The present invention generally relates to lubricating oil compositions useful for reducing NOACK volatility in finished lubricating oils of an internal combustion engine. Also disclosed is a method for reducing NOACK volatility in finished lubricating oils in said engine.

A product resulting from the reaction of at least: a hydroxybenzoic acid, optionally substituted by a hydrocarbyl group, a boron compound, an amine component selected from a di-fatty-alkyl(ene) polyalkylamine composition including one or more polyalkylamines of formulae (I) or (II). A lubricant composition includes this product. Use of this product as a lubricant for two-stroke marine engines and four-stroke marine engines, more preferably two-stroke marine engines.

Compositions resulting from the mixing of at least one oligomer A1, resulting from the copolymerization of at least one monomer functionalized by diol functions with at least a second monomer, and at least one compound A2 including at least two boronic ester functions. The compositions exhibit very varied rheological properties, depending on the proportion of the compounds A1 and A2 used. A composition also results from mixing at least one lubricating oil with such a composition of associative and exchangeable polymers, and to the use of this composition to lubricate a mechanical part.

A defoaming agent including a polymer, the polymer including: at least one first polymer chain including a polysiloxane structure represented by the following general formula (1); and at least one second polymer chain including a repeating unit represented by the following general formula (2) and bonded to the first polymer chain: ##STR00001##
wherein in the formula (1), repeating units may be in any order; each of R.sup.1 and R.sup.2 is independently a C.sub.1-18 organic group comprising no fluorine atom; at least one of R.sup.3 and R.sup.4 is the organic group comprising no less than 3 fluorine atoms; m is an integer of no less than 1; and n+m is 5 to 2000, ##STR00002##
wherein in the formula (2), X.sup.1 is a repeating unit obtainable by polymerization of an ethylenic unsaturated group; Y.sup.1 is a substituted or unsubstituted C.sub.1-40 hydrocarbyl group; and Z.sup.1 is a linking group linking X.sup.1 and Y.sup.1.

A VM concentrate comprising: from about 60 to about 95 parts (and at least 50 wt %) of a diluent oil (e.g., having a KV100 of about 2 cSt to about 40 cSt); and from about 5 parts to about 40 parts (and at least 6.0 wt %) of a linear triblock copolymer characterized by the formula: D′-PA-D″; wherein D′ represents a block derived from diene, PA represents a block derived from monoalkenyl arene, D″ represents a block derived from diene, and the linear triblock copolymer is present in an amount effective to modify a lubricating kinematic viscosity at approximately 100° C. (KV100) of the concentrate, and wherein the KV100 of the concentrate is about 3000 cSt or less. The linear triblock copolymer may additionally or alternatively have a thickening efficiency span of at most 0.5.

A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer (which repeat units may comprise from 7.0 wt % to 18 wt % of the repeat units of the comb copolymer viscosity modifier); (b) a C.sub.3-C.sub.8 alkyl (alk)acrylate ester monomer (which repeat units may comprise from 40 wt % to 71 wt % or from 45 wt % to 64 wt % of the repeat units of the comb copolymer viscosity modifier); and (c) a C.sub.12-C.sub.24 alkyl (alk)acrylate ester monomer, wherein repeat units based on the C.sub.12-C.sub.24 alkyl (alk)acrylate ester monomer comprise at least 21.0 wt % (and optionally up to 35.0 wt %) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity, are also contemplated herein.

A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) (optionally from 7.0 wt % to 18 wt %, by repeat units, of) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer; (b) (optionally from 33 wt % to 64 wt %, by repeat units, of) a C.sub.3-C.sub.8 alkyl (alk)acrylate ester monomer; (c) a C.sub.12-C.sub.24 alkyl (alk)acrylate ester monomer; and (d) (optionally from 3.0 wt % to 25 wt %, by repeat units, of) H-endcapped, C.sub.1-C.sub.18 alkyl-endcapped, or C.sub.6-C.sub.20 aryl-, aralkyl-, or alkaryl-endcapped C.sub.2-C.sub.6 oxyalkyl or C.sub.2-C.sub.6 oligo(alkylene glycol)-based (alk)acrylate ester monomer, wherein repeat units based on monomer (c) and/or monomer (d) comprise at least 21.0 wt % (and optionally up to 35.0 wt %) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity and dispersancy, are also contemplated.

A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) (optionally from 7.0 wt % to 18 wt %, by repeat units, of) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer; (b) (optionally from 33 wt % to 64 wt %, by repeat units, of) a C.sub.3-C.sub.8 alkyl (alk)acrylate ester monomer; (c) a C.sub.12-C.sub.24 alkyl (alk)acrylate ester monomer; and (d) (optionally from 3.0 wt % to 25 wt %, by repeat units, of) H-endcapped, C.sub.1-C.sub.18 alkyl-endcapped, or C.sub.6-C.sub.20 aryl-, aralkyl-, or alkaryl-endcapped C.sub.2-C.sub.6 oxyalkyl or C.sub.2-C.sub.6 oligo(alkylene glycol)-based (alk)acrylate ester monomer, wherein repeat units based on monomer (c) and/or monomer (d) comprise at least 21.0 wt % (and optionally up to 35.0 wt %) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity and dispersancy, are also contemplated.

The present disclosure relates to a continuously variable transmission oil composition containing a base oil containing a metallocene polyalpha olefin (mPAO) polymerized with a metallocene catalyst, a viscosity controlling agent containing Polybutadiene hydrogen phosphate Comb Polymethacrylate, and a clean dispersant, and contains mPAO and PHP Comb PMA, which have not been used previously, at a specific ratio to maximize the reduction in low-temperature viscosity while effectively forming an oil film, thereby enhancing fuel efficiency, and at the same time, enhancing durability of a transmission by increasing viscosity.

This disclosure relates to a method for improving air release and water separation in a lubricating oil. The method involves formulating a composition comprising at least one lubricating oil base stock as a major component, and one or more lubricating oil additives, as a minor component. The one or more lubricating oil additives include a mixture of antifoam agents. The mixture of antifoam agents includes at least one polysiloxane and at least one acrylate polymer. During operation of a lubricating system containing the lubricating oil, release of entrained air in the lubricating oil is improved, as determined by ASTM D-3427-15, and water separation from the lubricating oil is improved, as determined by ASTM D-1401-18b, as compared to release of entrained air and water separation achieved using a lubricating oil containing other than the mixture of antifoam agents. This disclosure also relates to lubricating oils having a mixture of antifoam agents including at least one polysiloxane and at least one acrylate polymer.