Patent classifications
C10N2030/041
LUBRICATING COMPOSITION CONTAINING AN OXYALKYLATED HYDROCARBYL PHENOL
The invention provides lubricating composition comprising: an oil of lubricating viscosity, and an oxyalkylated hydrocarbyl phenol, wherein the oxyalkylated hydrocarbyl phenol is substituted with at least one aliphatic hydrocarbyl group of 40 to 96 carbon atoms, and wherein the oxyalkylated hydrocarbyl phenol is substantially free of aromatic hydrocarbyl groups. The invention further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The invention further relates to the use of the oxyalkylated hydrocarbyl phenol in the lubricating composition to a passenger car internal combustion engine at least one of (i) control of fuel economy, (ii) control of corrosion, (iii) cleanliness, and (iv) control of bore wear.
LUBRICATING OIL COMPOSITION
A lubricating oil composition is provided, which can reduce friction even when the viscosity is lowered. A lubricating oil composition comprising a lubricating base oil, (A) a cleaning agent containing magnesium, and (B) a zinc dialkyl dithiophosphate, wherein the amount of component (A) is 200 to 1200 ppm by weight of magnesium per total weight of lubricating oil composition; the amount of component (B) is 300 to 1000 ppm by weight phosphorus based on total weight of lubricating oil composition; wherein component (B) comprises (B-1) a zinc dialkyl dithiophosphate having a primary alkyl group, and the proportion of the weight of component (B-1) to the total weight of component (B) is 30 weight % or more; and the concentration of boron [B] is less than 100 ppm by weight.
Oxazoline modified dispersants
The present disclosure relates to oxazoline modified lubricant additives that have dispersant properties and lubricating oil compositions including such dispersant lubricant additives. The disclosure also relates to the use of lubricant compositions comprising the additives of the disclosure for improving the soot or sludge handling characteristics of an engine lubricant composition while providing robust and consistent frictional performance at the same time.
High Viscosity Index Comb Copolymer Viscosity Modifiers and Methods of Modifying Lubricant Viscosity Using Same
A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) (optionally from 7.0 wt % to 18 wt %, by repeat units, of) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer; (b) (optionally from 33 wt % to 64 wt % or from 38 wt % to 58 wt %, by repeat units, of) a C.sub.3-C.sub.8 alkyl (alk)acrylate ester monomer; (c) (optionally up to 35.0 wt %, by repeat units, of) a C.sub.12-C.sub.24 alkyl (alk)acrylate ester monomer; and (d) (optionally from 3.0 wt % to 27 wt %, by repeat units, of) a C.sub.6-C.sub.20 aryl, aralkyl, or alkaryl (alk)acrylate ester monomer, such that a sum of repeat units due to (c) plus (d) constitute at least 21.0 wt % of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity and dispersancy, are also contemplated.
High Viscosity Index Comb Copolymer Viscosity Modifiers and Methods of Modifying Lubricant Viscosity Using Same
A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) (optionally from 7.0 wt % to 18 wt %, by repeat units, of) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer; (b) (optionally from 33 wt % to 64 wt %, by repeat units, of) a C.sub.3-C.sub.8 alkyl (alk)acrylate ester monomer; (c) a C.sub.12-C.sub.24 alkyl (alk)acrylate ester monomer; and (d) (optionally from 3.0 wt % to 25 wt %, by repeat units, of) H-endcapped, C.sub.1-C.sub.18 alkyl-endcapped, or C.sub.6-C.sub.20 aryl-, aralkyl-, or alkaryl-endcapped C.sub.2-C.sub.6 oxyalkyl or C.sub.2-C.sub.6 oligo(alkylene glycol)-based (alk)acrylate ester monomer, wherein repeat units based on monomer (c) and/or monomer (d) comprise at least 21.0 wt % (and optionally up to 35.0 wt %) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity and dispersancy, are also contemplated.
High Viscosity Index Comb Polymer Viscosity Modifiers and Methods of Modifying Lubricant Viscosity Using Same
A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) (optionally from 7.0 wt % to 18 wt %, by repeat units, of) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer; (b) (optionally from 33 wt % to 64 wt % or from 38 wt % to 58 wt %, by repeat units, of) a C.sub.3-C.sub.8 alkyl (alk)acrylate ester monomer; (c) (optionally up to 35.0 wt %, by repeat units, of) a C.sub.12-C.sub.24 alkyl (alk)acrylate ester monomer; and (d) (optionally from 3.0 wt % to 27 wt %, by repeat units, of) a C.sub.6-C.sub.20 aryl, aralkyl, or alkaryl (alk)acrylate ester monomer, such that a sum of repeat units due to (c) plus (d) constitute at least 21.0 wt % of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity and dispersancy, are also contemplated.
High Viscosity Index Comb Polymer Viscosity Modifiers and Methods of Modifying Lubricant Viscosity Using Same
A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) (optionally from 7.0 wt % to 18 wt %, by repeat units, of) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer; (b) (optionally from 33 wt % to 64 wt %, by repeat units, of) a C.sub.3-C.sub.8 alkyl (alk)acrylate ester monomer; (c) a C.sub.12-C.sub.24 alkyl (alk)acrylate ester monomer; and (d) (optionally from 3.0 wt % to 25 wt %, by repeat units, of) H-endcapped, C.sub.1-C.sub.18 alkyl-endcapped, or C.sub.6-C.sub.20 aryl-, aralkyl-, or alkaryl-endcapped C.sub.2-C.sub.6 oxyalkyl or C.sub.2-C.sub.6 oligo(alkylene glycol)-based (alk)acrylate ester monomer, wherein repeat units based on monomer (c) and/or monomer (d) comprise at least 21.0 wt % (and optionally up to 35.0 wt %) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity and dispersancy, are also contemplated.
Lubricating composition containing an oxyalkylated hydrocarbyl phenol
The invention provides lubricating composition comprising: an oil of lubricating viscosity, and an oxyalkylated hydrocarbyl phenol, wherein the oxyalkylated hydrocarbyl phenol is substituted with at least one aliphatic hydrocarbyl group of 40 to 96 carbon atoms, and wherein the oxyalkylated hydrocarbyl phenol is substantially free of aromatic hydrocarbyl groups. The invention further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The invention further relates to the use of the oxyalkylated hydrocarbyl phenol in the lubricating composition to a passenger car internal combustion engine at least one of (i) control of fuel economy, (ii) control of corrosion, (iii) cleanliness, and (iv) control of bore wear.
Sulfurized catecholate detergents for lubricating compositions
A lubricating composition includes a sulfurized oxy-substituted aromatic polyol compound and an oil of lubricating viscosity. The sulfurized oxy-substituted aromatic polyol compound includes at least one of a sulfurized oxy-substituted aromatic polyol and a salt of a sulfurized oxy-substituted aromatic polyol. The compound is suitable as a replacement for detergents that contain C.sub.n alkyl phenols derived from oligomers of propylene.
Engine oils for soot handling and friction reduction
Engine oil \s and methods for use in soot-producing engines. The engine oil contains a major amount of a base oil and a dispersant reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, and B) at least one polyamine, that is post-treated with C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups of C) are attached directly to an aromatic ring. A molar ratio of carboxyl groups from components A) and C) to nitrogen atoms from component B) of from 0.9 to 1.3 is used to make the dispersant which also has a molar ratio of component C) to component B) of at least 0.4 and when component B) has an average of 4-6 nitrogen atoms per molecule, a molar ratio of A) to B) is from 1.0 to 1.6.