Patent classifications
C10M105/70
IONIC LIQUID, LUBRICANT, AND MAGNETIC RECORDING MEDIUM
A lubricant, which includes an ionic liquid including a conjugate base and a conjugate acid, wherein the conjugate acid is represented by General Formula (A) below, and wherein a pKa of an acid that is a source of the conjugate base in acetonitrile is 10 or less,
##STR00001##
where, in General Formula (A), R.sub.1, R.sub.2, and R.sub.3 are each independently a group including a hydrocarbon group, with the proviso that at least one of the hydrocarbon groups in R.sub.1, R.sub.2, and R.sub.3 is a straight-chain hydrocarbon group having 6 or greater carbon atoms.
IONIC LIQUID, LUBRICANT, AND MAGNETIC RECORDING MEDIUM
A lubricant, which includes an ionic liquid including a conjugate base and a conjugate acid, wherein the conjugate acid is represented by General Formula (A) below, and wherein a pKa of an acid that is a source of the conjugate base in acetonitrile is 10 or less,
##STR00001##
where, in General Formula (A), R.sub.1, R.sub.2, and R.sub.3 are each independently a group including a hydrocarbon group, with the proviso that at least one of the hydrocarbon groups in R.sub.1, R.sub.2, and R.sub.3 is a straight-chain hydrocarbon group having 6 or greater carbon atoms.
METHOD FOR IMPROVING THE COKING RESISTANCE OF A LUBRICATING COMPOSITION
Disclosed is a method of lubrication including a step of lubricating a machine with a lubricating composition, the lubricating composition including 20-100% ionic liquid or of a mixture of several ionic liquids. The ionic liquid or the mixture is selected from at least: an anion A.sup.− chosen from sulfonylimides, the substituent(s) of which is (are) independently chosen from a fluoroalkyl, fluoroether, perfluorinated alkyl or perfluoroether group; and a cation C.sup.+ including a nitrogen-containing heterocycle or a quaternary ammonium, the substituent(s) of which is (are) independently chosen from: a hydrogen atom or alkyl, alkoxy, fluorinated alkyl, perfluorinated alkyl, alkylsilane, alkyl alcohol, vinyl, alkyl allyl, ether or polyether groups having a linear or branched chain having 1-3 carbon atoms. The deposition start temperature in thin film of the ionic liquid or of the mixture of ionic liquids is at least equal to 330° C. The lubricating composition reduces deposits formed in the machine.
METHOD FOR IMPROVING THE COKING RESISTANCE OF A LUBRICATING COMPOSITION
Disclosed is a method of lubrication including a step of lubricating a machine with a lubricating composition, the lubricating composition including 20-100% ionic liquid or of a mixture of several ionic liquids. The ionic liquid or the mixture is selected from at least: an anion A.sup.− chosen from sulfonylimides, the substituent(s) of which is (are) independently chosen from a fluoroalkyl, fluoroether, perfluorinated alkyl or perfluoroether group; and a cation C.sup.+ including a nitrogen-containing heterocycle or a quaternary ammonium, the substituent(s) of which is (are) independently chosen from: a hydrogen atom or alkyl, alkoxy, fluorinated alkyl, perfluorinated alkyl, alkylsilane, alkyl alcohol, vinyl, alkyl allyl, ether or polyether groups having a linear or branched chain having 1-3 carbon atoms. The deposition start temperature in thin film of the ionic liquid or of the mixture of ionic liquids is at least equal to 330° C. The lubricating composition reduces deposits formed in the machine.
Prelubricated stock sheet and method and system for making the same
A pre-lubricated stock sheet and a method and system for making the same are described. The pre-lubricated stock is generally in a coil wound form. The stock sheet can have opposing first and second sheet surfaces joined together by opposing side edges and opposing ends. Typically, the first and second sheet surfaces are substantially smooth and planar, wherein the sheet has 3 mg/foot.sup.2/side to about 200 mg/foot.sup.2/side of a solid lubricant having a melting temperature from about 80 to 212 degrees Fahrenheit. Moreover, the opposing side edges usually are substantially free of the solid lubricant. In some configurations, the stock sheet is an aluminum stock sheet, more particularly an aluminum can stock sheet. Furthermore, the lubricant can be in some configurations a food grade lubricant, that is qualifies a low volatile organic compound under one or more of municipal, state and federal governing authorities.
