The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.

The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.

The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.

An additive composition for limiting the chemical degradation of hydrocarbonaceous liquids due to nitrogen dioxide contamination at elevated temperature comprises the combination of an ionic liquid composed of a cation and a boron- and halogen-free, multi-functional anion and a detergent additive, the combination of ionic liquid and detergent serving to inhibit the nitration of hydrocarbonaceous liquid components that initiates degradation.

An embodiment of the present invention relates to a paste which includes a perfluoropolyether (A) having two or more ethylenically unsaturated bonds in the molecule, a polysiloxane (B) having two or more ethylenically unsaturated bonds in the molecule, and a radical initiator (C).

A lubricating oil composition for an internal combustion engine including: (A) a lubricant base oil having a kinematic viscosity at 100° C. of 2 to 5 mm.sup.2/s; (B) a metallic detergent in an amount of 500 to 2500 mass ppm in terms of Ca and 100 to 1000 mass ppm in terms of Mg, on the basis of the total mass of the composition, the metallic detergent including both (B1) a Ca-containing metallic detergent and (B2) a Mg-containing metallic detergent; (C) a boron-containing additive in an amount of 50 to 1000 mass ppm in terms of boron on the basis of the total mass of the composition, wherein the boron-containing additive is oil-soluble or oil-dispersible and is stable in oil, and wherein the boron-containing additive may compose at least a part of the component (B); and (D) an oil-soluble organic Mo compound in an amount of 100 to 2000 mass ppm in terms of Mo on the basis of the total mass of the composition, wherein a mass ratio (MB/Mg) of boron content of the composition (MB) to Mg content of the composition (Mg) is 0.5 to 10.

The invention relates to a polyalkyl (meth) acrylate for improving lubricating oil properties, which comprises repetition units which are derived from (meth) acrylates having 6 to 22 carbon atoms in the alcohol residues, and repetition units which are derived from amine derivatives of an ethylenically unsaturated monomer. The invention further relates to methods for producing and using the present polyalkyl (meth) acrylate.

A polymer surfactant for improving engine oil emulsion properties of a lubricating composition mixed with water and/or fuel contamination, particularly at very cold temperatures, is described herein. In approaches, selected polymeric and functionalized compounds can impart both robust emulsion properties and simultaneously deliver good low temperature fluidity for lubricating compositions that may contain residual amounts of water and/or fuel contamination. Lubricating compositions including such surfactants demonstrate robust properties at temperatures down to about −30° C.

A viscosity index improver comprising a polymer which has a high viscosity index and good shear stability and which exhibits sufficient solubility in a lubricating base oil, a process for producing the same, and a lubricating oil composition containing the viscosity index improver are provided, wherein the viscosity index improver comprising a polymer satisfying the following (1) to (4): (1) weight-average molecular weight (Mw) of 200,000 or more and 600,000 or less; (2) number-average molecular weight (Mn) of 90,000 or more; (3) molecular weight distribution (Mw/Mn) of 4.0 or less; and (4) branching degree of 1.0 or more.

A viscosity index improver comprising a polymer which has a high viscosity index and good shear stability and which exhibits sufficient solubility in a lubricating base oil, a process for producing the same, and a lubricating oil composition containing the viscosity index improver are provided, wherein the viscosity index improver comprising a polymer satisfying the following (1) to (4): (1) weight-average molecular weight (Mw) of 200,000 or more and 600,000 or less; (2) number-average molecular weight (Mn) of 90,000 or more; (3) molecular weight distribution (Mw/Mn) of 4.0 or less; and (4) branching degree of 1.0 or more.