A process for the production of charcoal comprising the steps of: a) feeding biomass, in particular wood chips, into a pyrolysis unit, in which the wood chips are pyrolyzed into a full stream comprising solid, liquid and gaseous material, b) feeding the full stream and a gasifying agent into an oxidation unit, wherein the full stream is oxidized at least partially and transported pneumatically, c) feeding the partially oxidized full stream from the oxidation unit into a reduction unit arranged essentially vertically, the material outlet of the oxidation unit being connected to the reduction unit, with the cross-section of the reduction unit increasing as the distance from the material outlet of the oxidation unit increases, the flow rate of the full stream in the reduction unit being adapted to the material of the full stream and to the shape of the flow cross-section of the reduction unit in such a way that a stable fixed bed kept in suspension is formed in the reduction unit, d) removing the raw charcoal from the reduction unit via an overflow, e) separating gaseous components in a hot gas filter and collecting the charcoal, and f) quenching the collected charcoal with water.

A method and an apparatus for manufacturing, with thermal treatment, biocoal which is non-energent, such as functional as a heat sink, by using a conveyor arrangement housed in an essentially Thompson Converter type process space. A to-be-processed feedstock is conveyed in the process space with the conveyor arrangement, which is closed relative thereto, in a longitudinal direction of the process space. A pyrolysis gas, generated from the to-be-processed feedstock present inside the conveyor arrangement as a result of heat transferring from the process space thereto, is conducted into a combustion chamber included in the process space for burning the gas, a thereby generated flue gas being removed from the process space by a discharge arrangement and a resulting non-energent biocoal being removed from the conveyor arrangement for further processing.

A system of treating waste materials (28) is provided, and includes a waste treatment reactor (10) configured to treat the waste materials. The waste treatment reactor (10) has a cylindrical body (12) having an inlet (14) to receive the waste materials, a waste chamber (26) to store the waste materials, and an outlet (16) configured to deliver treated waste materials out of the waste chamber. A bundle reactor (38) has the waste treatment reactor and performs a waste treatment for the waste materials stored in the waste chamber. An energy recirculation assembly (40) is connected to the bundle reactor and recirculates thermal energy associated with the bundle reactor during the waste treatment. The energy recirculation assembly (40) has a heating unit (42) to heat a first region of the bundle reactor, and a cooling unit (44) to cool a second region of the bundle reactor.

The present invention relates to a multifunctional spontaneous combustion inhibitor for bituminous coal in the form of a foam concentrate, which may inhibit the spontaneous combustion of bituminous coal, prevent the scattering of bituminous coal, prevent the occurrence of problems due to spontaneous combustion, such as a power plant operation failure, bituminous coal waste, and odor generation, enables a bituminous coal power plant to be operated economically, safely and environmentally friendlily through the use of inexpensive bituminous coal, and may be used even at −20° C. by improving the pour point thereof. The present invention is characterized in that a spontaneous combustion inhibitor is prepared in the form of a water-soluble foam concentrate by using an antioxidant, a volatile fraction activation inhibitor, and an emulsifier compound, is mixed with water and air, and is distributed and applied to bituminous coal in a foamed state.

A method and apparatus for producing a solid biofuel from hydrocarbonaceous feedstock is described. The process includes loading a hydrocarbonaceous feedstock into a reactor vessel, adding an aqueous catalyst solution into the reactor vessel, wherein the catalyst solution resides at the bottom of the reactor vessel under the hydrocarbonaceous feedstock position, heating the reactor vessel at or above 170° C. to catalyze a reaction of hydrocarbonaceous feedstock under saturated steam conditions for a time sufficient to yield a polymeric biofuel, and isolating the polymeric biofuel from the reactor vessel.

A method, a system, and an apparatus of certain embodiments are provided to recover water and carbon dioxide from combustion emissions. The recovery includes, among other things, electrolysis and carbon dioxide capture in a suitable solvent. The recovered water and carbon dioxide are subject to reaction, such as a catalytic methanation reaction, to generate at least methane.

A method for fabricating a coconut shell heat producing device. Heat is applied to coconut shells to form carbonized coconut charcoal pieces. The charcoal pieces are ground to form coconut charcoal powder. A moistened blend is created that includes the coconut charcoal powder, a binder and water. The moistened blend is placed into a press. Pressure is applied in the press to form the moistened blend into the heat providing device. The heat providing device includes at least one hole extending through the device. In a preferred embodiment the heat producing device is a coconut shell charcoal log.

A method is disclosed for producing a mechanically stable, energy dense and water-resistant biomass product. By utilizing a unique two-step heating process in combination with mechanical compression, the resulting biomass product retains its physical shape and strength after immersion in ambient water for many hours. The treatment is effective for a variety of cellulosic biomass materials including forest slash wood.

Embodiments of the disclosure provide a system and method for producing a linear alpha olefin. A disulfide, a hydrogen donating compound, and water are combined to produce a mixture. The mixture is introduced to a reactor operated at a pressure equal to or greater than 22.06 MPa and a temperature equal to or greater than 374 deg. C to produce an effluent stream. The effluent stream is separated to produce a product stream including the linear alpha olefin. The disulfide can be a compound of formula R—S—S—R′ where R is a first alkyl group having carbon atoms ranging from 1 to 12 and R′ is a second alkyl group having carbon atoms ranging from 5 to 12. The hydrogen donating compound can include a partially hydrogenated multi-ring aromatic compound.

Embodiments of the disclosure provide a system and method for producing a linear alpha olefin. A disulfide, a hydrogen donating compound, and water are combined to produce a mixture. The mixture is introduced to a reactor operated at a pressure equal to or greater than 22.06 MPa and a temperature equal to or greater than 374 deg. C. to produce an effluent stream. The effluent stream is separated to produce a product stream including the linear alpha olefin. The disulfide can be a compound of formula R—S—S—R′ where R is a first alkyl group having carbon atoms ranging from 1 to 12 and R′ is a second alkyl group having carbon atoms ranging from 5 to 12. The hydrogen donating compound can include a partially hydrogenated multi-ring aromatic compound.