Patent classifications
C10N2020/071
GREASE BASE OIL AND GREASE COMPOSITION CONTAINING SAID GREASE BASE OIL
A grease base oil, containing: condensation esters of alcohols (A) and carboxylic acids (B), wherein the alcohols (A) include a polyhydric alcohol represented by General Formula (1), the carboxylic acids (B) include a fatty acid having 5 to 9 carbon atoms (B-1), a branched fatty acid having 15 to 20 carbon atoms (B-2), a cycloalkane monocarboxylic acid having 4 to 8 carbon atoms (B-3), and an aromatic carboxylic acid (B-4), and the carboxylic acids (B) have a percentage of (B-1) above of 30 mol % to 50 mol %, a percentage of (B-2) above of 30 mol % to 50 mol %, a percentage of (B-3) above of 10 mol % to 30 mol %, and a percentage of (B-4) above of 1 mol % to 15 mol %. The grease base oil contains condensation esters having heat resistance and low temperature storageability.
LUBRICATING OIL COMPOSITION FOR INTERNAL COMBUSTION ENGINE
A lubricating oil composition for an internal combustion engine has a HTHS viscosity at 150° C. of 2.55-2.84 mPa.Math.s and includes: (A) a lubricating base oil including (a) mineral base oil(s) and/or (a) synthetic base oil(s), and having a kinematic viscosity at 100° C. of 3.8-4.6 mm.sup.2/s; (B) 1000-2000 mass ppm, in terms of metal content, of a metallic detergent including (a) metal salicylate detergent(s), and delivering 10 mmol/kg of total salicylate soap base per kilogram of the composition; (C) 1.0 to 4.0 mass % of a comb-shaped poly(meth)acrylate having a Mw of 350,000-1,000,000 and a PDI of ≤4.0; and (D) 100-1000 mass ppm, in terms of nitrogen, of a succinimide dispersant including (i) (a) non-modified succinimide dispersant(s) and/or (ii) (a) boric acid-modified succinimide dispersant(s), wherein the (i) and the (ii), in total, deliver 70 mass % of total nitrogen content of the component (D).
LUBRICATING OIL COMPOSITION FOR INTERNAL COMBUSTION ENGINE
A lubricating oil composition for an internal combustion engine has a HTHS viscosity at 150° C. of 2.55-2.84 mPa.Math.s and includes: (A) a lubricating base oil including (a) mineral base oil(s) and/or (a) synthetic base oil(s), and having a kinematic viscosity at 100° C. of 3.8-4.6 mm.sup.2/s; (B) 1000-2000 mass ppm, in terms of metal content, of a metallic detergent including (a) metal salicylate detergent(s), and delivering 10 mmol/kg of total salicylate soap base per kilogram of the composition; (C) 1.0 to 4.0 mass % of a comb-shaped poly(meth)acrylate having a Mw of 350,000-1,000,000 and a PDI of ≤4.0; and (D) 100-1000 mass ppm, in terms of nitrogen, of a succinimide dispersant including (i) (a) non-modified succinimide dispersant(s) and/or (ii) (a) boric acid-modified succinimide dispersant(s), wherein the (i) and the (ii), in total, deliver 70 mass % of total nitrogen content of the component (D).
LUBRICATING OIL COMPOSITION FOR INTERNAL COMBUSTION ENGINE
A lubricating oil composition for an internal combustion engine has a HTHS viscosity at 150° C. of 2.25 to <2.55 mPa.Math.s and includes: (A) a lubricating base oil including (a) mineral base oil(s) and/or (a) synthetic base oil(s), and having a kinematic viscosity at 100° C. of 3.8-4.6 mm.sup.2/s; (B) 1000-2000 mass ppm, in terms of metal content, of a metallic detergent including (a) metal salicylate detergent(s), and delivering ≥10 mmol/kg of total salicylate soap base per kilogram of the composition; (C) 1.0 to 4.0 mass % of a comb-shaped poly(meth)acrylate having a Mw of 350,000-1,000,000 and a PDI of ≤4.0; and (D) 100-1000 mass ppm, in terms of nitrogen, of a succinimide dispersant including (i) (a) non-modified succinimide dispersant(s) and/or (ii) (a) boric acid-modified succinimide dispersant(s), wherein the (i) and the (ii), in total, deliver 70 mass % of total nitrogen content of the component (D).
Method for converting carboxylic acids and esters into base oil hydrocarbons
A number of different branched hydrocarbon compounds (formula I) having a star-like configuration (S) are prepared from renewable oils containing fatty acids or derivatives containing fatty acids. The branched hydrocarbon compounds may be isolated individually or in mixtures, and may be used as part of base oils, such as renewable base oils (RBOs). A process for preparing the branched hydrocarbon compounds of formula I involve conditions that favour a trimerisation reaction followed by hydrotreating conditions. The compounds of formula I may be made by catalytically treating renewable material in a process, and the compounds have desirable qualities relating to lubrication, cold flow as well as having a low Noack volatility.
Process for the production of renewable base oil, diesel and naphtha
Hydrotreatment of biological oil is disclosed for producing renewable base oil and a diesel oil from low value biological oils. Low value biological oils containing free fatty acids and fatty acid esters can be processed into a renewable base oil and a renewable diesel oil in an efficient manner by first separating at least part of the free fatty acids from the feedstock and then processing separately this free acid feed in a ketonisation reaction followed by hydrodeoxygenation and hydroisomerisation reactions to yield a renewable base oil stream. The remaining free fatty acid depleted feed is processed in a separate hydrodeoxygenation and hydroisomerisation step to yield a renewable diesel stream.
USE OF BIODEGRADABLE HYDROCARBON FLUIDS AS DRILLING FLUIDS
The invention is a fluid having a kinematic viscosity from 3 to 6 mm.sup.2/s, a flash point of higher than 120° C. and a pour point lower than −40° C., having a boiling point in the range of from 200° C. to 400° C. and a boiling range below 80° C., said fluid comprising more than 95% isoparaffins and less than 3% of naphthens by weight, a biocarbon content of at least 95% by weight, containing less than 100 ppm aromatics by weight. The invention is also a drilling fluid and the use of the fluid to improve the viscosity of the drilling fluid.
Lubricating oils
A lubricating composition comprises an amide and at least one additive. The amide is the reaction product of a secondary, branched amine and a carboxylic acid. The carboxylic acid may be a monocarboxylic acid or a dicarboxylic acid, including dimer acid. The amide is hydrolytically stable, and may be used to increase the hydrolytic stability of the lubricant composition. Alternatively, the amide may be used to increase the additive solubility or detergency of the lubricant composition.
Lubricating oils
A lubricating composition comprises an amide and at least one additive. The amide is the reaction product of a secondary, branched amine and a carboxylic acid. The carboxylic acid may be a monocarboxylic acid or a dicarboxylic acid, including dimer acid. The amide is hydrolytically stable, and may be used to increase the hydrolytic stability of the lubricant composition. Alternatively, the amide may be used to increase the additive solubility or detergency of the lubricant composition.
Production of renewable base oil and diesel by pre-fractionation of fatty acids
Methods are disclosed for producing renewable base oil and a diesel oil from low-value biological oils. Low-value biological oils containing free fatty acids and fatty acid esters can be processed into a renewable base oil and a renewable diesel oil by first separating at least part of the saturated free fatty acids from the feedstock and then processing separately this saturated free acid feed in a ketonisation reaction followed by hydrodeoxygenation and hydroisomerisation reactions to yield a renewable base oil stream. The remaining free fatty acid depleted feed may be processed in a separate hydrodeoxygenation and hydroisomerisation step to yield a renewable diesel stream.