Patent classifications
C10M2217/044
Development of anti-bit balling fluids
Anti-bit balling drilling fluids and methods of making and using drilling fluids are provided. The anti-bit balling drilling fluid contains water, a clay-based component, and at least one of a surfactant having the formula: R(OC.sub.2H.sub.4).sub.xOH, where R is a hydrocarbyl group having from 10 to 20 carbon atoms and x is an integer from 1 and 10, or a polyethylene glycol having the formula: H(OCH.sub.2CH.sub.2).sub.nOH, where n is an integer from 1 to 50. Methods of making and using these drilling fluids are also provided.
Enhanced filtration control packages, wellbore servicing fluids utilizing the same, and methods of maintaining the structure of a wellbore
A wellbore servicing fluid comprises an aqueous base fluid, one or more alkali metal or alkali earth metal salts, at least one visocisifier, and a filtration control package. The filtration control package may comprise a carboxylic acid and an ethoxylated alcohol compound. Alternatively, the filtration control package may comprise a polyethylene glycol. The carboxylic acid may have from 8 to 20 carbon atoms. The ethoxylated alcohol compound may have a general formula R(OCH.sub.2CH.sub.2).sub.xOH, where R is a hydrocarbon having from 10 to 16 atoms and x is an integer from 6 to 9. The ethoxylated alcohol compound may have a hydrophilic-lipophilic balance of from 8.0 to 16.0. The polyethylene glycol may have a mass average molar mass (M.sub.w) of less than or equal to 1500 daltons.
Aqueous lubricant for plastic working of metal material and having superior gas clogging resistance and post-moisture absorption workability
A water-based lubricant for plastic working of a metallic material is obtained by adding to a water-based medium: (A) a polymer and/or a salt thereof containing a carboxylic acid or a derivative thereof as a constituent monomer; (B) an oxoacid of tungsten, of silicon, or of phosphorus, or a condensate thereof, and/or a salt thereof; (C) a hydroxide of an alkali metal; and (D) a lubricating component (D), and the solid content weight ratio (A)/[(A)+(B)+(C)+(D)] is 0.05 to 0.4.
DEVELOPMENT OF ANTI-BIT BALLING FLUIDS
Anti-bit balling drilling fluids and methods of making and using drilling fluids are provided. The anti-bit balling drilling fluid contains water, a clay-based component, and at least one of a surfactant having the formula: R(OC.sub.2H.sub.4).sub.xOH, where R is a hydrocarbyl group having from 10 to 20 carbon atoms and x is an integer from 1 and 10, or a polyethylene glycol having the formula: H(OCH.sub.2CH.sub.2).sub.nOH, where n is an integer from 1 to 50. Methods of making and using these drilling fluids are also provided.
ALIPHATIC TETRAHEDRAL BORATE COMPOUNDS FOR FULLY FORMULATED LUBRICATING COMPOSITIONS
A fully-formulating lubricating composition comprising an oil of lubricating viscosity; an ionic tetrahedral borate compound including a tetrahedral borate anion having a boron atom with two bidentate di-oxo ligands both being a linear C18-tartrimide; a first dispersant comprising a conventional ammonium substituted polyisobutenyl succinimide compound having a polyisobutenyl number average molecular weight of 750 to 2,500; a second dispersant comprising an ammonium substituted polyisobutenyl succinimde compound having an N:CO ratio of 1.8 and a polyisobutylenyl number average molecular weight of 750 to 2,500, wherein one or more of the first dispersant and the second dispersant are in cationic form. The fully formulated lubricating composition including one or more performance additives.
SPACER FLUID COMPOSITIONS, METHODS, AND SYSTEMS FOR AQUEOUS BASED DRILLING MUD REMOVAL
Spacer fluids include an emulsion, a surfactant package, and at least one additive that modifies the rheology of the spacer fluid, the density of the spacer fluid, or both. The emulsion may include an aqueous external phase and a hydrocarbon-based internal phase. The surfactant package may include one or more surfactants. The surfactant package may also include a surfactant having the general structure R(OCH.sub.2CH.sub.2).sub.9OH, where R is a hydrocarbyl having 12 carbon atoms, 13 carbon atoms, or 14 carbon atoms. The spacer fluid may contain at least 4.25 pounds of R(OCH.sub.2CH.sub.2).sub.9OH per barrel of the spacer fluid.
SPACER FLUID COMPOSITIONS, METHODS, AND SYSTEMS FOR AQUEOUS BASED DRILLING MUD REMOVAL
Spacer fluids include an emulsion, a surfactant package, and at least one additive that modifies the rheology of the spacer fluid, the density of the spacer fluid, or both. The emulsion may include an aqueous external phase and a hydrocarbon-based internal phase. The surfactant package may include one or more surfactants. The surfactant package may also include a surfactant having the general structure R(OCH.sub.2CH.sub.2).sub.9OH, where R is a hydrocarbyl having 12 carbon atoms, 13 carbon atoms, or 14 carbon atoms. The spacer fluid may contain at least 4.25 pounds of R(OCH.sub.2CH.sub.2).sub.9OH per barrel of the spacer fluid.
Polyolefin Dispersants and Methods of Making and Using Thereof
Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below
##STR00001##
where R.sup.x is cationic initiator residue; R.sup.a is a polyolefin group; R.sup.1 and R.sup.2 are each, independently in each (CR.sup.1R.sup.2) unit, H, alkyl, alkoxy, or alkylaryl; R.sup.3 and R.sup.4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.
Lubricating oil additives
A lubricating composition comprises an oil-soluble poly(2-oxazoline) additive having the repeat unit:
N(COR.sup.1)CH.sub.2CH.sub.2 where the number of repeat units (n) is an integer between 4 and 1000; where the polymer carries an inorganic or organic nucleophilic polymerization terminating group t, and a linear, branched or cyclic hydrocarbyl polymerization initiator group (i); and where R.sup.1 comprises a single or a mixture of linear branched or cyclic hydrocarbyl groups having 1-100 carbon atoms, some or all having 12-100 carbon atoms, or of at least one macro-monomeric hydrocarbyl group with more than 50 carbon atoms provided that when the polymer is a homopolymer and R.sup.1 lacks any hetero atoms; (A) i has a molecular weight of less than 250 g/mol, and R.sup.1 has an average number of carbon atoms of 12 to 50; or (B) n is greater than 15. The polymer may provide the composition, in the form of a lubricant, with friction modifier, and with low impact on lubricant viscosity. The polymer may be a homopolymer, a block copolymer or a star polymer.
ALIPHATIC TETRAHEDRAL BORATE COMPOUNDS FOR LUBRICATING COMPOSITIONS
An additive for a lubricating composition includes an ionic tetrahedral borate compound which includes a cation and a tetrahedral borate anion having a boron atom, the boron atom has at least one aliphatic bidentate di-oxo ligand. The cation may be selected to provide detergent and/or dispersant and/or antioxidant properties to a lubricating composition.