The instant disclosure generally relates to lubricating compositions having an oil of lubricating viscosity, a boron-containing additive, a boron-free dispersant, an overbased magnesium-based detergent, an overbased calcium-based detergent, an ashless friction modifier, and, optionally, other performance additives. The instant lubricating composition has a High Temperature High Shear (HTHS) viscosity according to ASTM D4683 of less than 2.7 mPa s. The instant lubricating compositions disclosed herein may accomplish one or more of the following improve fuel economy, reduce corrosion, reduce oxidation, improve cleanliness, and improve wear performance of an internal combustion engine.

The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.

The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.

A method of making a coating solution includes the steps of polymerising an initial monomer feed comprising an N-vinyl pyrrolidone and an acrylate, preferably methacrylate, salt in water to synthesise a copolymer thereof, acidifying the resulting copolymer-water mixture to give free carboxylic acid groups along the copolymer backbone, diluting the aqueous solution down with alcohol, and adding a cross-linking agent which is capable of reacting with the carboxylic acid groups and curing the copolymer at a later stage after the coating solution has been applied to a substrate and the copolymer coated thereon. Also disclosed are a coating solution in storage, a method of coating a substrate which is on, or is part of, a medical device or other article, a substrate, article or medical device having a coating so applied, and a coated medical device packaged in a hydration solution. The aqueous-alcoholic coating solution may be stored for an extended period, suitably for at least one month and desirably for substantially longer, without deteriorating.

A method of making a coating solution includes the steps of polymerising an initial monomer feed comprising an N-vinyl pyrrolidone and an acrylate, preferably methacrylate, salt in water to synthesise a copolymer thereof, acidifying the resulting copolymer-water mixture to give free carboxylic acid groups along the copolymer backbone, diluting the aqueous solution down with alcohol, and adding a cross-linking agent which is capable of reacting with the carboxylic acid groups and curing the copolymer at a later stage after the coating solution has been applied to a substrate and the copolymer coated thereon. Also disclosed are a coating solution in storage, a method of coating a substrate which is on, or is part of, a medical device or other article, a substrate, article or medical device having a coating so applied, and a coated medical device packaged in a hydration solution. The aqueous-alcoholic coating solution may be stored for an extended period, suitably for at least one month and desirably for substantially longer, without deteriorating.

An additive for a lubricating composition includes an ionic tetrahedral borate compound which includes a cation and a tetrahedral borate anion having a boron atom, the boron atom has at least one aliphatic bidentate di-oxo ligand. The cation may be selected to provide detergent and/or dispersant and/or antioxidant properties to a lubricating composition.

A lubricating oil composition for an internal combustion engine has a HTHS viscosity at 150° C. of 2.25 to <2.55 mPa.Math.s and includes: (A) a lubricating base oil including (a) mineral base oil(s) and/or (a) synthetic base oil(s), and having a kinematic viscosity at 100° C. of 3.8-4.6 mm.sup.2/s; (B) 1000-2000 mass ppm, in terms of metal content, of a metallic detergent including (a) metal salicylate detergent(s), and delivering ≥10 mmol/kg of total salicylate soap base per kilogram of the composition; (C) 1.0 to 4.0 mass % of a comb-shaped poly(meth)acrylate having a Mw of 350,000-1,000,000 and a PDI of ≤4.0; and (D) 100-1000 mass ppm, in terms of nitrogen, of a succinimide dispersant including (i) (a) non-modified succinimide dispersant(s) and/or (ii) (a) boric acid-modified succinimide dispersant(s), wherein the (i) and the (ii), in total, deliver 70 mass % of total nitrogen content of the component (D).

The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.

A method of lubricating at least a portion of a powertrain in a vehicle with an electric motor with a functional fluid composition containing greater than 50 wt % of a base oil; and an additive composition prepared by mixing: a) a hydrocarbyl acid phosphate of the formula (I) to provide at least 50 ppmw phosphorus to the functional fluid composition; ##STR00001##
wherein R is a C.sub.1-C.sub.6 hydrocarbyl group and R.sub.1 is selected from hydrogen and a C.sub.1-C.sub.6 hydrocarbyl group; b) an amount of one or more calcium-containing detergent(s) sufficient to provide at least 25 ppmw calcium to the functional fluid composition; and c) one or more nitrogen containing dispersants in an amount sufficient to provide greater than 20 ppmw of nitrogen to the functional fluid composition, all based on the total weight of the functional fluid composition. Functional fluid compositions containing the above-mentioned components and lubricating methods are also disclosed herein.

The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.