A CO shift catalyst according to the present invention reforms carbon monoxide (CO) in gas. The CO shift catalyst has one of molybdenum (Mo) or iron (Fe) as a main component and has an active ingredient having one of nickel (Ni) or ruthenium (Ru) as an accessory component and one or two or more kinds of oxides from among titanium (Ti), zirconium (Zr), and cerium (Ce) for supporting the active ingredient as a support. The temperature at the time of manufacturing and firing the catalyst is equal to or higher than 550° C.

A temperature measurement system for a gasifier may employ a first stage gasifier with a refractory wall that defines a first stage gasifier volume. A protruding refractory brick may protrude from the first stage refractory wall and into a gaseous flow path of the first stage gasifier volume. The temperature sensor may reside completely through the refractory wall, which may be a plurality of brick layers, except for a tip end of a temperature sensor that may reside in a blind or non-through hole within the protruding refractory brick. The protruding refractory brick protrudes beyond a normal wall surface of the plurality of brick layers that defines the first stage gasifier volume. The protruding refractory brick may have a face that forms an angle that is not 90 degrees, such as 45 degrees, relative to the gaseous flow path of the fluid stream through the first stage gasifier volume.

Disclosed are methods for accommodating changes in the conditions of partial oxidation of hydrocarbonaceous feedstock by changing characteristics of the hot oxygen used in the partial oxidation.

The present invention provides a process for obtaining solid recovered fuel and synthesis gas from a waste-based feedstock, comprising the steps of: I. converting the feedstock into a solid recovered fuel by means of a number of parameters pertaining to waste sorting, selection, comminution and/or screening; II. gasifying under suitable reaction conditions at least a portion of the solid recovered fuel to produce synthesis gas and by-product(s); and III. optionally cleaning at least a portion of the synthesis gas to produce clean synthesis gas and wastewater, wherein one or more of the solid recovered fuel, synthesis gas, and by-product(s) of the gasification are analysed during operation of the process, and wherein data from said analysis is used to control one or more parameters of step I) in order to influence reaction conditions in step II, and optionally step III).

The present invention provides a new hydrogen chloride removing agent that exhibits a good hydrogen chloride removal effect at a relatively low temperature. The present invention preferably provides a new hydrogen chloride removing agent for removing hydrogen chloride contained in a hydrogen-chloride-containing gas, such as a pyrolysis gas, a combustion exhaust gas, a dry distillation gas, etc., especially hydrogen chloride contained in a biomass pyrolysis gas. The present invention relates to a hydrogen chloride removing agent characterized by containing a mixture of a calcium carbonate and an imogolite and/or a synthetic imogolite, and relates to a method for removing, by using said hydrogen chloride removing agent, hydrogen chloride contained in a hydrogen-chloride-containing gas, especially hydrogen chloride contained in a biomass pyrolysis gas.

Apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Syngas exits the gasifier which is coupled to a thermal oxidizer and combusts at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat is recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger coupled with the thermal oxidizer. Various methods inject moisture into the gas stream, controlling temperature through evaporative cooling and/or injecting chemicals that react with gas stream components. Cooled flue gas mixes with hydrated lime capturing decomposed PFAS molecules with spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements, eliminating PFAS from wastewater biosolids and controlling emissions in the resulting flue gas.

A process and apparatus for producing pure hydrogen from a syngas generated by the high temperature gasification of municipal, agricultural or industrial derived wastes. The process is able to make pure hydrogen to be further reacted with nitrogen to make ammonia and urea.

The invention relates to a gas scrubbing process and plant for purifying raw synthesis gas by physical absorption in methanol. A raw synthesis gas stream which includes hydrogen and carbon monoxide as desired constituents and water and acid gases as undesired constituents is admixed with methanol and subsequently cooled below the freezing point of water. According to the invention a liquid phase including methanol and water is separated from the cooled raw synthesis gas stream. Acid gases are removed from the remaining gaseous phase by physical absorption in methanol at elevated pressure. Separating the water from the raw synthesis gas stream before the absorption of the acid gases prevents larger amounts of water passing into the methanol circuit of the gas scrubbing process. This achieves savings in resources and certain plant parts may be smaller than is customary.

The invention relates to a method and to a device for performing a process (P) having at least one heat-consuming process step (F). A first fluid (2), which arises in the process and contains acid gases and water vapor, is cooled indirectly against a second fluid (7), an acidic condensate thus being formed. The invention is characterized in that the first fluid (2) is cooled in at least two successive steps (E1, E2), between which heat for use in the heat-consuming process step (V) is indirectly drawn from the second fluid (10).

A high-temperature plastic pyrolysis process that can produce high yields of ethylene, propylene and other light olefins from waste plastics is disclosed. The plastic feed is pyrolyzed at a high temperature of about 600 to about 900° C. directly to monomers, such as ethylene and propylene. During pyrolysis, the plastic feed is contacted with a diluent gas stream at a mole ratio of carbon feed to diluent gas of 0.6 to 20.