Energy-efficient gasification-based multi-generation apparatus, facilities, or systems, and methods of modifying existing gasification-based multi-generation apparatus and the various conventional thermal coupling arrangements, are provided. An exemplary gasification-based multi-generation apparatus includes a gasification system configured to generate the raw syngas feed from a carbon-based feedstock. The gasification system includes a gasification plant or facility, a sour water stripping plant or facility comprising a sour water stripper, a gasification reactor, and a gasification system energy management system. The gasification system energy management system comprises a third gasification system process-to-process heat exchanger unit positioned to receive a wastewater bottom stream from the sour water stripper and to receive at least a portion of an oxygen feed to the gasification reactor to provide heat energy to the at least a second portion of the oxygen feed to the gasification reactor and to cool the wastewater bottom stream from the sour water stripper. The sour water stripping plant or facility is integrated into the gasification plant or facility through at least the wastewater bottom stream from the sour water stripper.

The invention relates to novel nitrogen compounds belonging to the family of tertiary diamines of general formula (I) below, wherein R is an alkanediyl radical (CH.sub.2)n- with n=2, 3, 4, 5 or 6.

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The compound according to the invention is for example N,N,N,N-(tetramethyl)-1,6-diamino-2,5-hexanediol or N,N,N,N-(tetramethyl)-1,8-diamino-2,7-octanediol. The invention also relates to the method for preparing them and to their use for removing acid compounds contained in a gaseous effluent.

A process and system for the treatment of solid waste based on a temperature gradient generated by two distinct thermal sources, notably of a sequenced technological assembly, is able to process solid waste of any class, which operates through a reactor (1) having two chambers (2 and 3), each having a thermal source (4 and 5), where a thermal gradient is generated, followed by a heat exchanger (6) where gases are abruptly cooled and taken to a neutralizing tank (7), for then being directed to an activated charcoal filter (8), due to the action of a blower (9), before finally entering a burner (10) that works under electrical discharges, passing through a catalytic converter (11) and chimney (12) where it is extravasated into the completely inert atmosphere.

Energy-efficient gasification-based multi-generation apparatus, facilities, or systems, and methods of modifying existing gasification-based multi-generation apparatus and the various conventional thermal coupling arrangements, are provided. Apparatus for managing waste heat recovery through integration of a gasification-based multi-generation facility or other multi-generation system with a hydrocarbon refining facility or other hydrocarbon refining system and methods of providing the respective integration are also provided. An exemplary apparatus includes an integrated site energy management system configured according to one or more process-based thermal coupling schemes comprising one or more thermal coupling arrangements between a gasification-based multi-generation system or facility and a hydrocarbon refining system or facility. The gasification-based multi-generation system or facility can include an acid gas removal system or plant configured to remove acidic contaminants from a raw syngas feed to thereby provide a treated syngas feed, the acid gas removal system or plant containing a separation section including a solvent regenerator, and a gasification system configured to generate the raw syngas feed from a carbon-based feedstock. The hydrocarbon refining system or facility can include an aromatics system or plant containing a xylene products separation section including one or more of the following: an Extract column and a Raffinate column. The integrated site energy management system can include a hot-water system extending between the separation section of the acid gas removal system or plant and the xylene products separation section of the aromatics system or plant, and a plurality of added heat exchanger units providing various advanced thermal coupling arrangements.

The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures containing hydrogen sulfide. The aqueous alkanolamine solution comprises (i) an amino compound with the formula:

R.sup.1R.sup.2NCH.sub.2CH(OH)CH.sub.2OH

wherein R.sup.1 and R.sup.2 independently represent lower alkyl groups of 1 to 3 carbon atoms, (ii) piperazine, and (iii) optionally a physical solvent, wherein said solution does not contain a strong acid. Further, the present invention relates to a process for removing hydrogen sulfide from a gaseous mixture containing hydrogen sulfide, and additionally other acid gases, if present, for example carbon dioxide, comprising the step of contacting the gaseous mixture contain hydrogen sulfide with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140 F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.

A gasification system includes a scrubber in communication with a particulate removal subsystem and a quench sub-system.

A method and apparatus for continuously treating acid gases including recovering absorbent chemicals by introducing streams leaving a regenerator and/or leaving an absorber into a static mixing zone wherein supplemental washing water is added to recover absorbent chemicals. Improvements to the prior art methods are provided where one or more absorbent chemical recovery units are included to increase the amount of recovered absorbent chemicals exiting the regenerator and/or exiting the absorber are increased and/or maximized. Absorbent chemical recovery units can include mixing units where liquid is added to the stream of sour gas and absorbent chemical to mix with and absorb the absorbent chemical from the stream.

Disclosed are methods for accommodating changes in the conditions of partial oxidation of hydrocarbonaceous feedstock by changing characteristics of the hot oxygen used in the partial oxidation.

A method of removing impurities from black water associated with a gasifier includes adding a flocculant to the black water to create a black water and flocculant mixture, settling the black water and flocculant mixture in a gravity settling device to separate the black water and flocculant mixture into clarified water, a froth phase, and a heavy phase, the froth phase comprising soot, water, and air or gas, the heavy phase comprising soot and water, drawing off the clarified water from the settled black water and flocculant mixture, collecting a dilute slurry comprising the froth phase and the heavy phase, and phase separating the dilute slurry in a high-speed centrifuge to provide additional clarified water and a concentrated slurry, wherein the black water is obtained from wet gas scrubbing of syngas.

Methods and systems are disclosed for improving the efficiency and reducing the carbon intensity of transportation fuels produced from heavy oil extracted with the steam injection process, by replacing natural gas from fossil fuel sources with a substitute renewable gas produced from solid carbonaceous materials while co-producing a solid carbonaceous byproduct.