Provided herein are estolide compositions having high oxidative stability, said compositions comprising at least one compound of formula: ##STR00001##
in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R.sub.1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.3 and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided herein are uses for the compositions and methods of preparing the same.

A polyester is useful as a high viscosity base fluid. A method for its preparation involves epoxidizing an alpha-olefin, reacting the alpha-epoxide or diol with a saturated linear aliphatic dicarboxylic acid, and isolating the polyester. Lubricant compositions can contain such polyesters and the compositions are useful as automatic transmission fluids, manual transmission fluids, continuously variable transmission fluids, gear oil formulations, industrial gear oil formulations, axle fluid formulations, dual clutch transmission fluids, dedicated hybrid transmission fluids, or as hydraulic oils.

A composition is provided to comprise a non-aqueous medium and a 3,4-oxypyridinone compound of structure (I):

##STR00001##

with each A being oxygen and/or sulfur, and with a variety of substituents at R.sub.1-R.sub.5 to enable a solution or an at least semi-stable emulsion to be formed in the non-aqueous medium. Methods of use are included herein, which may be focused on situations where the composition can be used as a lubricant and/or coolant.

Lubricant compositions comprising an improved ashless organic friction modifier additive have been found to be capable of reducing both friction and wear. It has been found that mixtures of fatty-alkanolamides containing secondary hydroxyls on the amino alkyl substituent, such as amide mixtures prepared from bis(2-hydroxypropyl)amine and mixtures of at least two different C.sub.8-24 fatty acids, provide better oil solubility and friction reduction than alkanolamides with primary, hydroxyl functionality, such as amide mixtures prepared from di-ethanol)amine.

Lubricant compositions comprising an improved ashless organic friction modifier additive have been found to be capable of reducing both friction and wear. It has been found that mixtures of fatty-alkanolamides containing secondary hydroxyls on the amino alkyl substituent, such as amide mixtures prepared from bis(2-hydroxypropyl)amine and mixtures of at least two different C.sub.8-24 fatty acids, provide better oil solubility and friction reduction than alkanolamides with primary, hydroxyl functionality, such as amide mixtures prepared from di-ethanol)amine.

A fluid contains a base oil consisting of an alcohol-initiated polyalkylene glycol where polyalkylene glycol component is selected from a homopolymer of 1,2-butylene oxide and copolymer of 1,2-butylene oxide and propylene oxide; a glycerol-initiated unsaturated ester that is free of tertiary carbon atoms and quaternary carbon atoms; and an antioxidant.

A fluid contains a base oil consisting of an alcohol-initiated polyalkylene glycol where polyalkylene glycol component is selected from a homopolymer of 1,2-butylene oxide and copolymer of 1,2-butylene oxide and propylene oxide; a glycerol-initiated unsaturated ester that is free of tertiary carbon atoms and quaternary carbon atoms; and an antioxidant.

Disclosed is a lubricant base stock blend comprising a PAO base stock and an alkylated aromatics (AA) base stock, wherein at least the longer portion of the pendant groups attached to the carbon backbones of the PAO molecules have comparable length to at least the longer portion of the side chain groups attached to the aromatic ring structure of the AA molecules. The comparable lengths of at least the longer portion of the pendant groups and the side chain groups lead to enhanced improvement in oxidation stability of the blend.

A low viscosity oil has more than 50% by weight of 9-methyl-11,13-dioctyltricosane. A lubricating composition having this low viscosity oil as base oil and, optionally, another base oil or an additive. The low viscosity oil has a kinematic viscosity at 100 C., measured by the ASTM D445 standard, of 4 to 8 mm.sup.2.Math.s.sup.1. The low viscosity oil can be prepared using a metallocene catalyst, and the low viscosity oil as high performance lubricant can be used for lubrication in the field of motors, hydraulic fluids and gears, in particular bridges and transmissions.

A low viscosity oil has more than 50% by weight of 9-methylnonadecane. A lubricating composition has this low viscosity oil as base oil and, optionally, another base oil or an additive. The low viscosity oil has a kinematic viscosity at 100 C., measured by the ASTM D445 standard, of 0.5 to 2.5 mm.sup.2 s.sup.1. The low viscosity oil can be prepared using a metallocene catalyst, and the low viscosity oil can be used as high performance lubricant for lubrication in the field of motors, hydraulic fluids and gears, in particular bridges and transmissions.