Compounds having the formula (F-I) below are provided herein:

##STR00001##

wherein R.sup.1 and R.sup.2 at each occurrence are independently a C.sub.1-C.sub.5000 alkyl group; R.sup.3 at each occurrence is independently hydrogen or a C.sub.1-C.sub.5000 alkyl group; R.sup.4 is a C.sub.1-C.sub.50 alkyl group or an unsubstituted or substituted phenyl group; R.sup.5 at each occurrence is independently hydrogen or a C.sub.1-C.sub.30 alkyl group; n is 1, 2, 3, or 4; and m+n is 5. Processes for preparing compounds of formula (F-I) as well as base stock and lubricant compositions containing compounds of formula (F-I) are also provided.

Compounds having the formula (F-I) below are provided herein:

##STR00001##

wherein R.sup.1 and R.sup.2 at each occurrence are independently a C.sub.1-C.sub.5000 alkyl group; R.sup.3 at each occurrence is independently hydrogen or a C.sub.1-C.sub.5000 alkyl group; R.sup.4 is a C.sub.1-C.sub.50 alkyl group or an unsubstituted or substituted phenyl group; R.sup.5 at each occurrence is independently hydrogen or a C.sub.1-C.sub.30 alkyl group; n is 1, 2, 3, or 4; and m+n is 5. Processes for preparing compounds of formula (F-I) as well as base stock and lubricant compositions containing compounds of formula (F-I) are also provided.

In one embodiment, a retarded acid system comprises an aqueous acid and a retarding surfactant. The aqueous acid may comprise from 5 wt. % to 25 wt. % of a strong acid, that is, an acid having a K.sub.a greater than or equal to 0.01. The aqueous acid may further comprise from 75 wt. % to 95 wt. % water. The retarding surfactant may have the general chemical formula R(OC.sub.2H.sub.4).sub.XOH where R is a hydrocarbon having from 11 to 15 carbon atoms and x is an integer from 6 to 10. The retarding surfactant may have a hydrophilic-lipophilic balance from 8 to 16.

In one embodiment, a retarded acid system comprises an aqueous acid and a retarding surfactant. The aqueous acid may comprise from 5 wt. % to 25 wt. % of a strong acid, that is, an acid having a K.sub.a greater than or equal to 0.01. The aqueous acid may further comprise from 75 wt. % to 95 wt. % water. The retarding surfactant may have the general chemical formula R(OC.sub.2H.sub.4).sub.XOH where R is a hydrocarbon having from 11 to 15 carbon atoms and x is an integer from 6 to 10. The retarding surfactant may have a hydrophilic-lipophilic balance from 8 to 16.

The present invention relates to a lubricating oil composition containing a base oil (A) containing an olefin-based polymer (A1) having an area ratio of a peak derived from a hydride (A11) of a decene trimer of 80% or more relative to 100% of a total area of peaks derived from the olefin-based polymer (A1) detected in a chromatogram and having predetermined kinematic viscosity, flash point, and pour point, a viscosity index improver (B) containing a comb-shaped polymer (B1), and an organic molybdenum-based compound (C), in which the content of the comb-shaped polymer (B1) is regulated within a specified range and having a HTHS viscosity at each of 150 C. and 50 C. of the lubricating oil composition and a NOACK value in predetermined ranges, respectively.

The present invention relates to a lubricating oil composition containing a base oil (A) containing an olefin-based polymer (A1) having an area ratio of a peak derived from a hydride (A11) of a decene trimer of 80% or more relative to 100% of a total area of peaks derived from the olefin-based polymer (A1) detected in a chromatogram and having predetermined kinematic viscosity, flash point, and pour point, a viscosity index improver (B) containing a comb-shaped polymer (B1), and an organic molybdenum-based compound (C), in which the content of the comb-shaped polymer (B1) is regulated within a specified range and having a HTHS viscosity at each of 150 C. and 50 C. of the lubricating oil composition and a NOACK value in predetermined ranges, respectively.

A lubricating grease composition containing a base oil having a kinematic viscosity of 10 mm.sup.2/s or more and 60 mm.sup.2/s or less at 40 C.; a thickener containing at least one soap selected from a metal soap and a metal complex soap; and a solid lubricant containing porous polyamide particles. An amount of the porous polyamide particles blended is 1% by mass or more and 20% by mass or less based on a total mass of the lubricating grease composition.

A lubricating grease composition containing a base oil having a kinematic viscosity of 10 mm.sup.2/s or more and 60 mm.sup.2/s or less at 40 C.; a thickener containing at least one soap selected from a metal soap and a metal complex soap; and a solid lubricant containing porous polyamide particles. An amount of the porous polyamide particles blended is 1% by mass or more and 20% by mass or less based on a total mass of the lubricating grease composition.

Disclosed herein is a mixed composition for a refrigerator, which contains: a refrigerant containing at least one unsaturated fluorinated hydrocarbon compound selected from compounds represented by the following molecular formula (1): C.sub.pF.sub.rH.sub.s, and a refrigerator lubricating oil containing, as a major component, a polyoxyalkylene glycol compound represented by the following general formula (2), and containing an amine compound in an amount of 1.0% by mass or more based on the total amount of the refrigerator lubricating oil: R.sup.1[(OR.sup.2).sub.mOR.sup.3].sub.n (2). According to the present disclosure, a mixed composition for a refrigerator can be provided that has a less possibility of autoignition under a high temperature environment even in an unexpected leakage thereof in a refrigerator using a refrigerant containing a slightly flammable refrigerant, and a refrigerator lubricating oil can be provided that is capable of being applied to the mixed composition for a refrigerator.

Disclosed herein is a mixed composition for a refrigerator, which contains: a refrigerant containing at least one unsaturated fluorinated hydrocarbon compound selected from compounds represented by the following molecular formula (1): C.sub.pF.sub.rH.sub.s, and a refrigerator lubricating oil containing, as a major component, a polyoxyalkylene glycol compound represented by the following general formula (2), and containing an amine compound in an amount of 1.0% by mass or more based on the total amount of the refrigerator lubricating oil: R.sup.1[(OR.sup.2).sub.mOR.sup.3].sub.n (2). According to the present disclosure, a mixed composition for a refrigerator can be provided that has a less possibility of autoignition under a high temperature environment even in an unexpected leakage thereof in a refrigerator using a refrigerant containing a slightly flammable refrigerant, and a refrigerator lubricating oil can be provided that is capable of being applied to the mixed composition for a refrigerator.