Embodiments provide a method of compound removal from a fluid. The method includes contacting one or more metal organic framework (MOF) compositions with a fluid and sorbing one or more compounds, such as CO.sub.2, H.sub.2S and condensable hydrocarbons. One or more of CO.sub.2, H.sub.2S and condensable hydrocarbons can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF.

Methods and systems for producing carbon-negative hydrogen and renewable natural gas from biomass are included herein. In an embodiment, the method may include gasifying biomass in a gasification unit to form a first stream comprising syngas. The syngas may include methane, hydrogen, carbon dioxide, carbon monoxide, ethylene, and water. The method may also include reacting the carbon monoxide with water in the presence of a catalyst to form a second stream. The second stream may include a greater hydrogen concentration than the first stream. The method may further include separating at least a portion of the second stream to form a hydrogen stream and a natural gas stream. The hydrogen stream may have a greater concentration of hydrogen than the second stream. The natural gas stream may have a greater concentration of methane than the second stream.

A method for removing contaminants from a gas stream including contacting a gas stream comprising hydrocarbons and sulfur contaminants with a modified nanocomposite adsorbent. Also provided are compositions and processes for forming compositions of a modified nanocomposite adsorbent composition for removing sulfur contaminants from a hydrocarbon stream. Additionally, provided is system for removing sulfur impurities from a gaseous hydrocarbon stream, where the system includes a plurality of adsorbent vessels arranged in series, where the adsorbent vessels include an emulsion of a modified nanocomposite adsorbent composition.

Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H.sub.2S, H.sub.2O, and CO.sub.2. Methods include capturing one or more of H.sub.2S, H.sub.2O, and CO.sub.2 from fluid compositions, such as natural gas.

A method for recovering sulfur within a gas processing system is described herein. The method includes contacting a natural gas stream including an acid gas with a solvent stream within a co-current contacting system to produce a sweetened natural gas stream and a rich solvent stream including an absorbed acid gas. The method also includes removing the absorbed acid gas from the rich solvent stream within a regenerator to produce a concentrated acid gas stream and a lean solvent stream. The method further includes recovering elemental sulfur from hydrogen sulfide (H.sub.2S) within the concentrated acid gas stream via a sulfur recovery unit.

Disclosed herein are processes and systems for removing heavy C5+ hydrocarbon components from a natural gas feed gas by subjecting the natural gas feed gas stream to an adsorber. The adsorber in the processes and systems described herein operating at a pressure that may be associated with improved adsorption capacity and longer breakthrough time.

A method for capturing CO.sub.2 from a gas stream using a metal organic framework (MOF) based physisorbent CO.sub.2 concentrator is provided. In the method, MOF material is pretreated, a gas stream is then introduced into the CO.sub.2 concentrator which comprises the pretreated MOF material. CO.sub.2 from the gas stream is captured with the CO.sub.2 concentrator to generate a CO.sub.2-free stream, which is discharged the from the CO.sub.2 concentrator into the atmosphere. Introduction of the gas stream into the CO.sub.2 concentrator is stopped when the pretreated MOF material becomes saturated with CO.sub.2. The CO.sub.2 concentrator with the saturated MOF material is then regenerated by introducing hot air, hot nitrogen, vacuum, or a combination thereof into the CO.sub.2 concentrator thereby generating a CO.sub.2-rich stream. The CO.sub.2-rich stream is diverted for purification and the regenerated CO.sub.2 concentrator is recycled for future capture of CO.sub.2.

The present invention relates to a method for modifying the crystalline inorganic framework of an adsorbent with coatings to provide rate selectivity for one gas over others is described. The method described herein narrows the effective pore size of crystalline porous solids with pores less than about 5 Å for rate selective separations. This method of the invention comprises treating the hydrated or partially hydrated zeolite with a silicone derived binding agent followed by subsequent heat treatment. The additive content and treatment are adjusted to match effective pore size to specific separations. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products.

Process for producing biomethane from a biogas stream including methane, carbon dioxide and at least one impurity chosen from ammonia, volatile organic compounds, water, sulfur-based impurities (H.sub.2S) and siloxanes. A biogas stream is dried, the at least one impurity is at least partially removed by solidification and removal of the impurity. The methane and the carbon dioxide contained in the biogas obtained from the second step are separated so as to produce a biomethane stream and a CO.sub.2 stream.

Embodiments may include a hydrogen sulfide scrubber system that includes a charging chamber, a reaction vessel, and a treated gas trap. Embodiments may include a mobile vehicle, vessel, or platform that includes a mobile vehicle, vessel, or platform with a mounted hydrogen sulfide scrubber system. The hydrogen sulfide scrubber system is configured as previously described. Embodiments may include a method of using a hydrogen sulfide scrubber system.