The invention relates to industrial gear oil compositions that have been specially designed to have improved storage stability and/or paint compatibility and/or seal compatibility. This improvement is achieved while maintaining good performance in other areas. These improvements are particularly relevant to synthetic lubricants, such as those made with polyalphaolefin (PAO) base oils. This balance of properties has been difficult to achieve in synthetic compositions where problems in the areas of storage stability, paint compatibility and/or seal compatibility of become more pronounced. The invention also relates to processes of making such compositions and methods of using the same.

In some embodiments, a compound has the formula (I) where: R.sub.1 and R.sub.2 are alkyl or, together with the carbon atom to which they are attached, cycloalkyl; R.sub.3, R.sub.4 and R.sub.5 are H or alkyl (formula II); R.sub.6 is alkyl or where: R.sub.7 and R.sub.8 are H, alkyl or, together with the carbon atom to which they are attached, cycloalkyl; R.sub.9 is H or alkyl; X is alkylene or is absent; and p is 0, 1, 2 or 3; and m and n are 0, 1, 2 or 3 provided that m is 0 when R.sub.4 and R.sub.5 are H. The compound is suitable for use as a base stock which provides low volatility for a given viscosity profile. The compound may be used in a lubricant composition for an internal combustion engine. ##STR00001##

A composition including at least one lubricant including polyol esters and a refrigerant fluid F including 1-chloro-3,3,3-trifluoropropene. Also, a composition including at least one lubricant based on polyol esters and a refrigerant fluid F including 1-chloro-3,3,3-trifluoropropene and at least one C3 to C6 alkene stabilizing compound including a single double bond. Also, different uses of the compositions.

A process for the preparation of saturated hydrocarbon base oils is provided, comprising oligomerization of a feed mixture that has an average carbon number in the range of 14 to 18 to produce an oligomer product comprising dimers, trimers, and higher oligomers, where the dimer has a branching proximity (BP) of 20 or greater, isomerization of at least the dimer portion, and hydrogenation of the isomerized product. The dimer portion is separated from the oligomer product, and a saturated hydrocarbon base oil is obtained comprising greater than 90% dimers having an average carbon number in the range of from 29 to 36, and the dimer portion having a weight average molecular weight in the range of 422 to 510, where the dimers have an average Branching Index (BI) in a range of 22 to 26 and an average paraffin branching proximity (BP) in a range of from 18 to 26.

The present invention relates to a polyalphaolefin having a uniform structure and a method of preparing the same, and more particularly to a method of preparing polyalphaolefin having a uniform comb-like structure by minimizing the formation of short chain branches, which deteriorate the properties of lubricant base oil, using a homogeneous single-active-site metallocene catalyst, an organometallic compound cocatalyst and an organoboron compound promoter.

This disclosure relates to ester compounds formed from gamma-branched aliphatic alcohols, lubricating oil base stocks comprising such ester compounds, lubricating oil compositions comprising such ester compounds, and method of making such base stocks. The lubricating oil base stocks comprising the ester compounds exhibit desirable lubricating properties such as polarity.

A lubricating oil for hybrid engine includes a major amount of an oil of lubricating viscosity; a boron-containing compound in an amount to provide 50 to 300 ppm of boron to lubricating oil composition; an overbased calcium salicylate or a mixture of an overbased calcium sulfonate and overbased calcium salicylate individually having a total base number of greater than 150 mg KOH/g, measured by the method of ASTM D-2896, present in an amount that provides 800 ppm to 1800 ppm of calcium to the lubricating oil composition; zinc dithiophosphate (ZnDTP) in an amount to bring from 100 to 800 ppm of phosphorus to the lubricating oil composition; and a non-dispersant comb polymethacrylate (PMA) viscosity index improver (VII). The boron-containing compound includes a borated dispersant. The KV at 100 C. of the lubricating oil composition is from 6 cSt to 8.5 cSt, the KV at 40 C. of the lubricating oil composition is from 25 cSt to 35 cSt, and the VI of the lubricating oil composition is greater than 200.

A base oil includes an ester compound obtained by reacting a fatty acid component and a monohydric alcohol component. The fatty acid component includes a C.sub.4-C.sub.28 fatty acid. The monohydric alcohol component includes at least one C.sub.4-C.sub.22 straight chain monohydric alcohol and at least one C.sub.4-C.sub.22 branched chain monohydric alcohol. A lubricant oil composition including the base oil is also disclosed.

A base oil includes an ester compound obtained by reacting a fatty acid component and a monohydric alcohol component. The fatty acid component includes a C.sub.4-C.sub.28 fatty acid. The monohydric alcohol component includes at least one C.sub.4-C.sub.22 straight chain monohydric alcohol and at least one C.sub.4-C.sub.22 branched chain monohydric alcohol. A lubricant oil composition including the base oil is also disclosed.

A composition comprising olefin oligomers of one or more olefin monomers, the olefin monomers comprising a branched C.sub.10 olefin monomer comprising i) 3-propyl-1-heptene, ii) 4-ethyl-1-octene, iii) 5-methyl-1-nonene, or iv) any combination thereof. A composition comprising substantially hydrogenated olefin oligomers, wherein the olefin oligomers are oligomers of one or more olefin monomers, the olefin monomers comprising a branched C.sub.10 olefin monomer comprising i) 3-propyl-1-heptene, ii) 4-ethyl-1-octene, iii) 5-methyl-1-nonene, or iv) any combination thereof. A process comprising a) contacting 1) a catalyst system and 2) a monomer feedstock comprising a branched C.sub.10 olefin monomer comprising i) 3-propyl-1-heptene, ii) 4-ethyl-1-octene, iii) 5-methyl-1-nonene, or iv) any combination thereof in a reaction zone; and b) forming olefin oligomers.