The present disclosure provides processes for producing alkylated fatty acids and derivatives thereof. In at least one embodiment, a process includes introducing a terminal alkyl transferase and a fatty acid into a bioreactor. The process includes introducing an internal methyl transferase and internal methyl reductase into the bioreactor or a second bioreactor. The process includes obtaining an alkylated fatty acid having a methyl substituent located at an internal carbon atom of the fatty acid and a methyl substituent or ethyl substituent located at a carbon atom alpha to the terminal carbon atom of the fatty acid.

Compounds having the formula (F-I) below are provided herein: ##STR00001##
wherein R.sup.1 and R.sup.2 at each occurrence are independently a C.sub.1-C.sub.5000 alkyl group; R.sup.3 at each occurrence is independently hydrogen or a C.sub.1-C.sub.5000 alkyl group; R.sup.4 is a C.sub.1-C.sub.50 alkyl group or an unsubstituted or substituted phenyl group; R.sup.5 at each occurrence is independently hydrogen or a C.sub.1-C.sub.30 alkyl group; n is 1, 2, 3, or 4; and m+n is 5. Processes for preparing compounds of formula (F-I) as well as base stock and lubricant compositions containing compounds of formula (F-I) are also provided.

A liquid blend of octylated phenyl-α-naphthylamine, and at least one low molecular weight aromatic ester, wherein the octylated phenyl-α-naphthylamine is present from about 15% to about 35% by weight of the blend, as well as a lubricating composition comprising a lubricant base and an amount of the blend which provides up to 2.0% by weight of the octylated phenyl-α-naphthylamine in the composition.

A comb polymer can be used for reducing a Noack evaporation loss of a lubricant composition, especially of an engine oil composition. Application of the comb polymer to the lubricant composition can bring about the desired reduction. The comb polymer can include specified amounts of macromonomer and alkyl acrylates. Resulting lubricant compositions can include the comb polymer.

Methods are disclosed for producing renewable base oil and a diesel oil from low-value biological oils. Low-value biological oils containing free fatty acids and fatty acid esters can be processed into a renewable base oil and a renewable diesel oil by first separating at least part of the saturated free fatty acids from the feedstock and then processing separately this saturated free acid feed in a ketonisation reaction followed by hydrodeoxygenation and hydroisomerisation reactions to yield a renewable base oil stream. The remaining free fatty acid depleted feed may be processed in a separate hydrodeoxygenation and hydroisomerisation step to yield a renewable diesel stream.

A number of different branched hydrocarbon compounds (formula I) having a star-like configuration (S) are prepared from renewable oils containing fatty acids or derivatives containing fatty acids. The branched hydrocarbon compounds may be isolated individually or in mixtures, and may be used as part of base oils, such as renewable base oils (RBOs). A process for preparing the branched hydrocarbon compounds of formula I involve conditions that favour a trimerisation reaction followed by hydrotreating conditions. The compounds of formula I may be made by catalytically treating renewable material in a process, and the compounds have desirable qualities relating to lubrication, cold flow as well as having a low Noack volatility.

Provided herein are lubricant compositions comprising renewable base oils as embodied by hydrocarbon mixtures with controlled structure characteristics in combination with lubricant additives that address performance requirements and stricter environmental and fuel economy regulations. The lubricant composition provides performance in the cold crank simulated viscosity (CCS) vs Noack volatility relationship, which allows for the formulation of lower viscosity engine oils with improved fuel economy, improved fuel economy retention, and retained LSPI prevention additionally conferring improved characteristics to other devices or apparatus requiring lubrication.

Compounds having the formula (F-I) below are provided herein:

##STR00001##

wherein R.sup.1 and R.sup.2 at each occurrence are independently a C.sub.1-C.sub.5000 alkyl group; R.sup.3 at each occurrence is independently hydrogen or a C.sub.1-C.sub.5000 alkyl group; R.sup.4 is a C.sub.1-C.sub.50 alkyl group or an unsubstituted or substituted phenyl group; R.sup.5 at each occurrence is independently hydrogen or a C.sub.1-C.sub.30 alkyl group; n is 1, 2, 3, or 4; and m+n is 5. Processes for preparing compounds of formula (F-I) as well as base stock and lubricant compositions containing compounds of formula (F-I) are also provided.

Compounds having the formula (F-I) below are provided herein: ##STR00001##
wherein R.sup.1 and R.sup.2 at each occurrence are independently a C.sub.1-C.sub.5000 alkyl group; R.sup.3 at each occurrence is independently hydrogen or a C.sub.1-C.sub.5000 alkyl group; R.sup.4 is a C.sub.1-C.sub.50 alkyl group or an unsubstituted or substituted phenyl group; R.sup.5 at each occurrence is independently hydrogen or a C.sub.1-C.sub.30 alkyl group; n is 1, 2, 3, or 4; and m+n is 5. Processes for preparing compounds of formula (F-I) as well as base stock and lubricant compositions containing compounds of formula (F-I) are also provided.

A comb polymer can be used for reducing a Noack evaporation loss of a lubricant composition, especially of an engine oil composition. Application of the comb polymer to the lubricant composition can bring about the desired reduction. The comb polymer can include specified amounts of macromonomer and alkyl acrylates. Resulting lubricant compositions can include the comb polymer.