The disclosure relates to a coating composition comprising a polymerizable compound of formula [1], wherein G is a residue of a hydrophobic hydroxy-functional oligomer, n is 1-10, each R1 independently is a residue of a C.sub.6-C.sub.20 aliphatic, cycloaliphatic, or aromatic hydrocarbon compound, and Z is a moiety having a polymerizable group; Formula [1] a hydrophilic polymer; a photo-initiator; optionally one or more further components, and a solvent. The polymerizable compound of formula [1] is typically present in an amount of 2.0-30 mass % based on total dry mass of the composition. Such coating composition can be made into a well-adhering single-layer hydrophilic coating on a surface of polymer substrates without providing a primer layer or chemically modifying the surface of the substrate. Upon wetting, the coating shows excellent lubricity and durability. In further aspects, the disclosure provides a method of applying a hydrophilic and optionally lubricious coating to an article; and an article like a medical device having on at least part of its surface a single-layer, hydrophilic and optionally lubricious coating, like a catheter, guidewire, or a delivery device for an implant.

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The disclosure relates to a coating composition comprising a polymerizable compound of formula [1], wherein G is a residue of a hydrophobic hydroxy-functional oligomer, n is 1-10, each R1 independently is a residue of a C.sub.6-C.sub.20 aliphatic, cycloaliphatic, or aromatic hydrocarbon compound, and Z is a moiety having a polymerizable group; Formula [1] a hydrophilic polymer; a photo-initiator; optionally one or more further components, and a solvent. The polymerizable compound of formula [1] is typically present in an amount of 2.0-30 mass % based on total dry mass of the composition. Such coating composition can be made into a well-adhering single-layer hydrophilic coating on a surface of polymer substrates without providing a primer layer or chemically modifying the surface of the substrate. Upon wetting, the coating shows excellent lubricity and durability. In further aspects, the disclosure provides a method of applying a hydrophilic and optionally lubricious coating to an article; and an article like a medical device having on at least part of its surface a single-layer, hydrophilic and optionally lubricious coating, like a catheter, guidewire, or a delivery device for an implant.

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To provide a technique capable of realizing an appropriate wear resistance in a resin coating layer. The sliding member of the present invention is a sliding member including a base layer and a resin coating layer formed on the base layer, wherein the resin coating layer is formed of a polyamide-imide resin as a binder, barium sulfate particles, molybdenum disulfide particles, and unavoidable impurities, wherein the resin coating layer is composed of a plurality of overcoated application layers, and wherein the plurality of application layers are different from each other in content of hard particles.

To provide a technique capable of realizing an appropriate wear resistance in a resin coating layer. The sliding member of the present invention is a sliding member including a base layer and a resin coating layer formed on the base layer, wherein the resin coating layer is formed of a polyamide-imide resin as a binder, barium sulfate particles, molybdenum disulfide particles, and unavoidable impurities, wherein the resin coating layer is composed of a plurality of overcoated application layers, and wherein the plurality of application layers are different from each other in content of hard particles.

A lubrication board includes a substrate; and a lubrication layer disposed on a surface of the substrate, wherein the lubrication layer comprises a polymer expressed by formula (I) below,

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wherein R.sub.1 is selected from a substituted or unsubstituted C.sub.6-C.sub.18 alkyl; R.sub.2 is selected from a substituted or unsubstituted C.sub.2-C.sub.18 alkyl or C.sub.2-C.sub.18 alkyl which is interrupted by —O—; R.sub.3 is selected from —NH— or —S—; R.sub.4 is selected from —NH.sub.2, —OH or —SH; and n, p and q are positive integers ranging from 2 to 20000.

A lubrication board includes a substrate; and a lubrication layer disposed on a surface of the substrate, wherein the lubrication layer comprises a polymer expressed by formula (I) below,

##STR00001##

wherein R.sub.1 is selected from a substituted or unsubstituted C.sub.6-C.sub.18 alkyl; R.sub.2 is selected from a substituted or unsubstituted C.sub.2-C.sub.18 alkyl or C.sub.2-C.sub.18 alkyl which is interrupted by —O—; R.sub.3 is selected from —NH— or —S—; R.sub.4 is selected from —NH.sub.2, —OH or —SH; and n, p and q are positive integers ranging from 2 to 20000.

Some variations provide a low-adhesion coating comprising a continuous matrix containing a first component, a plurality of inclusions containing a second component, and a solid-state lubricant distributed within the coating, wherein one of the first component or the second component is a low-surface-energy polymer, and the other of the first component or the second component is a hygroscopic material. The solid-state lubricant may be selected from graphite, graphene, molybdenum disulfide, tungsten disulfide, hexagonal boron nitride, or poly(tetrafluoroethylene) or other fluoropolymers. The solid-state lubricant particles may be coated with a metal selected from cadmium, lead, tin, zinc, copper, nickel, or alloys containing one or more of these metals. The solid-state lubricant is typically characterized by an average particle size from about 0.1 μm to about 500 μm. The solid-state lubricant is preferably distributed throughout the coating.

Polyurea crosslinked particles for a transport device member are provided that have high acid resistance, increase long-term retainability when included in a coating film, and are capable of maintaining a high sliding property for a long time. The polyurea crosslinked particles for a transport device member are particles formed of reactants of a self-emulsifying isocyanate having two or more isocyanate groups and a non-self-emulsifying isocyanate having two or more isocyanate groups and having a ring structure in the presence of water and a crosslink density thereof is 1×10.sup.−4 mol/g or more.

Polyurea crosslinked particles for a transport device member are provided that have high acid resistance, increase long-term retainability when included in a coating film, and are capable of maintaining a high sliding property for a long time. The polyurea crosslinked particles for a transport device member are particles formed of reactants of a self-emulsifying isocyanate having two or more isocyanate groups and a non-self-emulsifying isocyanate having two or more isocyanate groups and having a ring structure in the presence of water and a crosslink density thereof is 1×10.sup.−4 mol/g or more.

A mixture of polymers with lubricating properties is provided. The polymer can be used to produce a lubricating fluid. They can also be born on a surface or embedded in a porous material. This mixture of polymers comprises (a) a pharmaceutically acceptable bottle-brush polymer comprising a backbone with polymeric pendant chains, and (b) a pharmaceutically acceptable linear polymer. In the lubricating fluid, the bottle-brush polymer and the linear polymer are dissolved together in a pharmaceutically acceptable solvent.