The present invention relates to the use of amines and/or Mannich adducts as detergents and/or dispersants in fuel and lubricant compositions for direct-injection gasoline engines. The invention further relates to fuel and lubricant compositions which comprise at least one such Mannich adduct, and also a bisaminoalkylated Mannich adduct.

A method for preventing or reducing low speed pre-ignition in an engine lubricated with a lubricating oil while maintaining or improving cleanliness by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and at least one boron-containing compound and at least one overbased calcium detergent as minor components. The at least one boron-containing compound includes at least one borated dispersant, or a mixture of a boron-containing compound and a non-borated dispersant. The boron to nitrogen ratio for the at least one boron-containing compound is less than or equal to about 0.3 and the lubricating oil is essentially free of elemental magnesium. The lubricating oils of this disclosure are particularly advantageous as passenger vehicle engine oil (PVEO) products.

A method for preventing or reducing low speed pre-ignition in an engine lubricated with a lubricating oil while maintaining or improving cleanliness by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and at least one boron-containing compound and at least one overbased calcium detergent as minor components. The at least one boron-containing compound includes at least one borated dispersant, or a mixture of a boron-containing compound and a non-borated dispersant. The boron to nitrogen ratio for the at least one boron-containing compound is less than or equal to about 0.3 and the lubricating oil is essentially free of elemental magnesium. The lubricating oils of this disclosure are particularly advantageous as passenger vehicle engine oil (PVEO) products.

Provided are lubricating engine oils including a lubricating oil base stock as a major component having a base oil viscosity at 100 deg. C. ranging from 4.5 to 7.5 cSt, and a carboxylic functionalized polymer dispersant with aromatic amine functionality, as a minor component, wherein the lubricating engine oils have a cold crank simulator viscosity at 30 deg. C. of less than 8500 mPa.Math.s. The lubricating engine oils may provide improved engine wear protection at equivalent fuel efficiency or improved fuel efficiency at equivalent engine wear protection compared to a lubricating engine oil containing a dispersant as a minor component other than the carboxylic functionalized polymer with aromatic amine functionality. Methods of making the lubricating engine oil are also provided. The lubricating engine oils are useful in internal combustion engines including direct injection, gasoline and diesel engines.

The disclosed technology relates to ashless compounds exhibiting neutral pH and having sufficient polarity to act as a dispersant. The disclosed technology additionally relates to the use of the ashless compounds in engine lubricants as dispersants for preventing engine deposit without degrading seals or increasing (i.e. contributing to) corrosion.

Polyisobutylenes (PIBs) containing a high proportion of vinylidene end groups are generally favored over conventional PIBs because of their higher reactivity in reactions that are needed to prepare fuel and lubricant additives. However, detergent additives that have been prepared from conventional PIBs actually perform better than detergent additives prepared from high reactive PIBs. Specifically, detergent additives that were prepared from conventional PIB that was then enriched with tri- and tetra-PIB resulted in altered thermal stability and improved detergency of the resulting compound as compared to the structures which were created using a high proportion of vinylidene end groups.

A synergistic mixture comprising from 1 to 99.9% by weight of compounds having structural elements (I) ##STR00001##
in which the free valencies on the oxygen atom and on the nitrogen atom may be combined to form a five-, six- or seven-membered ring and the benzene ring may also bear substituents at one or more of the free positions, and from 0.1 to 99% by weight of sulfur-containing organic compounds with antioxidant action. This synergistic mixture is suitable as a stabilizer for stabilizing inanimate organic material, especially mineral oil products and fuels, against the action of light, oxygen and heat.

The present technology is related to amide or ester containing quaternary ammonium salts having a hydrocarbyl substituent of number average molecular weight ranging from 300 to 750, and the use of such quaternary ammonium salts in fuel compositions to improve the water shedding performance of the fuel composition.

The present invention relates to functional fluid compositions containing friction modifiers, and specifically stable compositions containing friction modifiers with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and friction modifiers that contain one or more amide functional groups, where the friction modifier is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.

The present technology is related to imide containing quaternary ammonium salts having a hydrocarbyl substituent of number average molecular weight of 1300 to 3000, and the use of such quaternary ammonium salts in fuel compositions or lubricating compositions to improve the water shedding performance of the fuel or lubricant composition.