A process for surface treatment of metal substrates, including the steps of: providing a metal substrate including hydroxyl groups at its surface; bringing the metal substrate into contact with a solution of at least one organophosphorus compound to enable the reaction of the hydroxyl groups at the surface of the metal substrate with the organophosphorus compound to form a monomolecular layer over the surface and a second layer of physisorbed organophosphorus molecules at least preponderantly crystallized, the obtained treated substrate being coated with the organophosphorus compound in the form of a first monomolecular layer coating at least 15% of the surface of the substrate and in the form of a physisorbed second layer at least preponderantly crystallized. A treated metal substrate which may be obtained by the process thereof, corresponding solution and its use for treating metallic substrates to improve their tribological properties during their shaping, in particular their stamping.

A low transition temperature mixture (LTTM) or deep eutectic solvent (DES) useful as a lubricating oil base stock and lubricating oil including a eutectic mixture of at least a first component and at least a second component. The at least first component comprises a hydrogen bond acceptor and the at least second component comprises a hydrogen bond donor. The eutectic mixture includes an equilibrium phase between the at least first component and the at least second component. The equilibrium phase does not exhibit physical characteristics of the at least first component in an unmixed state and the at least second component in an unmixed state. The at least first component and the at least second component form an intermolecular interaction between each other sufficient to prevent crystallization of the at least first component and the at least second component in the eutectic mixture. The eutectic mixture is a liquid at 20 C.

A lubricant formulation. The lubricant formulation includes a polyol-based base lubricant, an ionic liquid, and an organic nanoparticle. The ionic liquid is selected from the group consisting of trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate, trihexyl(tetradecyl)phosphonium bis-2,4,4-(trimethylpentyl)phosphinate, and trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl)imide, or a combination thereof. The organic nanoparticle has a median particle size less than about 200 nm. The organic nanoparticle forms about 0.01 to about 5% by weight of the lubricant formulation. The ionic liquid forms about 0.5 to about 10% by weight of the lubricant formulation.

The present disclosure relates to polysiloxanes, processes for preparing polysiloxanes, and hydraulic fluids comprising polysiloxanes. This disclosure also relates to hydraulic fluids comprising one or more polysiloxane compounds and diphosphonate compounds, and to the use of diphosphonate compounds in hydraulic fluids or as additives or components in various compositions, for example to provide fire retardant properties to a fluid or composition. This disclosure also relates to use of the compositions as hydraulic fluids, which may be used in various machines, vehicles and craft, including aircraft.

The present invention describes the highly advantageous properties of a mixture of thiol-perfluoropolyether (PFPE) molecules with perfluorinated bisphosphonic (PF-BP) compounds. This mixture makes it possible in effect to obtain a lipophobic behavior (also referred to as epilame effect) with common watch-making lubricants on all the materials tested, including metals, inter alia gold and alloys thereof, ceramics and semiconductors, and gives the surface treated a good resistance to ageing and to cleaning products.

The present disclosure relates to polysiloxanes, processes for preparing polysiloxanes, and hydraulic fluids comprising polysiloxanes. This disclosure also relates to hydraulic fluids comprising one or more polysiloxane compounds and diphosphonate compounds, and to the use of diphosphonate compounds in hydraulic fluids or as additives or components in various compositions, for example to provide fire retardant properties to a fluid or composition. This disclosure also relates to use of the compositions as hydraulic fluids, which may be used in various machines, vehicles and craft, including aircraft.

The present invention provides methods of reducing friction on a surface of an apparatus that stores or transports a gas, comprising: (a) contacting the surface either directly or through an intermediate organometallic layer with a fluorinated material in a diluent, wherein the fluorinated material has the following structure: ##STR00001##
wherein A is an oxygen radical or a chemical bond; n is 1 to 20; Y is H, F, C.sub.nH.sub.2n+1 or C.sub.nF.sub.2n+1; X is H or F; b is at least 1, m is 0 to 50, p is 1 to 20, and Z is an acid group or an acid derivative; (b) forming a hydrophobic surface layer on the surface; and (c) introducing the gas into the apparatus.

The present invention provides treated gravel pack screens comprising a metal surface and a hydrophobic surface layer applied thereto, directly or through an intermediate layer. The surface layer comprises a self-assembled monolayer prepared from a fluorinated material having the structure: ##STR00001##
wherein A is an oxygen radical or a chemical bond; n is 1 to 20; Y is H, F, C.sub.nH.sub.2n+1 or C.sub.nF.sub.2n+1; X is H or F; b is at least 1, m is 0 to 50, p is 1 to 20, and Z is an acid group or an acid derivative. Also provided is a method of reducing deposition of a contaminant on a metal surface of a gravel pack screen, comprising: contacting the surface with the above fluorinated material in a diluent, directly or through an intermediate layer; forming a hydrophobic surface layer on the surface; and introducing a fluid through the gravel pack screen.

In examples, a microelectromechanical systems (MEMS) device comprises a moveable element configured to contact a portion of a surface, and a film formed of a self-assembled lubricant, the lubricant comprising a compound having (i) an oxoacid moiety and (ii) a hydrophobic moiety with an A value of equal to or greater than about 3 kilocalories/mole on the portion of the surface.