Prelubricated stock sheet and method and system for making the same
A pre-lubricated stock sheet and a method and system for making the same are described. The pre-lubricated stock is generally in a coil wound form. The stock sheet can have opposing first and second sheet surfaces joined together by opposing side edges and opposing ends. Typically, the first and second sheet surfaces are substantially smooth and planar, wherein the sheet has 3 mg/foot.sup.2/side to about 200 mg/foot.sup.2/side of a solid lubricant having a melting temperature from about 80 to 212 degrees Fahrenheit. Moreover, the opposing side edges usually are substantially free of the solid lubricant. In some configurations, the stock sheet is an aluminum stock sheet, more particularly an aluminum can stock sheet. Furthermore, the lubricant can be in some configurations a food grade lubricant, that is qualifies a low volatile organic compound under one or more of municipal, state and federal governing authorities.
FULLERENE COMPOUND, LUBRICANT FOR MAGNETIC RECORDING MEDIUM, AND MAGNETIC RECORDING MEDIUM
The invention provides a fullerene compound; a lubricant that is for a magnetic recording medium and that contains the fullerene compound; and a magnetic recording medium. The fullerene compound is an ionic liquid that is represented by general formula (1) and is formed from a Bronsted acid (H.sub.n1X) and a Bronsted base ([R.sub.2R.sub.3)N—].sub.m1—R.sub.1); wherein one of the Brønsted acid and the Broønsted base contains a group having a fullerene; and the other contains a perfluoroalkyl chain.
##STR00001##
FULLERENE COMPOUND, LUBRICANT FOR MAGNETIC RECORDING MEDIUM, AND MAGNETIC RECORDING MEDIUM
The invention provides a fullerene compound; a lubricant that is for a magnetic recording medium and that contains the fullerene compound; and a magnetic recording medium. The fullerene compound is an ionic liquid that is represented by general formula (1) and is formed from a Bronsted acid (H.sub.n1X) and a Bronsted base ([R.sub.2R.sub.3)N—].sub.m1—R.sub.1); wherein one of the Brønsted acid and the Broønsted base contains a group having a fullerene; and the other contains a perfluoroalkyl chain.
##STR00001##
Low transition temperature mixtures or deep eutectic solvents and processes for preparation thereof
A low transition temperature mixture (LTTM) or deep eutectic solvent (DES) useful as a lubricating oil base stock and lubricating oil including a eutectic mixture of at least a first component and at least a second component. The at least first component comprises a hydrogen bond acceptor and the at least second component comprises a hydrogen bond donor. The eutectic mixture includes an equilibrium phase between the at least first component and the at least second component. The equilibrium phase does not exhibit physical characteristics of the at least first component in an unmixed state and the at least second component in an unmixed state. The at least first component and the at least second component form an intermolecular interaction between each other sufficient to prevent crystallization of the at least first component and the at least second component in the eutectic mixture. The eutectic mixture is a liquid at 20 C.
Low transition temperature mixtures or deep eutectic solvents and processes for preparation thereof
A low transition temperature mixture (LTTM) or deep eutectic solvent (DES) useful as a lubricating oil base stock and lubricating oil including a eutectic mixture of at least a first component and at least a second component. The at least first component comprises a hydrogen bond acceptor and the at least second component comprises a hydrogen bond donor. The eutectic mixture includes an equilibrium phase between the at least first component and the at least second component. The equilibrium phase does not exhibit physical characteristics of the at least first component in an unmixed state and the at least second component in an unmixed state. The at least first component and the at least second component form an intermolecular interaction between each other sufficient to prevent crystallization of the at least first component and the at least second component in the eutectic mixture. The eutectic mixture is a liquid at 20 C.