The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.

The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.

A lubricant composition of an oil of lubricating viscosity, a grafted copolymer viscosity modifier that is an ashless condensation reaction product of an olefm polymer, having a number average molecular weight of about 1000 to about 10,000, comprising carboxylic acid or equivalent functionality grafted onto the polymer backbone, with a monoamine or a polyamine often having a single primary amino group, which exhibits good dispersancy and viscometric performance in a driveline device.

A lubricant composition of an oil of lubricating viscosity, a grafted copolymer viscosity modifier that is an ashless condensation reaction product of an olefm polymer, having a number average molecular weight of about 1000 to about 10,000, comprising carboxylic acid or equivalent functionality grafted onto the polymer backbone, with a monoamine or a polyamine often having a single primary amino group, which exhibits good dispersancy and viscometric performance in a driveline device.

A viscosity index improver comprising a copolymer having a unit (a) derived from a maleimide monomer and a unit (b) derived from a macromonomer, wherein viscosity measured by the following method is 8000 mPa.Math.s or less. Viscosity measurement method: A solution composed of 78 mass % of a Group III base oil (viscosity index: 122, kinematic viscosity at 40° C.: 19.6 mm.sup.2/s) on the American Petroleum Institute (API) classification and 22 mass % of the copolymer is measured with a viscometer (TVB-10 manufactured by Toki Sangyo Co., Ltd., rotor: SPINDLE No. M3, rotation speed: 6 rpm) at 25° C.

A viscosity index improver comprising a copolymer having a unit (a) derived from a maleimide monomer and a unit (b) derived from a macromonomer, wherein viscosity measured by the following method is 8000 mPa.Math.s or less. Viscosity measurement method: A solution composed of 78 mass % of a Group III base oil (viscosity index: 122, kinematic viscosity at 40° C.: 19.6 mm.sup.2/s) on the American Petroleum Institute (API) classification and 22 mass % of the copolymer is measured with a viscometer (TVB-10 manufactured by Toki Sangyo Co., Ltd., rotor: SPINDLE No. M3, rotation speed: 6 rpm) at 25° C.

A method of lubricating at least a portion of a powertrain in a vehicle with an electric motor with a functional fluid composition containing greater than 50 wt % of a base oil; and an additive composition prepared by mixing: a) a hydrocarbyl acid phosphate of the formula (I) to provide at least 50 ppmw phosphorus to the functional fluid composition;

##STR00001##

wherein R is a C.sub.1-C.sub.6 hydrocarbyl group and R.sub.1 is selected from hydrogen and a C.sub.1-C.sub.6 hydrocarbyl group; b) an amount of one or more calcium-containing detergent(s) sufficient to provide at least 25 ppmw calcium to the functional fluid composition; and c) one or more nitrogen containing dispersants in an amount sufficient to provide greater than 20 ppmw of nitrogen to the functional fluid composition, all based on the total weight of the functional fluid composition. Functional fluid compositions containing the above-mentioned components and lubricating methods are also disclosed herein.

Ethylene-C.sub.3-C.sub.10 alpha olefin copolymers, dispersants and lubricating oils/fuel compositions incorporating dispersants, and related methods are generally described herein. The copolymer may comprise ethylene-derived units and C.sub.3-C.sub.10 alpha-olefin-derived units. The C.sub.3-C.sub.10 alpha-olefin-derived units may have a carbon number from three to ten. For example, the C.sub.3-C.sub.10 alpha-olefin-derived units may be propylene-derived units. The dispersants may be made from copolymers having low metal and/or fluorine contents.

Ethylene-C.sub.3-C.sub.10 alpha olefin copolymers, dispersants and lubricating oils/fuel compositions incorporating dispersants, and related methods are generally described herein. The copolymer may comprise ethylene-derived units and C.sub.3-C.sub.10 alpha-olefin-derived units. The C.sub.3-C.sub.10 alpha-olefin-derived units may have a carbon number from three to ten. For example, the C.sub.3-C.sub.10 alpha-olefin-derived units may be propylene-derived units. The dispersants may be made from copolymers having low metal and/or fluorine contents.

Amine alkenyl substituted succinimide reaction product compositions including the reaction products of (1) an amine component including at least one multifunctional amine of structure (1): ##STR00001##
wherein each R is independently H or CH.sub.2CH.sub.2CH.sub.2NH.sub.2; R.sub.1 is H, CH.sub.2CH.sub.2CH.sub.2NH.sub.2, C1-C21 alkyl, or C2-C21 alkenyl; n is 2; and m is 1 or 2 and (2) an alkenyl substituted anhydride. Additive compositions, fuel additives, fuel compositions and methods for reducing deposit formations in a fuel system are also disclosed.