C10L2290/543

Configurations and method of integrating a gas to liquids (GTL) plant in a refinery

A crude oil processing plant that comprises a Fischer-Tropsch reactor is disclosed. The crude oil processing plant comprises a crude oil processing section and a hydrogen production section. The hydrogen production section is coupled to a hydrocracker in the crude oil processing section to deliver a high purity hydrogen stream. The Fischer-Tropsch reactor receives a syngas stream from the hydrogen production section and produces a hydrocarbon stream. When light crude oil is processed, the hydrocracker typically has excess capacities to upgrade the hydrocarbon stream from the Fischer-Tropsch reactor.

Butanol purification

Provided are methods for removing one or more components from a butanol based composition. The methods comprise providing a butanol based composition comprising one or more components, targeting at least one component or a combination thereof for reduction, and processing said butanol based composition such that the at least one targeted component is substantially removed. The butanol based composition can, for example, be bio-produced.

Fuel compositions from light tight oils and high sulfur fuel oils
11198826 · 2021-12-14 · ·

Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

Process for dehydrating a hydrocarbon-based gas
11198091 · 2021-12-14 · ·

The present invention proposes to use a dry stream which is rich in C4 to C10 hydrocarbons as stripping agent for improving the regeneration of the liquid desiccant according to the invention. This dry stream rich in C4 to C10 hydrocarbons is extracted from the gas derived from the dehydration, for example during a step of extraction of NGL located downstream of the gas dehydration unit. The stream of stripping agent recovered at the outlet of the liquid desiccant regeneration unit may be recycled into the process of the invention or sent to a unit external to the process according to the invention. For example, this stream of stripping agent recovered at the outlet of the regeneration unit is sent to a unit which can receive wet condensates, such as a three-phase separation unit at the inlet of a crude gas processing plant, a condensate stabilization unit, etc.

Processes For Producing High Biogenic Concentration Fischer-Tropsch Liquids Derived From Municipal Solid Wastes (MSW) Feedstocks
20210380893 · 2021-12-09 ·

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

System for high-value utilization of organic solid waste

A system for high-value utilization of organic solid waste includes an anaerobic digestion unit, a biogas measurement and collection unit and a methane purification and liquefaction unit. The anaerobic digestion unit includes an organic solid waste pretreatment system and an anaerobic digestion device. The biogas measurement and collection unit includes a gas flow meter and a high-pressure biogas collection device. The methane purification and liquefaction unit includes a high-pressure separation tank, a liquefaction pretreatment system, a heavy hydrocarbon and benzene removal device, a two-stage rectification system, a low-temperature pressure liquid storage tank device and a buffer storage tank. The organic solid waste undergoes an anaerobic digestion treatment to produce methane followed by collection, purification and liquefaction.

Fuel compositions from light tight oils and high sulfur fuel oils
11370981 · 2022-06-28 · ·

Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

HYDROTHERMAL LIQUEFACTION SYSTEM

A hydrothermal liquefaction (HTL) system can comprise a biomass slurry source, a first pump in fluid communication with the slurry source and configured to pressurize a biomass slurry stream from the slurry source to a first pressure, a first heat exchanger in fluid communication with the first pump and configured to heat a slurry stream received from the first pump to a first temperature, a second pump in fluid communication with the first heat exchanger and configured to pressurize a slurry stream received from the first heat exchanger to a second pressure higher than the first pressure, a second heat exchanger in fluid communication with the second pump and configured to heat a slurry stream received from the second pump to a second temperature higher than the first temperature, and a HTL reactor configured to produce biocrude from a slurry stream received from the second heat exchanger.

OPERATION OF NATURAL GAS LIQUIDS STABILIZER COLUMN

A method for improved operation of a natural gas liquids stabilizer column, particularly a small-scale, is provided. The method can include the steps of: introducing a first feed stream comprising heavy hydrocarbons and natural gas to a stabilizer column to produce a top gas and a bottoms liquid, wherein the top gas has a higher concentration of natural gas as compared to the first feed stream, and the bottoms liquid has a higher concentration of heavy hydrocarbons as compared to the first feed stream; introducing a second feed stream into the stabilizer column, wherein the second feed stream has a higher concentration of natural gas as compared to the first feed stream, wherein the second feed stream is at a warmer temperature than the first feed stream when introduced into the stabilizer column, wherein the second feed stream is a gaseous stream; withdrawing the top gas from a top portion of the stabilizer column; withdrawing the bottoms liquid from a bottom portion of the stabilizer column; and sending at least a portion of the bottoms liquid to a liquid storage tank.

Coal ash treatment system and method

A system and method for producing a modified coal ash involves collecting a bulk quantity of such coal ash, generally after it has been produced or landfilled, or is otherwise at temperatures closer to ambient, as opposed to power plant operational temperatures. In one possible implementation, the method herein involves removing carbon from the coal ash, such removal occurring by exposing the carbon to indirect heat, that is, externally-applied heat. For coal ashes with higher ash content. This removal is accomplished by subjecting the coal ash stream to heat, in one implementation, ranging between 850° F. and 1200° F., and such heat exposure occurring from about 10 minutes to about 30 minutes. The range of exposure time for the coal ash is determined so as to reduce the LOI from its initial level to a level acceptable for intended re-use or recycling. In one application, the LOI of carbon in the ash is reduced to 3% or less carbon. Upon completion of the range of the exposure time, the coal ash stream is removed from the sublimation heat, thereby forming a modified coal ash.