Embodiments disclosed relate to a debutanizer with a dividing wall. The configuration of the debutanizer includes having a feed section, a top section, a bottom section, and a draw-off section. The debutanizer produces a C4s product, a C5s product and a natural gasoline (NG) product from a C4+s feed. The dividing wall is configured such that an upper portion of the dividing wall is positioned off-set from a vertical centerline and a lower portion of the dividing wall is positioned along the vertical centerline of the debutanizer. A process of use of the debutanizer is also disclosed. A natural gas liquids (NGL) system that includes parallel debutanizers, each with a dividing wall, and a process of use of such system, is also disclosed.

Described are methods for shortening the combustion delay of ammonia fuels and reducing the amount of NO formed during the combustion process. The methods include mixing ammonia with hydrogen peroxide and water to form a fuel mixture and then combusting the fuel mixture. Methods of powering an internal combustion engine with ammonia fuels are also described.

A method for reducing the tendency of a hydrocarbon fluid to oxidise comprises combining an additive having a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms to form a secondary amine and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon with the hydrocarbon fluid. The additive may also be used for protecting a system in which a hydrocarbon fluid is used from the effects of oxidation.

An octane-enhancing additive includes a mixed butanol composition, sec-butyl ether, methanol, methyl tert-butyl ether, and a C4-dimer, the mixed butanol composition comprising sec-butanol and tert-butanol, and the C4-dimer comprising di-isobutylene, 2,2,4 trimethylpentane, 2,3,3 trimethylpentane, or a combination comprising at least one of the foregoing.

Unleaded aviation gasoline. An aviation gasoline fuel blend includes an unleaded aviation gasoline base fuel, with an effective amount of selected alkyl benzenes to improve the functional engine performance to avoid harmful detonation sufficient to meet or exceed selected standards for detonation performance requirements in full scale aircraft piston spark ignition engines designed for use with Grade 100LL avgas. Suitable alkylated benzenes may include a mixture of xylene isomers. Aromatic amines, such as m-toluidine, may also be added to increase MON. Base fuels may be a high quality aviation alkylate, or may be a commercial iso-octane, or a mixture of high quality aviation alkylate enhanced by iso-octane, or by commercial iso-octane mixtures, and may include iso-pentane or butane or both iso-pentane and butane in sufficient quantity to provide appropriate vapor pressure for the final fuel blend.

The present disclosure provides a fuel composition that includes hydrocarbon-based fuel boiling in the gasoline or diesel range; an amine-based detergent given by formula R.sub.1—O—(CH.sub.2).sub.m—NHR.sub.2, wherein the additive is present in about 10 ppm to about 750 ppm by weight based on total weight of the fuel composition; wherein R.sub.1 is a hydrocarbylgroup having 8 to 20 carbons, R.sub.2 is hydrogen or (CH.sub.2).sub.nNH.sub.2 moiety, and wherein m, n are independently integers having a value of 3 or greater; and one or more nitrogen-containing detergent.

Processes for producing high-octane-number fuel components, particularly those useful for AvGas blends, can be advantageously produced from hydrocarbon feed streams comprising C8+ aromatic hydrocarbons. Such feed streams may be produced by, among others, separation and other optional post-processing of an effluent produced from a steam cracker (e.g., a liquid feed steam cracker cracking liquid feeds such as naphtha and/or other crude fractions, a gas steam cracker cracking gas feeds such as ethane and/or propane), hydrocarbon reforming of a crude fraction or steam cracker effluent fraction, C6-C7 aromatic hydrocarbon methylation, transalkylation between C6-C7 aromatic hydrocarbons and C9+ aromatic hydrocarbons, isomerization of C8 aromatic hydrocarbons, and toluene disproportionation processes.

A fuel additive for fuel formulations comprising calcium sulfonates in an amount effective to limit or eliminate valve seat recession in engines utilizing such fuel formulations. The fuel additive may also include a detergent, particularly in an amount to enhance the VSR limiting effect of the calcium sulfonates. Also included are fuel formulations containing calcium sulfonates in a concentration effective to limit vale seat recession in engines utilizing the fuel formulations. Methods for treating VSR in piston engines are also provided.

The present disclosure provides a method for catalytic conversion of waste plastic into liquid fuel. The method comprises thermally decomposing the waste plastic at a temperature in the range of 350 to 650° C. and under a pressure in the range of 0.0010 psi to 0.030 psi, to obtain a gaseous stream. The gaseous stream is further subjected to four stage sequential cooling to a temperature in the range of −5 to −15° C. to obtain a gas-liquid mixture comprising a gaseous fraction and a liquid fraction. The gas-liquid mixture is fed to the gas-liquid separator to obtain the gaseous fraction comprising C1 to C4 hydrocarbons and the liquid fraction comprising liquid fuel. The method of the present disclosure is simple, economical and energy efficient, which provides a high value liquid fuel with enhanced yield.

The present invention relates to a combustion additive comprising a colloidal solution containing dispersed fine metal particles. The present invention also relates to a method for producing the colloid. More particularly the present teaching relates to a combustion additive having a colloid, wherein the colloid comprises metal particles providing in an alkaline aqueous solution, the metal particles being dispersed within that solution and having an average diameter in the range of 30 nm to 30 μm. The colloid can partly/fully substitute water of a water injection system or used as an air humidification component for combustion.