System and Method
A system for the pyrolysis of a pyrolysis feedstock utilizes a pyrolysis reactor for producing pyrolysis products from the pyrolysis feedstock to be pyrolyzed. An eductor condenser unit in fluid communication with the pyrolysis reactor is used to condense pyrolysis gases. The eductor condenser unit has an eductor assembly having an eductor body that defines a first flow path with a venturi restriction disposed therein for receiving a pressurized coolant fluid and a second flow path for receiving pyrolysis gases from the pyrolysis reactor The second flow path intersects the first flow path so that the received pyrolysis gases are combined with the coolant fluid. The eductor body has a discharge to allow the combined coolant fluid and pyrolysis gases to be discharged together from the eductor. A mixing chamber in fluid communication with the discharge of the eductor to facilitates mixing of the combined coolant fluid and pyrolysis gases, wherein at least a portion of the pyrolysis gases are condensed within the mixing chamber.
Gasification reactor with pipe distributor
A large-scale fluidized bed biogasifier provided for gasifying biosolids. The biogasifier includes a reactor vessel with a pipe distributor and at least two fuel feed inlets for feeding biosolids into the reactor vessel at a desired fuel feed rate of more than 40 tons per day with an average of about 100 tons per day during steady-state operation of the biogasifier. A fluidized bed in the base of the reactor vessel has a cross-sectional area that is proportional to at least the targeted fuel feed rate such that the superficial velocity of gas is in the range of 0.1 m/s (0.33 ft/s) to 3 m/s (9.84 ft/s). In operation, biosolids are heated inside the fluidized bed reactor to a temperature range between 900 F. (482.2 C.) and 1600 F. (871.1 C.).
METHOD AND FACILITY FOR PRODUCING ELECTRICITY FROM AN SRF LOAD
A method and a facility for producing electricity, wherein the following steps are performed: a) supplying a solid recovered fuel, b) producing a raw synthesis gas from the solid recovered fuel, c) purifying the raw synthesis gas in order to generate a synthesis gas in which the reduced concentration of tars determines a dew point of the tars less than or equal to 20 C., d) cleaning the synthesis gas purified in this way in order to obtain a clean synthetic gas, e) lowering the relative humidity of the clean synthesis gas, and f) injecting at least a portion thereof into a gas engine in order to produce electricity.
INTEGRATED COAL GASIFICATION COMBINED POWER GENERATION PROCESS WITH ZERO CARBON EMISSION
The present disclosure relates to the technical field of coal chemical industry, and particularly discloses an integrated coal gasification combined power generation process with zero carbon emission, the process comprising: pressurizing air for performing air separation to obtain liquid oxygen and liquid nitrogen, wherein the liquid oxygen is used for gasification and power generation, the liquid nitrogen is applied as the coolant for the gasification and power generation, the liquid nitrogen and a part of liquid oxygen stored during the valley period with low electricity load are provided for use during the peak period with high electricity load; the pulverized coal delivered under pressure and high-pressure oxygen enter a coal gasification furnace for gasification, so as to generate high-temperature fuel gas, which subjects to heat exchange and purification, and then the high-pressure fuel gas enters into a combustion gas turbine along with oxygen and recyclable CO.sub.2 for burning and driving an air compressor and a generator to rotate at a high speed; the air compressor compresses the air to a pressure of 0.40.8 MPa, and the generator generates electricity; the high-temperature combustion flue gas performs the supercritical CO.sub.2 power generation, its coolant is liquid oxygen or liquid nitrogen; the heat exchanged combustion fuel gas subsequently perform heat exchange with liquid nitrogen, the liquid nitrogen vaporizes to drive a nitrogen turbine generator for generating electricity, the cooled flue gas is dehydrated and distilled to separate CO.sub.2, a part of CO.sub.2 is used for circulation and temperature control, and another portion of CO.sub.2 is sold outward as liquid CO.sub.2 product. The power generation process provided by the present disclosure not only solves the difficult problems of high water consumption, low power generation efficiency and small range of peak load adjustment capacity of the existing IGCC technology; but also can compress air with high unit volume for energy storage with a high conversion efficiency, and greatly reduce load of the air compressor, thereby perform CO.sub.2 capture and utilization with low-cost, zero NO.sub.x emission and discharging fuel gas at a normal temperature, and significantly improve the power generation efficiency.
Gasification Reactor and Method of Gasification
A large-scale fluidized bed biogasifier provided for gasifying biosolids. The biogasifier includes a reactor vessel with a pipe distributor and at least two fuel feed inlets for feeding biosolids into the reactor vessel at a desired fuel feed rate of more than 40 tons per day with an average of about 100 tons per day during steady-state operation of the biogasifier. A fluidized bed in the base of the reactor vessel has a cross-sectional area that is proportional to at least the targeted fuel feed rate such that the superficial velocity of gas is in the range of 0.1 m/s (0.33 ft/s) to 3 m/s (9.84 ft/s). In operation, biosolids are heated inside the fluidized bed reactor to a temperature range between 900 F. (482.2 C.) and 1600 F. (871.1 C.).
Pyrolysis reactor system and method
A system and method for the pyrolysis of a pyrolysis feedstock utilizes a pyrolysis reactor having a pyrolysis conduit and a solids return conduit segment. Each segment is configured with an outlet and an inlet to receive and discharge solid materials that are circulated through the reactor through the different segments. A solids conveyor is disposed within the pyrolysis conduit segment to facilitate conveying solid materials from the solids inlet upward through the pyrolysis conduit segment toward the solids discharge outlet. A pyrolysis feedstock is introduced into the pyrolysis reactor and at least a portion of the feedstock is converted to pyrolysis gases within the pyrolysis conduit segment, which are discharged through a gas outlet.