A lubricating oil composition excellent in the wear resistance and a refrigerator oil composition excellent in the oxidation stability using the lubricating oil composition are provided by a lubricating oil composition containing a base oil (A) and a phosphine derivative (B) having one or more oxygen atom in a molecule.

A lubricating oil composition excellent in the wear resistance and a refrigerator oil composition excellent in the oxidation stability using the lubricating oil composition are provided by a lubricating oil composition containing a base oil (A) and a phosphine derivative (B) having one or more oxygen atom in a molecule.

A lubricant composition comprising: at least one base oil; and from 0.1% to 30% by weight of a phosphorus ester compound of formula (A):

##STR00001## in which s is 0 or 1; and the radicals X represent, independently of each other, —OR′ or R′ moieties, where R′ represents hydrogen or a linear or branched hydrocarbon moiety, preferably having from 1 to 36 carbon atoms, with the proviso that: when s is 0, the three X radicals represent —OR′ moieties, and when s is 1, at least two of the three X radicals are —OR′ moieties.

A lubricant composition comprising: at least one base oil; and from 0.1% to 30% by weight of a phosphorus ester compound of formula (A):

##STR00001## in which s is 0 or 1; and the radicals X represent, independently of each other, —OR′ or R′ moieties, where R′ represents hydrogen or a linear or branched hydrocarbon moiety, preferably having from 1 to 36 carbon atoms, with the proviso that: when s is 0, the three X radicals represent —OR′ moieties, and when s is 1, at least two of the three X radicals are —OR′ moieties.

The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.

The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.

The invention relates to the use of at least one phosphorus compound, which is free of sulfur and has no amine function, as an anti-wear and extreme-pressure additive in a lubricant composition for a propulsion system of an electric or hybrid vehicle. The invention also relates to the use of a lubricant composition comprising at least one phosphorus compound, which is free of sulfur and has no amine function, as an anti-wear and extreme-pressure additive, for lubricating and optionally cooling a propulsion system of an electric or hybrid vehicle, in particular for lubricating and cooling the electric motor and the power electronics of an electric or hybrid vehicle.

The invention relates to the use of at least one phosphorus compound, which is free of sulfur and has no amine function, as an anti-wear and extreme-pressure additive in a lubricant composition for a propulsion system of an electric or hybrid vehicle. The invention also relates to the use of a lubricant composition comprising at least one phosphorus compound, which is free of sulfur and has no amine function, as an anti-wear and extreme-pressure additive, for lubricating and optionally cooling a propulsion system of an electric or hybrid vehicle, in particular for lubricating and cooling the electric motor and the power electronics of an electric or hybrid vehicle.

A surface protection composition contains (a) a phosphorus compound represented by formula (1), (b-1) a metal-containing compound or (b-2) an amine compound, (c) a (meth)acrylate having a hydrocarbon chain having 4 or more carbon atoms, (d-1) an acylphosphine oxide photopolymerization initiator and (d-2) an α-aminoacetophenone photopolymerization initiator. Further, the composition has the compound (d-1) in an amount of 0.1 to 3.0 mass % with respect to the total amount of the composition, compound (d-2) in an amount of 0.1 to 3.0 mass % with respect to the total amount of the composition and a total amount of the compound (d-1) and (d-2) is less than 5.0 mass % with respect to the total amount of the composition.

##STR00001##

In the above formula, R.sup.1 represents a hydrogen atom, R.sup.2 represents a hydrocarbon group having 4 to 30 carbon atoms, and R.sup.3 represents a hydrogen atom or a hydrocarbon group having 4 to 30 carbon atoms.

A surface protection composition contains (a) a phosphorus compound represented by formula (1), (b-1) a metal-containing compound or (b-2) an amine compound, (c) a (meth)acrylate having a hydrocarbon chain having 4 or more carbon atoms, (d-1) an acylphosphine oxide photopolymerization initiator and (d-2) an α-aminoacetophenone photopolymerization initiator. Further, the composition has the compound (d-1) in an amount of 0.1 to 3.0 mass % with respect to the total amount of the composition, compound (d-2) in an amount of 0.1 to 3.0 mass % with respect to the total amount of the composition and a total amount of the compound (d-1) and (d-2) is less than 5.0 mass % with respect to the total amount of the composition.

##STR00001##

In the above formula, R.sup.1 represents a hydrogen atom, R.sup.2 represents a hydrocarbon group having 4 to 30 carbon atoms, and R.sup.3 represents a hydrogen atom or a hydrocarbon group having 4 to 30 carbon atoms.