The present disclosure describes lubricant compositions effective to minimize average engine sludge through selection of lubricant additives that control the total nitrogen as well as the origin of the nitrogen in the lubricant composition. In aspects, the lubricant compositions herein include at least a base oil of lubricating viscosity, a dispersant system, and at least one antioxidant.

The present invention provides a hydraulic fluid comprising: (a) 40 to 2000 ppm by weight in terms of nitrogen content of a corrosion inhibiting agent which is one or more compounds of formula (I):

##STR00001## and/or tribologically acceptable salts thereof, wherein in formula (I): each R.sup.1 is independently a hydrocarbyl group comprising 1 to 10 carbon atoms, x is 0 to 4, each of R.sup.2 and R.sup.3 is independently hydrogen or a hydrocarbyl group comprising 1 to 20 carbon atoms, R.sup.4 is —NR.sup.5R.sup.6 or —OR.sup.7, each of R.sup.5 and R.sup.6 is independently an aryl group comprising 6 to 14 carbon atoms, optionally substituted with one or more hydrocarbyl groups comprising 1 to 20 carbon atoms, R.sup.7 is a hydrocarbyl group comprising 1 to 20 carbon atoms, and in each of said hydrocarbyl groups containing 2 or more carbon atoms, the carbon chain may, independently, optionally be interrupted by one or more ether groups; (b) 0.1 to 1% by weight of an ashless dispersant; and (c) a major amount of a base oil.

The present invention provides a hydraulic fluid comprising: (a) 40 to 2000 ppm by weight in terms of nitrogen content of a corrosion inhibiting agent which is one or more compounds of formula (I):

##STR00001## and/or tribologically acceptable salts thereof, wherein in formula (I): each R.sup.1 is independently a hydrocarbyl group comprising 1 to 10 carbon atoms, x is 0 to 4, each of R.sup.2 and R.sup.3 is independently hydrogen or a hydrocarbyl group comprising 1 to 20 carbon atoms, R.sup.4 is —NR.sup.5R.sup.6 or —OR.sup.7, each of R.sup.5 and R.sup.6 is independently an aryl group comprising 6 to 14 carbon atoms, optionally substituted with one or more hydrocarbyl groups comprising 1 to 20 carbon atoms, R.sup.7 is a hydrocarbyl group comprising 1 to 20 carbon atoms, and in each of said hydrocarbyl groups containing 2 or more carbon atoms, the carbon chain may, independently, optionally be interrupted by one or more ether groups; (b) 0.1 to 1% by weight of an ashless dispersant; and (c) a major amount of a base oil.

A lubricating oil composition may include a base oil (A), succinimide (B) which has not been modified with boron, succinimide (C) modified with boron, a metallic detergent (D), and an antioxidant (E), wherein the ratio of the content of boron atoms derived from ingredient (C) to the content of nitrogen atoms derived from ingredients (B) and (C), B/N, is 0.30 or less by mass, the lubricating oil composition satisfying requirement (I) and/or requirement (II). Requirement (I): Ingredient (D) includes a metallic detergent (D1) having a base value less than 100 mgKOH/g. Requirement (II): Ingredient (E) includes an amine-based antioxidant (E1), the content of ingredient (E1) being 1.00 mass % or less.

A lubricating oil composition may include a base oil (A), succinimide (B) which has not been modified with boron, succinimide (C) modified with boron, a metallic detergent (D), and an antioxidant (E), wherein the ratio of the content of boron atoms derived from ingredient (C) to the content of nitrogen atoms derived from ingredients (B) and (C), B/N, is 0.30 or less by mass, the lubricating oil composition satisfying requirement (I) and/or requirement (II). Requirement (I): Ingredient (D) includes a metallic detergent (D1) having a base value less than 100 mgKOH/g. Requirement (II): Ingredient (E) includes an amine-based antioxidant (E1), the content of ingredient (E1) being 1.00 mass % or less.

An extremely rheopectic sulfonate-based grease composition and method comprising adding overbased calcium sulfonate, overbased magnesium sulfonate, and a facilitating acid, using a particular type of overbased calcium sulfonate and/or methods for adding overbased calcium sulfonate relative to the magnesium sulfonate and facilitating acid to favor the reaction between the magnesium sulfonate and facilitating acid. A preferred overbased calcium sulfonate comprises benzene rings having multiple alkyl groups. Preferred methods comprise (1) adding all calcium sulfonate after adding the magnesium sulfonate and facilitating acid, (2) adding a first portion of calcium sulfonate with the magnesium sulfonate before adding the facilitating acid and a second portion of calcium sulfonate after the facilitating acid, and/or (3) one or more calcium sulfonate delay periods relative to adding the facilitating acid. The extremely rheopectic grease is fluid and pourable and only takes on a grease structure after milling or shearing.

An extremely rheopectic sulfonate-based grease composition and method comprising adding overbased calcium sulfonate, overbased magnesium sulfonate, and a facilitating acid, using a particular type of overbased calcium sulfonate and/or methods for adding overbased calcium sulfonate relative to the magnesium sulfonate and facilitating acid to favor the reaction between the magnesium sulfonate and facilitating acid. A preferred overbased calcium sulfonate comprises benzene rings having multiple alkyl groups. Preferred methods comprise (1) adding all calcium sulfonate after adding the magnesium sulfonate and facilitating acid, (2) adding a first portion of calcium sulfonate with the magnesium sulfonate before adding the facilitating acid and a second portion of calcium sulfonate after the facilitating acid, and/or (3) one or more calcium sulfonate delay periods relative to adding the facilitating acid. The extremely rheopectic grease is fluid and pourable and only takes on a grease structure after milling or shearing.

The disclosed technology provides alkylphenol-containing detergent having at least one unit (a) of an alkyl-substituted phenol wherein the alkyl group is derived from oligomers of an olefin compound containing 3 to 8 carbon atoms, wherein the polyolefin-derived alkyl group comprises at least 30 mol percent of an olefin with 4 or more carbon atoms. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.

The disclosed technology provides alkylphenol-containing detergent having at least one unit (a) of an alkyl-substituted phenol wherein the alkyl group is derived from oligomers of an olefin compound containing 3 to 8 carbon atoms, wherein the polyolefin-derived alkyl group comprises at least 30 mol percent of an olefin with 4 or more carbon atoms. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.

A lubricating oil composition which may contain a zinc dialkyl dithiophosphate, and whose color deterioration over time is alleviated. Such a lubricating oil composition may contain: a base oil (A); a zinc dialkyl dithiophosphate (B); and a sodium-based detergent (C). In such a lubricating oil composition, a content of zinc atoms may be 100 ppm by mass to 2,000 ppm by mass based on a total amount of the lubricating oil composition, and a content of sodium atoms may be 5 ppm by mass to 1,000 ppm by mass based on the total amount of the lubricating oil composition.