In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise a refrigerant mixture consisting essentially of HFC-32, HFO-1234yf, and CO.sub.2. The compositions are useful as refrigerants in processes to produce cooling and heating, in methods for replacing refrigerant R-410A, and in refrigeration, air conditioning or heat pump systems. These inventive compositions match cooling capacity for R-410A within ±10% with GWP less than 400 or less than 300.

A C.sub.31 renewable base oil is disclosed that is suitable as a base oil to provide low viscosity base oils, such as having both low Noack volatility and low CCS-30° C. viscosity and/or to provide low viscosity base oils at the same time having a combination of acceptable HTHS and KV100 to allow the industry's base oil blenders to formulate high quality engine oils, such as SAE grade 0W-20, 0W-16, 0W-12 or 0W-8.

The present disclosure provides a method of producing a lubricant composition comprising the steps of hydrolyzing a starting material to provide a hydrolyzed product mixture, reacting the hydrolyzed product mixture under conditions capable of producing a condensation product mixture, contacting the condensation product mixture with a cyclic compound to provide a coupled product mixture, and hydrogenating the coupled product mixture to provide the lubricant composition. In addition, other methods and compositions thereof are also provided.

The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.

A lubricating oil composition is provided, including a fullerene and a base oil, in which the fullerene is a fullerene sublimate, and the base oil is a multiply alkylated cyclopentane oil or an ionic liquid.

The disclosure relates to a biobased metal-working fluid (MWF) composition and method for making same, and more particularly metal-working fluid with biobased lubricants with improved emulsion stability. At least 50 wt. % of the base oil component in the MWF concentrate is a plant-derived liquid decarboxylated rosin acid oil (“DCR”). The DCR comprises 50 to 100 wt. % of tricyclic compounds having 18-20 carbon atoms, one or more C═C groups, and m/z (mass/charge) value of 220-280; an oxygen content of <5%; a density of 0.9 to 1.0 g/cm.sup.3 at 20° C.; and an acid value of <10 mg KOH/g. The resulting MWF is characterized as having comparable if not better performance compared to a MWF containing only mineral oil (e.g., Group I or Group II).

Disclosed is a mixture comprising the compound trans-1,1,1,4,4,4-hexafluoro-2-butene and at least one additional compound selected from the group consisting of HFOs, HFCs, HFEs, CFCs, CO2, olefins, organic acids, alcohols, hydrocarbons, ethers, aldehydes, ketones, and others such as methyl formate, formic acid, trans-1,2 dichloroethylene, carbon dioxide, cis-HFO-1234ze+HFO-1225yez, mixtures of these plus water; mixtures of these plus CO2; mixtures of these trans 1,2-dichloroethylene (DCE); mixtures of these plus methyl formate; mixtures with cis-HFO-1234ze+CO2, mixtures with cis-HFO-1234ze+HFO-1225yez+CO2, and mixtures with cis-HFO-1234ze+HFC-245fa. Also disclosed are methods of using and products of using the above compositions as blowing agents, solvents, heat transfer compositions, aerosol propellant compositions, fire extinguishing and suppressant compositions.

A lubricating oil composition is provided, including a fullerene and a base oil, in which the fullerene is a fullerene sublimate, and the base oil is a multiply alkylated cyclopentane oil or an ionic liquid.

The disclosed technology relates to a traction fluid containing a base fluid having at least one of cedrene, cedrol, thujopsene or mixtures thereof, preferably provided from cedar oil, as well as a method of lubricating a power transmission apparatus with the traction fluid.

To provide a lubricating oil composition achieving both of high traction coefficient and excellent low temperature fluidity at a higher level and having a high flash point, which contains a naphthene-based synthetic oil (a) having a flash point of 140° C. or higher, and an ester (b) having 5 to 32 carbon atoms and having a branched chain, wherein the content of the naphthene-based synthetic oil (a) based on the total amount of the composition is 35% by mass or more and less than 80% by mass, a method for producing the lubricating oil composition, and a continuously variable transmission using the lubricating oil composition.